2-pyridyl carbinol
pyridine, 2-(hydroxymethyl)-
Identification
| Name | 2-pyridyl carbinol |
| IUPAC | pyridin-2-ylmethanol |
| CAS Number | 586-98-1 |
| EINECS | 209-592-7 |
| FDA UNII | 7HQ8UT1TPS |
| Molecular Formula | C6 H7 N O |
| Molecular Weight | 109.12799000 |
| MDL Number | MFCD00006348 |
| Nikkaji Number | J32.889H |
| Beilstein | 0107849 |
| XlogP3 | 0.10 (est) |
Regulatory
Physical Properties
| Appearance | colorless to pale yellow clear liquid (est) |
| Assay | 95.00 to 100.00 |
| Food Chemicals Codex Listed | No |
| Specific Gravity | 1.13300 to 1.13500 @ 20.00 °C. |
| Pounds per Gallon - (est). | 9.439 to 9.455 |
| Refractive Index | 1.54200 to 1.54600 @ 20.00 °C. |
| Melting Point | -6.00 to -5.00 °C. @ 760.00 mm Hg |
| Boiling Point | 112.00 °C. @ 15.00 mm Hg, 222.00 to 223.00 °C. @ 760.00 mm Hg (est) |
| Vapor Pressure | 0.026000 mmHg @ 25.00 °C. (est) |
| Flash Point | 179.00 °F. TCC ( 81.70 °C. ) (est) |
| logP (o/w) | 0.060 |
| Soluble in | water, 1e+006 mg/L @ 25 °C (est) |
Organoleptic Properties
| Taste Description | roasted moldy |
Safety Information
| Preferred SDS | View |
| Oral/Parenteral Toxicity | oral-quail LD50 1000 mg/kg |
| Dermal Toxicity | Not determined |
| Inhalation Toxicity | Not determined |
GHS Classification
['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']
Safety in Use
| Category | information only not used for fragrances or flavors |
| Recommendation for 2-pyridyl carbinol usage levels up to | not for fragrance use. |
| Recommendation for 2-pyridyl carbinol flavor usage levels up to | not for flavor use. |
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Potential Uses
Natural Occurrence
Synonyms
2-
hydromethyl pyridine
2-
hydromethyl-pyridine
2-
hydroxymethyl pyridine
2-
hydroxymethyl-pyridine
2-(
hydroxymethyl)pyridine
2-
hydroxymethylpyridine
2-
picolyl alcohol
alpha-
picolyl alcohol
piconol
pyridin-2-yl)methanol
pyridin-2-ylmethanol
pyridine-2-carbinol
pyridine-2-methanol
pyridine-2-ylmethanol
pyridine, 2-(hydroxymethyl)-
2-
pyridinemethanol
2-
pyridinyl methanol
2-
pyridinylmethanol
2-
pyridylcarbinol
2-
pyridylmethan-1-ol
2-
pyridylmethanol
US Patents:
3,952,024 - Furfurylthioacetone
PubMed:
A one-dimensional coordination polymer with a capped [Cu4O4] cubane core assembled from 2-(hydroxymethyl)pyridine.
US Patents:
Certain 2,5-dimethyl-3-thiopyrazines
PubMed:
Manganese/cerium clusters spanning a range of oxidation levels and CeMn(8), Ce(2)Mn(4), and Ce(6)Mn(4) nuclearities: structural, magnetic, and EPR properties.
PubMed:
A racemic and enantiopure unsymmetric diiron(III) complex with a chiral o-carborane-based pyridylalcohol ligand: combined chiroptical, magnetic, and nonlinear optical properties.
PubMed:
Closer to photosystem II: a Co4O4 cubane catalyst with flexible ligand architecture.
PubMed:
Synthesis, structural characterization and cell death-inducing effect of novel palladium(II) and platinum(II) saccharinate complexes with 2-(hydroxymethyl)pyridine and 2-(2-hydroxyethyl)pyridine on cancer cells in vitro.
PubMed:
Two novel lead(II) complexes of 2-(hydroxymethyl)pyridine: a threefold diamondoid supramolecular network based on Pb4O4 cores and a two-dimensional (4,4) network based on Pb2O2 units.
PubMed:
Synthesis, crystal structures, DNA binding and cytotoxicity of two novel platinum(II) complexes containing 2-(hydroxymethyl)pyridine and pyridine-2-carboxylate ligands.
PubMed:
trans-Dichloridopalladium(II) and platinum(II) complexes with 2-(hydroxymethyl)pyridine and 2-(2-hydroxyethyl)pyridine: synthesis, structural characterization, DNA binding and in vitro cytotoxicity studies.
PubMed:
Tuning the interactions from antiferro- to ferro-magnetic by molecular tailoring and manipulating.
PubMed:
Bis[2-(2-hy-droxy-meth-yl)pyridine-κ(2)N,O](pivalato-κO)copper(II).
PubMed:
Synthesis, structure and magnetic study of a novel mixed-valent Co(II)10Co(III)4 shield constructed by mixed pyridine-alcoholate ligands.
PubMed:
New mixed-valent Mn clusters from the use of N,N,N',N'-tetrakis(2-hydroxyethyl)ethylenediamine (edteH4): Mn3, Mn4, Mn6, and Mn10.
PubMed:
A new family of nonanuclear lanthanide clusters displaying magnetic and optical properties.
PubMed:
Carboxylate-free Mn(III)2Ln(III)2 (Ln = lanthanide) and Mn(III)2Y(III)2 complexes from the use of (2-hydroxymethyl)pyridine: analysis of spin frustration effects.
PubMed:
Mn8 and Mn16 clusters from the use of 2-(hydroxymethyl)pyridine, and comparison with the products from bulkier chelates: a new high nuclearity single-molecule magnet.
PubMed:
A linear tetranuclear single-molelcule magnet of Mn(II)(2)Mn(III)(2) with the anion of 2-(Hydroxymethyl)pyridine.
PubMed:
Mn(7) and Mn(12) clusters from use of 2-(pyridine-2-yl)propan-2-ol: a new half-integer single-molecule magnet.
PubMed:
Mn4, Mn6, and Mn11 clusters from the use of bulky diphenyl(pyridine-2-yl)methanol.
PubMed:
Azide groups in higher oxidation state manganese cluster chemistry: from structural aesthetics to single-molecule magnets.
PubMed:
High-spin Mn4 and Mn10 molecules: large spin changes with structure in mixed-valence MnII4MnIII6 clusters with azide and alkoxide-based ligands.
PubMed:
New Fe4, Fe6, and Fe8 clusters of iron(III) from the use of 2-pyridyl alcohols: structural, magnetic, and computational characterization.
PubMed:
Synthesis, structures, and magnetic properties of heteronuclear Cu(II)-Ln(III) (Ln = La, Gd, or Tb) complexes.
PubMed:
Synthesis, structure, and magnetic properties of a Mn(21) single-molecule magnet.
PubMed:
Heptanuclear and decanuclear manganese complexes with the anion of 2-hydroxymethylpyridine.
PubMed:
Single-molecule magnets: a new family of Mn(12) clusters of formula [Mn(12)O(8)X(4)(O(2)CPh)(8)L(6)].