(Z+E)-2-hexene

2-hexene (mixed cis & trans)

CAS: 592-43-8 C6 H12 MW: 84.16164000

Identification

Name(Z+E)-2-hexene
IUPAChex-2-ene
CAS Number592-43-8
EINECS209-755-2
FDA UNIIRBV8CN16R2
Molecular FormulaC6 H12
Molecular Weight84.16164000
MDL NumberMFCD00009473
Beilstein969179

Regulatory

Physical Properties

Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Specific Gravity 0.68100 to 0.68500 @ 20.00 °C.
Pounds per Gallon - (est). 5.673 to 5.707
Refractive Index 1.39300 to 1.39700 @ 20.00 °C.
Boiling Point 68.00 °C. @ 760.00 mm Hg
Vapor Pressure 147.386993 mmHg @ 25.00 °C. (est)
Flash Point -5.00 °F. TCC ( -20.56 °C. )
logP (o/w) 3.355 (est)
Soluble in water, 88.53 mg/L @ 25 °C (est)

No sensory data available

Safety Information

Preferred SDSView
Oral/Parenteral ToxicityNot determined
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryinformation only not used for fragrances or flavors
Recommendation for (Z+E)-2-hexene usage levels up tonot for fragrance use.
Recommendation for (Z+E)-2-hexene flavor usage levels up tonot for flavor use.

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Potential Uses

None Found

Natural Occurrence

not found in nature

Synonyms

hex-2-ene 2- hexene 2- hexene (mixed cis & trans) PubMed: Highly cis-selective and lead-free hydrogenation of 2-hexyne by a supported Pd catalyst with an ionic-liquid layer. PubMed: Olefin isomerization and hydrosilylation catalysis by Lewis acidic organofluorophosphonium salts. PubMed: Oil constituents of Artemisia nilagirica var. septentrionalis growing at different altitudes. PubMed: Imaging the dynamics of chlorine atom reactions with alkenes. PubMed: Freshness characterisation of whiting (Merlangius merlangus) using an SPME/GC/MS method and a statistical multivariate approach. PubMed: Rate constants for the gas-phase reactions of OH radicals with a series of C6-C14 alkenes at 299 +/- 2 K. PubMed: Heterogeneous ozone oxidation reactions of 1-pentene, cyclopentene, cyclohexene, and a menthenol derivative studied by sum frequency generation. PubMed: Stereochemical preferences in 4-center syn-eliminations from gaseous ions. PubMed: Highly regioselective isomerization-hydroformylation of internal olefins to linear aldehyde using rh complexes with tetraphosphorus ligands. PubMed: Structure-activity relationship (SAR) for the gas-phase ozonolysis of aliphatic alkenes and dialkenes. PubMed: Addition of the phenoxathiin cation radical to alkenes and nonconjugated dienes. Formation of (E)- and (Z)-(10-phenoxathiiniumyl)alkenes and (E)- and (Z)-(10-phenoxathiiniumyl)dienes on basic alumina. PubMed: Rhodium-catalyzed hydroformylation of 1-hexene in an ionic liquid: a molecular dynamics study of the hexene/[BMI][PF6] interface. PubMed: Benzidine transformation processes in natural sediments. PubMed: Determination of the adsorption model of alkenes and alcohols on sulfonic copolymer by inverse gas chromatography. PubMed: Adducts of phenoxathiin and thianthrene cation radicals with alkenes and cycloalkenes. PubMed: Binding and functional affinity of some newly synthesized phenethylamine and phenoxypropanolamine derivatives for their agonistic activity at recombinant human beta3-adrenoceptor. PubMed: Synthesis of (+)-polyoxamic acid and D-sorbitol from simple achiral allylic halides employing (S,S)-hydrobenzoin as a chiral source. PubMed: Synthesis of 4,6-dideoxyfuranoses through the regioselective and diastereoselective oxyfunctionalization of a dimethylphenylsilyl-substituted chiral homoallylic alcohol. PubMed: Synthesis of (2S, 4S, 5S)-5-(t-Butoxycarbonylamino)-4-(t-Butyldimethylsilyloxy)-2-Isopropyl-7-Methyl Octanoic Acid. PubMed: A Novel Synthesis of Poly(ester-alt-sulfide)s by the Ring-Opening Alternating Copolymerization of Oxiranes with gamma-Thiobutyrolactone Using Quaternary Onium Salts or Crown Ether Complexes as Catalysts. PubMed: Benzotriazole- and 1,2,4-Triazole-Stabilized Allylic Anions: Applications in Syntheses of Functionalized alpha,beta-Unsaturated Ketones, gamma-Lactones, gamma-Lactams, and beta-Substituted Esters. PubMed: 193-nm Photodissociation of ions from saturated and unsaturated aliphatic molecules. PubMed: Reactivity of 4',4"-diethylstilbestrol quinone, a metabolic intermediate of diethylstilbestrol. PubMed: Deuterium labeling of diethylstilbestrol and analogues. PubMed: Isomerization of trans-diethylstilbestrol to pseudo-diethylstilbestrol. PubMed: The genetics of alpha-hydroxyacid oxidase and alcohol dehydrogenase in the mouse: evidence for multiple gene loci and linkage between Hao-2 and Adh-3. PubMed: Metal clusters in catalysis: Hydrocarbon reactions.