methyl morpholine oxide

morpholine, 4-methyl-, 4-oxide

CAS: 7529-22-8 C5 H11 N O2 MW: 117.14807000

Identification

Namemethyl morpholine oxide
IUPAC4-methyl-4-oxidomorpholin-4-ium
CAS Number7529-22-8
EINECS231-391-8
FDA UNIIARC64PKJ0F
Molecular FormulaC5 H11 N O2
Molecular Weight117.14807000
MDL NumberMFCD00005947
Nikkaji NumberJ256.599D
Beilstein0507437

Regulatory

Physical Properties

Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Specific Gravity 1.13000 @ 25.00 °C.
Flash Point 32.00 °F. TCC ( 0.00 °C. ) (est)
logP (o/w) -1.820 (est)
Soluble in water, 9.223e+005 mg/L @ 25 °C (est)

Cosmetic Information

CosIngcosmetic data
Cosmetic Usescleansing agents

No sensory data available

Safety Information

Preferred SDSView
Oral/Parenteral ToxicityNot determined
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryfoam boosting, surfactant agents
Recommendation for methyl morpholine oxide usage levels up tonot for fragrance use.
Recommendation for methyl morpholine oxide flavor usage levels up tonot for flavor use.

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Potential Uses

surfactants

Natural Occurrence

not found in nature

Synonyms

4- methyl morpholine 4-oxide monohydrate 4- methyl morpholine N-oxide 4- methyl-4-oxidomorpholin-4-ium 4- methylmorpholine 4-oxide 4- methylmorpholine 4-oxide monohydrate 4- methylmorpholine 4-oxide, monohydrate 4- methylmorpholine N-oxide N- methylmorpholine oxide 4- methylmorpholine-4-oxide morpholine, 4-methyl-, 4-oxide PubMed: Iron(II) complexes supported by sulfonamido tripodal ligands: endogenous versus exogenous substrate oxidation. PubMed: Preparation and reactivity of the versatile uranium(IV) imido complexes U(NAr)Cl₂(R₂bpy)₂ (R = Me, (t)Bu) and U(NAr)Cl₂(tppo)₃. PubMed: Biogas production from lignocelluloses by N-methylmorpholine-N-oxide (NMMO) pretreatment: effects of recovery and reuse of NMMO. PubMed: Biogas production from N-methylmorpholine-N-oxide (NMMO) pretreated forest residues. PubMed: Effect of oleic acid ligand on photophysical, photoconductive and magnetic properties of monodisperse SnO2 quantum dots. PubMed: Pretreatment of oil palm empty fruit bunch (OPEFB) by N-methylmorpholine-N-oxide (NMMO) for biogas production: structural changes and digestion improvement. PubMed: Enzymatic saccharification of sugarcane bagasse by N-methylmorpholine-N-oxide-tolerant cellulase from a newly isolated Galactomyces sp. CCZU11-1. PubMed: A new simple and high-yield synthesis of 5α-dihydrotestosterone (DHT), a potent androgen receptor agonist. PubMed: Role of solvent parameters in the regeneration of cellulose from ionic liquid solutions. PubMed: Ultrasound-assisted compatible in situ hydrolysis of sugarcane bagasse in cellulase-aqueous-N-methylmorpholine-N-oxide system for improved saccharification. PubMed: Kinetic modeling of rapid enzymatic hydrolysis of crystalline cellulose after pretreatment by NMMO. PubMed: Techno-economical study of ethanol and biogas from spruce wood by NMMO-pretreatment and rapid fermentation and digestion. PubMed: Correlating physical changes and enhanced enzymatic saccharification of pine flour pretreated by N-methylmorpholine-N-oxide. PubMed: A pilot study on lignocelluloses to ethanol and fish feed using NMMO pretreatment and cultivation with zygomycetes in an air-lift reactor. PubMed: A novel process for ethanol or biogas production from cellulose in blended-fibers waste textiles. PubMed: An expedient procedure for the oxidative cleavage of olefinic bonds with PhI(OAc)2, NMO, and catalytic OsO4. PubMed: Oxidative addition to U(V)-U(V) dimers: facile routes to uranium(VI) bis(imido) complexes. PubMed: Enhancement of ethanol and biogas production from high-crystalline cellulose by different modes of NMO pretreatment. PubMed: Enzymatic hydrolysis of cellulose dissolved in N-methyl morpholine oxide/water solutions. PubMed: Pretreatment of spruce and oak by N-methylmorpholine-N-oxide (NMMO) for efficient conversion of their cellulose to ethanol. PubMed: Enhanced enzymatic hydrolysis of sugarcane bagasse by N-methylmorpholine-N-oxide pretreatment. PubMed: Regenerated cellulose-silk fibroin blends fibers. PubMed: N-Methylmorpholine-N-oxide ring cleavage registration by ESR under heating conditions of the Lyocell process. PubMed: Kinetics of cellulose regeneration from cellulose--NaOH--water gels and comparison with cellulose--N-methylmorpholine-N-oxide--water solutions. PubMed: Luminescent property and catalytic activity of Ru(II) carbonyl complexes containing N, O donor of 2-hydroxy-1-naphthylideneimines. PubMed: 'Pincer' dicarbene complexes of some early transition metals and uranium. PubMed: Wet spinning of Bombyx mori silk fibroin dissolved in N-methyl morpholine N-oxide and properties of regenerated fibres. PubMed: Kinetics of precipitation of cellulose from cellulose-NMMO-water solutions. PubMed: Solubility and rheological behavior of silk fibroin (Bombyx mori) in N-methyl morpholine N-oxide. PubMed: Kinetic and chemical studies on the isomerization of monosaccharides in N-methylmorpholine-N-oxide (NMMO) under Lyocell conditions. PubMed: Synthesis of 2-fluoronoraristeromycin and its inhibitory activity against Plasmodium falciparum S-adenosyl-L-homocysteine hydrolase. PubMed: Novel Oxidative Transformation of Indenoisoquinolines to Isoquinoline-3-spiro-3'-phthalides in the Presence of Osmium Tetraoxide and 4-Methylmorpholine N-Oxide. PubMed: Swelling and dissolution of silk fibroin (Bombyx mori) in N-methyl morpholine N-oxide. PubMed: Biodegradation of N-methylmorpholine-N-oxide. PubMed: High substrate specificity and induction characteristics of trimethylamine-N-oxide reductase of Escherichia coli. PubMed: Tetrapropylammonium perruthenate as a mild and efficient oxidant for sensitive steroidal alcohols. PubMed: 4-Methylmorpholine N-oxide-methyl sulfoxide soluble glucan of Piptoporus betulinus. PubMed: Cell-wall glucans of Cryptococcus neoformans Cap 67. PubMed: Pollen sporoplasts: dissolution of pollen walls.