p-phenylenediamine
4-phenylenediamine
Identification
| Name | p-phenylenediamine |
| IUPAC | benzene-1,4-diamine |
| CAS Number | 106-50-3 |
| EINECS | 203-404-7 |
| FDA UNII | U770QIT64J |
| Molecular Formula | C6 H8 N2 |
| Molecular Weight | 108.14376000 |
| MDL Number | MFCD00007901 |
| Nikkaji Number | J4.035E |
| Beilstein | 749029 |
| XlogP3 | -0.30 (est) |
Regulatory
| FDA Mainterm (IAUFC) | 106-50-3 ; P-PHENYLENEDIAMINE |
Physical Properties
| Appearance | white to purple crystalline solid (est) |
| Assay | 95.00 to 100.00 |
| Food Chemicals Codex Listed | No |
| Melting Point | 146.00 °C. @ 760.00 mm Hg |
| Boiling Point | 267.00 °C. @ 760.00 mm Hg |
| Flash Point | > 230.00 °F. TCC ( > 110.00 °C. ) |
| logP (o/w) | -0.300 |
| Soluble in | water, 3.70E+04 mg/L @ 23C (exp) |
Cosmetic Information
| CosIng | cosmetic data |
| Cosmetic Uses | hair dyeing agents |
No sensory data available
Safety Information
| Preferred SDS | View |
| Oral/Parenteral Toxicity | oral-bird - wild LD50 100 mg/kg |
| Dermal Toxicity | subcutaneous-dog LDLo 100 mg/kg |
| Inhalation Toxicity | inhalation-rat LC50 920 mg/m3/4H |
GHS Classification
['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']
Safety in Use
| Category | hair dyeing agents |
| Recommendation for p-phenylenediamine usage levels up to | not for fragrance use. |
| Recommendation for p-phenylenediamine flavor usage levels up to | not for flavor use. |
ECSA Chemicals
Human Chemistry
ECSA Chemicals has been active since 1913 in the trading and international commerce of raw materials. With an organisation divided into industrial segments managed by specialists, it has become one of...
Potential Uses
Natural Occurrence
Synonyms
p-
aminoaniline
aminogen II
(4-
aminophenyl)amine
4-
aminophenylamine
benzene-1,4-diamine
1,4-
benzenediamine
p-
benzenediamine
1,4-
benzenediamine (9CI)
benzofur D
c.i. 76060
C.I. developer 13
C.I. oxidation base 10
ci 76060
developer 13
developer PF
1,4-
diaminobenzene
p-
diaminobenzene
para-
diaminobenzene
durafur black R
p-
fenylendiamin
fouramine D
fourrine 1
fourrine D
fur black 41867
fur black R
fur brown 41866
fur yellow
furro D
futramine D
nako H
oxidation base 10
pelagol D
pelagol DR
pelagol grey D
peltol D
1,4-
phenyldiamine
1,4-
phenylene diamine
4-
phenylene diamine
p-
phenylene diamine
para-
phenylene diamine (c.i. 76060)
phenylenediamine
1,4-
phenylenediamine
4-
phenylenediamine
para-
phenylenediamine
phenylenediamine, para
renal PF
rodol D
santoflex IC
santoflex LC
tertral D
ursol D
ursol-D
vulkanox 4020
zoba black D
PubMed:
Oligomeric complexes of some heteroaromatic ligands and aromatic diamines with rhodium and molybdenum tetracarboxylates: (13) C and (15) N CPMAS NMR and density functional theory studies.
PubMed:
Batchwise dyeing of bamboo cellulose fabric with reactive dye using ultrasonic energy.
PubMed:
Application of mechanosynthesized azine-decorated zinc(II) metal-organic frameworks for highly efficient removal and extraction of some heavy-metal ions from aqueous samples: a comparative study.
PubMed:
Photocatalytic applications with CdS ⢠block copolymer/exfoliated graphene nanoensembles: hydrogen generation and degradation of Rhodamine B.
PubMed:
Enhanced lifetime of organic light-emitting diodes using an anthracene derivative with high glass transition temperature.
PubMed:
meso-Tetraphenylbenzoporphyrin-2(2),2(3)-dicarboxylic anhydride: a platform to benzoporphyrin derivatives.
PubMed:
Conformational landscape, photochemistry, and infrared spectra of sulfanilamide.
PubMed:
Synthesis and characterization of new donor-acceptor type copolymers based on fluorene derivatives for photovoltaic solar cells.
PubMed:
N,N'-Bis[1-(pyridin-2-yl)-ethyl-idene]benzene-1,4-diamine.
PubMed:
Poly[di-μ(3)-chlorido-di-μ(2)-chlorido-{μ(4)-N,N,N',N'-tetra-kis-[(diphenyl-phosphan-yl)meth-yl]benzene-1,4-diamine-κ(4)P:P':P'':P'''}tetra-copper(II)].
PubMed:
Effect of the environment on the electrical conductance of the single benzene-1,4-diamine molecule junction.
PubMed:
A third polymorph of N,N'-bis-(pyridin-2-yl)benzene-1,4-diamine.
PubMed:
N,N'-Bis(4-methyl-benzyl-idene)benzene-1,4-diamine.
PubMed:
(E,E)-N-(2,3,4,5,6-Penta-fluoro-benzyl-idene)-N-(3,4,5-trimeth-oxy-benzyl-idene)benzene-1,4-diamine.
PubMed:
N,N'-Bis(pyridin-2-yl)benzene-1,4-diamine-naphthalene (2/1).
PubMed:
N,N'-Bis(pyridin-2-yl)benzene-1,4-diamine-quinoxaline (2/1).
PubMed:
N,N-Diethynyl-N,N-diphenyl-benzene-1,4-diamine.
PubMed:
Tetra-aqua-bis-[N,N'-bis-(pyridin-3-yl-methyl-idene)benzene-1,4-diamine]-zinc dinitrate 1.49-hydrate.
PubMed:
{μ-N,N,N',N'-Tetra-kis[(diphenyl-phosphan-yl)meth-yl]benzene-1,4-diamine}-bis-[(2,2'-bipyrid-yl)copper(I)] bis-(tetra-fluoridoborate).
PubMed:
A centrosymmetric monoclinic polymorph of N,N-bis-(pyridin-3-yl-methyl-idene)benzene-1,4-diamine.
PubMed:
2,5-Bis{2,2-bis-[4-(dimethyl-amino)-phen-yl]ethen-yl}-N,N'-diphenyl-N,N'-dipropyl-benzene-1,4-diamine.
PubMed:
Synthesis, structural characterization and luminescent properties of a series of Cu(I) complexes based on polyphosphine ligands.
PubMed:
Conformational polymorphism of (E,E)-N,N'-bis(4-nitrobenzylidene)benzene-1,4-diamine.
PubMed:
DNA binding, oxidative DNA cleavage, cytotoxicity, and apoptosis-inducing activity of copper(II) complexes with 1,4-tpbd (N,N,N',N'-tetrakis(2-yridylmethyl)benzene-1,4-diamine) ligand.
PubMed:
4-Salicylideneamino-3-methyl-1,2,4-triazole-5-thione as a sensor for aniline recognition.
PubMed:
Novel on-site sample preparation approach with a portable agitator using functional polymer-coated multi-fibers for the microextraction of organophosphorus pesticides in seawater.
PubMed:
Electrochemical degradation of aromatic amines on BDD electrodes.
PubMed:
Design of small molecules that target metal-A{beta} species and regulate metal-induced A{beta} aggregation and neurotoxicity.
PubMed:
N-[(E)-4-Chloro-benzyl-idene]-N'-phenyl-benzene-1,4-diamine.
PubMed:
catena-Poly[[(nitrato-κO,O')silver(I)]-μ-N,N'-bis-(3-pyridyl-methyl-idene)benzene-1,4-diamine].
PubMed:
Dichlorido[N-(2-pyridylmethyl-idene)benzene-1,4-diamine]zinc(II).
PubMed:
Small molecule modulators of copper-induced Abeta aggregation.
PubMed:
N,N-Diethyl-N'-[(E)-4-pyridylmethylene]benzene-1,4-diamine: a combined X-ray and density functional theory study.
PubMed:
Synthesis, X-ray crystal structures, magnetism, and DNA cleavage properties of copper(II) complexes with 1,4-tpbd ligand.
PubMed:
Self-assembly of 2D Borromean networks through hydrogen-bonding recognition.
PubMed:
N,N'-Bis(2-thienylmethyl-ene)benzene-1,4-diamine.
PubMed:
{μ-trans-N,N'-Bis[(diphenyl-phosphan-yl)meth-yl]benzene-1,4-diamine-κP:P'}bis-{(acetonitrile-κN)[dipyrido[3,2-a:2',3'-c]phenazine-κN,N]copper(I)} bis-(tetra-fluoridoborate).
PubMed:
Self-assembly of triple helical and meso-helical cylindrical arrays tunable by bis-tripodal coordination converters.
PubMed:
Final report on the safety assessment of HC Red No. 7.
PubMed:
Self-assembly of a one-dimensional iron(II) coordination polymer with p-phenylenebis(picolinaldimine).
PubMed:
[The expanding role of occupational and non-occupational allergy to paraphenylenediamine].
PubMed:
N,N'-Bisbenzylidenebenzene-1,4-diamines and N,N'-Bisbenzylidenenaphthalene-1,4-diamines as Sirtuin Type 2 (SIRT2) Inhibitors.
PubMed:
Self-assembly, reorganization, and photophysical properties of silver(I)-Schiff-base molecular rectangle and polymeric array species.
PubMed:
N,N-dimethyl-N'-[(1E,2E)-3-(4-nitrophenyl)prop-2-enylidene]benzene-1,4-diamine and N,N-dimethyl-4-[(1E,3E)-4-(4-nitrophenyl)buta-1,3-dienyl]-1-naphthylamine.
PubMed:
Degradation of aniline by newly isolated, extremely aniline-tolerant Delftia sp. AN3.