allyl bromide
1-bromo-2-propene
Identification
| Name | allyl bromide |
| IUPAC | 3-bromoprop-1-ene |
| CAS Number | 106-95-6 |
| EINECS | 203-446-6 |
| FDA UNII | FXQ8X2F74Z |
| Molecular Formula | C3 H5 Br |
| Molecular Weight | 120.97685000 |
| MDL Number | MFCD00000244 |
| Nikkaji Number | J4.040A |
| Beilstein | 0605308 |
| XlogP3 | 1.80 (est) |
Regulatory
Physical Properties
| Appearance | colorless to pale yellow clear liquid (est) |
| Assay | 95.00 to 100.00 |
| Food Chemicals Codex Listed | No |
| Specific Gravity | 1.39800 @ 25.00 °C. |
| Melting Point | -11.90 °C. @ 760.00 mm Hg |
| Boiling Point | 70.10 °C. @ 760.00 mm Hg |
| Vapor Pressure | 153.455002 mmHg @ 25.00 °C. (est) |
| Vapor Density | 4.17 ( Air = 1 ) |
| Flash Point | 28.00 °F. TCC ( -2.22 °C. ) |
| logP (o/w) | 1.790 |
| Soluble in | water, 3830 mg/L @ 25 °C (exp) |
No sensory data available
Safety Information
| Preferred SDS | View |
| Oral/Parenteral Toxicity | intraperitoneal-mouse LD50 48 mg/kg |
| Dermal Toxicity | Not determined |
| Inhalation Toxicity | inhalation-mammal (species unspecified) LC50 4110 mg/m3 |
GHS Classification
['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']
Safety in Use
| Category | pharmaceuticals / chemical synthisis |
| IFRA Purity Specification | < 0.1% free allyl alcohol |
| Recommendation for allyl bromide usage levels up to | not for fragrance use. |
| Recommendation for allyl bromide flavor usage levels up to | not for flavor use. |
Potential Uses
Natural Occurrence
Synonyms
allylbromide
bromallylene
1-
bromo-2-propene
3-
bromo-propene
3-
bromoprop-1-ene
3-
bromopropene
3-
bromopropylene
1-
propene, 3-bromo-
PubMed:
Nematicidal activity of allyl bromide and dibromo(nitro)methane under laboratory conditions
PubMed:
Toxicology studies of allyl bromide (CAS No. 106-95-6) in genetically modified (FVB Tg.AC hemizygous) mice and carcinogenicity studies of allyl bromide in genetically modified [B6.129-Trp53tm1Brd (N5) Hapl
PubMed:
Retraction: Beltaef et al. An expeditious synthesis of [1,2]isoxazolidin-5-ones and [1,2]oxazin-6-ones from functional allyl bromide derivatives. Molecules 2010, 15, 4094-4101
PubMed:
Indium-Mediated Stereoselective Allylation
PubMed:
Design, synthesis, and SAR study of isopropoxy allylbenzene derivatives as 15-lipoxygenase inhibitors
PubMed:
Furan Oxidation Strategy for the Synthesis of the Macrolactone Analogue of Migrastatin
PubMed:
Rotation-Triggered Transmetalation on a Heterobimetallic Cu/Al N-Phosphine-Oxide-Substituted Imidazolylidene Complex
PubMed:
Hyperbranched Poly(ether-siloxane)s Containing Ammonium Groups: Synthesis, Characterization and Catalytic Activity
PubMed:
Direct and Delayed Dynamics in Electron-Induced Surface Reaction
PubMed:
Synthesis of Quaternary-Substituted Thiazolines via Halocyclization of S-Allyl Thioimidate Salts
PubMed:
Bioconversion of ethyl 4-chloro-3-oxobutanoate by permeabilized fresh brewer's yeast cells in the presence of allyl bromide
PubMed:
Palladium-catalyzed allyl cross-coupling reactions with in situ generated organoindium reagents
PubMed:
Synthesis of novel tri- and tetrasubstituted C18 furan fatty esters
PubMed:
The Role Ionic Liquid [BMIM][PF(6)] in One-Pot Synthesis of Tetrahydropyran Rings through Tandem Barbier-Prins Reaction
PubMed:
Chromium(III)-Catalyzed C(sp(2))-H Alkynylation, Allylation, and Naphthalenation of Secondary Amides with Trimethylaluminum as Base
PubMed:
An expeditious synthesis of [1,2]isoxazolidin-5-ones and [1,2]oxazin-6-ones from functional allyl bromide derivatives
PubMed:
Mannan-based conjugates as a multimodal imaging platform for lymph nodes
PubMed:
In-situ synthesis of acylated sodium alginate-g-(tetrahydrofuran(5)-b-polyisobutylene) terpolymer/Ag-NPs nanocomposites
PubMed:
Total synthesis of alotaketal A
PubMed:
?-Cyclodextrin functionalized polystyrene porous monoliths for separating phenol from wastewater
PubMed:
Novel Quaternary Ammonium-Functionalized Covalent Organic Frameworks/Poly(2,6-dimethyl-1,4-phenylene oxide) Hybrid Anion Exchange Membranes with Enhanced Ion Conductivity and Stability
PubMed:
B-B Bond Nucleophilicity in a Tetraaryl ?-Hydridodiborane(4) Anion
PubMed:
Redox-Active Ligand-Assisted Two-Electron Oxidative Addition to Gallium(II)
PubMed:
A mild synthesis of new aryl vinyl ethers and diethyl 1-[(alkyl)(cyano)methyl]vinylphosphonates via the substitution of a 2,3-difunctional allyl bromide
PubMed:
Allylic compounds bind directly to DNA: investigation of the binding mechanisms in vitro
PubMed:
Synthesis of a spirocyclic indoline lactone
PubMed:
Organic impurity profiling of 3,4-methylenedioxymethamphetamine (MDMA) synthesised from catechol
PubMed:
N,N,N-trimethylchitosan modified with well defined multifunctional polymer modules used as pDNA delivery vector
PubMed:
Structures and Reactivities of Sodiated Evans Enolates: Role of Solvation and Mixed Aggregation on the Stereochemistry and Mechanism of Alkylations
PubMed:
An efficient asymmetric synthesis of diacylglycerols
PubMed:
Synthesis and antimicrobial evaluation of novel pyrazolones and pyrazolone nucleosides
PubMed:
Preparation of (+)-trans-isoalliin and its isomers by chemical synthesis and RP-HPLC resolution
PubMed:
Gas-phase synthesis of [Ag4H]+ and its mediation of the C--C coupling of allyl bromide
PubMed:
Expeditious synthesis of the fused hexacycle of puberuline C via a radical-based cyclization/translocation/cyclization process
PubMed:
Synthesis and anticancer activity of some new s-glycosyl and s-alkyl 1,2,4-triazinone derivatives
PubMed:
Direct synthesis of B-allyl and B-allenyldiisopinocampheylborane reagents using allyl or propargyl halides and indium metal under Barbier-type conditions
PubMed:
Design and synthesis of modular oxazoline ligands for the enantioselective chromium-catalyzed addition of allyl bromide to ketones
PubMed:
Oxidation state, aggregation, and heterolytic dissociation of allyl indium reagents
PubMed:
Kinetic and spectroscopic characterization of the isomers of the allyl bromide molecular ion
PubMed:
Preparation of cis-?-hydroxycarvone derivatives for synthesis of sesterterpenoid natural products: total synthesis of phorbin A
PubMed:
Pharmacological actions of levallorphan allyl bromide (CM 32191), a new peripheral narcotic antagonist
PubMed:
Per-O-(3-hydroxy)propyl-beta-cyclodextrin: a cyclodextrin derivative bearing only primary hydroxyl groups
PubMed:
Rapid detection of avian influenza A virus by immunochromatographic test using a novel fluorescent dye
PubMed:
Reactions of atoms and free radicals in solution; the reaction of allyl bromide with bromotrichloromethane
PubMed:
Structure and reactivity of the cysteine methyl ester radical cation
PubMed:
Structure and Reaction Chemistry of Magnesium Organocuprates Derived from Magnesiacyclopentadienes and Copper(I) Salts
PubMed:
Asymmetric syntheses of epohelmins A and B by In-mediated allylation
PubMed:
Mutagenicity of vinyl compounds in Salmonella typhimurium
PubMed:
Metal-free activation in the anionic ring-opening polymerization of cyclopropane derivatives
PubMed:
One-pot preparation of trifluoromethylated homoallylic N-acylhydrazines or à-methylene-?-lactams from acylhydrazines, trifluoroacetaldehyde methyl hemiacetal, allyl bromide and tin
PubMed:
Secondary deuterium kinetic isotope effects in irreversible additions of allyl reagents to benzaldehyde
PubMed:
Copper-catalyzed regioselective fluorination of allylic halides
PubMed:
[Investigation on isotopic exchange of bromine between sodium bromide and allyl bromide in alcohol solution]
PubMed:
Role of Hydrogen Bonding on the Reactivity of Thiyl Radicals: A Mass Spectrometric and Computational Study Using the Distonic Radical Ion Approach
PubMed:
Fractionation of whey proteins with high-capacity superparamagnetic ion-exchangers
PubMed:
Pressure dependent product formation in the photochemically initiated allyl + allyl reaction
PubMed:
New (99m)Tc(CO)(3) mannosylated dextran bearing S-derivatized cysteine chelator for sentinel lymph node detection
PubMed:
Synthetic and mechanistic studies of indium-mediated allylation of imines in ionic liquids
PubMed:
[Molecular toxicological mechanism of the lethal interactions of the new antiviral drug, sorivudine, with 5-fluorouracil prodrugs and genetic deficiency of dihydropyrimidine dehydrogenase]
PubMed:
7-Bromo-4b-methyl-7,8-dihydro-4bH-9-thia-8a-aza-fluorene 9,9-dioxide
PubMed:
Kinetics and mechanisms of the unimolecular elimination of 2,2-diethoxypropane and 1,1-diethoxycyclohexane in the gas phase: experimental and theoretical study
PubMed:
Aromatic allylation via diazotization: variation of the allylic moiety and a short route to a benzazepine derivative
PubMed:
Highly efficient formal synthesis of cephalotaxine, using the Stevens rearrangement--acid lactonization sequence as a key transformation
PubMed:
Gastragogue effect of laxatives and allyl-bromide-mixture
PubMed:
Indium-catalyzed reduction of allyl bromide with gallium or aluminum. Formation of allylgallium and allylaluminum sesquibromides
PubMed:
A synthetic macromolecule for sentinel node detection: (99m)Tc-DTPA-mannosyl-dextran
PubMed:
Photodissociation dynamics of allyl bromide at 234, 265, and 267 nm
PubMed:
Synthesis and antibacterial activity of 2, 3-dehydro-3-O-(3-aryl-E-prop-2-enyl)-10, 11-anhydroclarithromycin derivatives
PubMed:
The design and synthesis of 9-phenylcyclohepta[d]pyrimidine-2,4-dione derivatives as potent non-nucleoside inhibitors of HIV reverse transcriptase
PubMed:
Synthesis of halogenated 4-quinolones and evaluation of their antiplasmodial activity
PubMed:
Directed hydrozirconation of propargylic alcohols
PubMed:
Kinetics and mechanisms of the thermal decomposition of 2-methyl-1,3-dioxolane, 2,2-dimethyl-1,3-dioxolane, and cyclopentanone ethylene ketal in the gas phase. Combined experimental and DFT study
PubMed:
Selective palladium(ii)-mediated oxidation of homoallylic N-tert-butanesulfinyl amine derivatives
PubMed:
Synthesis of Chiral 1,3-Dienes through Ring-Closing Metathesis of Enantioenriched Enynes: Potential Precursors of Morphane Analogs
PubMed:
Stereochemical Study of the Allylation of Aldehydes with Allyl Halides in Cosolvent/Water(Salt)/Zn and in Cosolvent/Water(Salt)/Zn/Haloorganotin Media
PubMed:
Indium and zinc-mediated Barbier-type addition reaction of 2,3-allenals with allyl bromide: an efficient synthesis of 1,5,6-alkatrien-4-ols
PubMed:
Stereoselective synthesis of pyroglutamate natural product analogs from à- aminoacids and their anti-cancer evaluation
PubMed:
Titanocene(III) chloride mediated radical induced allylation of aldimines: formal synthesis of C-linked 4'-deoxy aza-disaccharide
PubMed:
DFT computational study of the mechanism of allyl halides carbonylation catalyzed by nickel tetracarbonyl
PubMed:
Low energy electron-induced decomposition of (?(3)-C(3)H(5))Ru(CO)(3)Br, a potential focused electron beam induced deposition precursor with a heteroleptic ligand set
PubMed:
Stereoselective à-aminoallylation of aldehydes with chiral tert-butanesulfinamides and allyl bromides
PubMed:
Synthesis and evaluation of 3-salicyloylpyridine derivatives as cytotoxic mitochondrial apoptosis inducers
PubMed:
Mechanism-based inactivation of human dihydropyrimidine dehydrogenase by (E)-5-(2-bromovinyl)uracil in the presence of NADPH
PubMed:
Stereospecific 7à-alkylation of 20-hydroxyecdysone in a lithium-ammonia solution
PubMed:
2-(chromon-3-yl)imidazole derivatives as potential antimicrobial agents: synthesis, biological evaluation and molecular docking studies
PubMed:
Enantioselective synthesis and preliminary metabolic studies of the optical isomers of 2-n-propyl-4-pentenoic acid, a hepatotoxic metabolite of valproic acid
PubMed:
Palladium complexes with a tridentate PNO ligand. Synthesis of eta1-allyl complexes and cross-coupling reactions promoted by boron compounds
PubMed:
Synthesis of a deoxy analogue of ADP L-glycero-D-manno-heptose
PubMed:
[Alkylation of gem-dibromocyclopropanes with higher-order organocuprates]
PubMed:
Synthesis of the oxepinochromone natural products ptaeroxylin (desoxykarenin), ptaeroxylinol, and eranthin
PubMed:
N,N'-(Hexane-1,6-diyl)bis(4-methyl-N-(oxiran-2-ylmethyl)benzenesulfonamide): Synthesis via cyclodextrin mediated N-alkylation in aqueous solution and further Prilezhaev epoxidation
PubMed:
Total synthesis of antillatoxin
PubMed:
Aromatic allylation via diazotization: metal-free C-C bond formation
PubMed:
Addition of organochromium reagents to heteroaryl aldehydes. Synthesis of heteroaryl substituted bis-allyl ethers and homoallyl ethers
PubMed:
[Biotransformation of 4-methyl-7-allyloxy coumarin by transgenic hairy roots of Polygonum multiflorum]
PubMed:
Preparation of 4'-substituted thymidines by substitution of the thymidine 5'-esters
PubMed:
Indium-mediated asymmetric barbier-type allylations: additions to aldehydes and ketones and mechanistic investigation of the organoindium reagents
PubMed:
Polar reactions of acyclic conjugated bisallenes
PubMed:
Chiral Diarylmethanes via Copper-Catalyzed Asymmetric Allylic Arylation with Organolithium Compounds
PubMed:
A novel palladium-catalyzed coupling of epoxides with allyl bromide mediated by indium(I) chloride: a cascade epoxide rearrangement-carbonyl allylation
PubMed:
Experimental and theoretical studies of the homogeneous, unimolecular gas-phase elimination kinetics of trimethyl orthovalerate and trimethyl orthochloroacetate
PubMed:
An advance on exploring N-tert-butanesulfinyl imines in asymmetric synthesis of chiral amines
PubMed:
Copper-free asymmetric allylic alkylation with a Grignard reagent: design of the ligand and mechanistic studies
PubMed:
Synthesis of acyclovir and HBG analogues having nicotinonitrile and its 2-methyloxy 1,2,3-triazole
PubMed:
Preparation of 1,3-bis(allyloxy)benzene under a new multi-site phase-transfer catalyst combined with ultrasonication--a kinetic study
PubMed:
Sensory irritating effects of allyl halides and a role for hydrogen bonding as a likely feature at the receptor site
PubMed:
Joint experimental and DFT study of the gas-phase unimolecular elimination kinetic of methyl trifluoropyruvate
PubMed:
Investigation into the regiochemistry of some isoxazoles derived from 1,3-dipolar cycloaddition of 4-nitrobenzonitrile oxide with some dipolarophiles: a combined theoretical and experimental studies
PubMed:
Modified glycogen as construction material for functional biomimetic microfibers
PubMed:
Zinc-mediated allylation and alkylation of aminals in the presence of TMSCl and diisopropylamine
PubMed:
Reactions of atoms and free radicals in solution; decomposition of diacetyl peroxide in allyl bromide
PubMed:
Manganese-Mediated Carbon-Carbon Bond Formation in Aqueous Media: Chemoselective Allylation and Pinacol Coupling of Aryl Aldehydes
PubMed:
Synthesis and anti-HIV-1 activity of novel 2,3-dihydro-7H-thiazolo[3,2-a]pyrimidin-7-ones
PubMed:
Glucopyranosylidene-spiro-iminothiazolidinone, a new bicyclic ring system: synthesis, derivatization, and evaluation for inhibition of glycogen phosphorylase by enzyme kinetic and crystallographic methods
PubMed:
Structure-activity relationships of alpha, beta-unsaturated carbonylic compounds
PubMed:
Reactivity and enantioselectivity in the reactions of scalemic stereogenic alpha-(N-carbamoyl)alkylcuprates
PubMed:
Frequency of C-allylations on oligoglycinates via N-ylides
PubMed:
Reactivity of alkynylzirconates towards allyl bromides: selective formation of ?-allyl-zirconacyclopentadienes
PubMed:
Metal-mediated allylation of enzymatically oxidized methyl à-D-galactopyranoside
PubMed:
Cotton functionalized with peptides: characterization and synthetic methods
PubMed:
Silica: An efficient catalyst for one-pot regioselective synthesis of dithioethers
PubMed:
Synthesis and anticholinesterase activity of (-)-N1-norphysostigmine, (-)-eseramine, and other N(1)-substituted analogues of (-)-physostigmine
PubMed:
P(NMe2)3-Mediated Umpolung Alkylation and Nonylidic Olefination of à-Keto Esters
PubMed:
Vinylic C--H borylation of cyclic vinyl ethers with bis(pinacolato)diboron catalyzed by an Iridium(I)-dtbpy complex
PubMed:
Aliphatic analogues of nucleotides: synthesis and affinity towards nucleases
PubMed:
Enantioselective allylic alkylation of stereodefined polysubstituted copper enolates as an entry to acyclic quaternary carbon stereocentres
PubMed:
Mono(cycloheptatrienyl) tantalum chemistry: synthesis and characterization of new tantalum halide, hydride, and alkyl species
PubMed:
Indium-mediated asymmetric Barbier-type allylation of aldimines in alcoholic solvents: synthesis of optically active homoallylic amines
PubMed:
Synthesis of Six-Membered Spiro Azacyclic Oxindole Derivatives via a One-Pot Process of Umpolung Allylation/Aza-Prins Cyclization
PubMed:
Structural and oxo-transfer reactivity differences of hexacoordinate and pentacoordinate (nitro)(tetraphenylporphinato)cobalt(III) derivatives
PubMed:
A convenient procedure for bismuth-mediated Barbier-type allylation of aldehydes in water containing fluoride ions
PubMed:
Synthesis of 2,5-Diaryl-1,5-dienes from Allylic Bromides Using Visible-Light Photoredox Catalysis
PubMed:
[Effects of ATP-regulated potassium channels modulators, N-(2-pyridyl)-N'-(4-toluol) sulfonylcarbamides, on electromechanical activity in guinea pig myocardium]
PubMed:
An enantiospecific approach to tricyclic sesquiterpenes mayurone and thujopsenes
PubMed:
Stereoselective allylation of 4-oxoazetidine-2-carbaldehydes. Application To the stereocontrolled synthesis of fused tricyclic beta-lactams via intramolecular diels-alder reaction of 2-azetidinone-tethered
PubMed:
Analytical application of poly{methyl[3-(2-hydroxy-3,4-difluoro)phenyl]propyl siloxane} as a QCM coating for DMMP detection
PubMed:
An approach to the total synthesis of the marine ascidian metabolite perophoramidine via a halogen-selective tandem Heck/carbonylation strategy
PubMed:
Toward a protecting-group-free halogen-metal exchange reaction: practical, chemoselective metalation of functionalized aromatic halides using dianion-type zincate, tBu4ZnLi2
PubMed:
A versatile synthesis of ?-lactam-fused oxacycles through the palladium-catalyzed chemo-, regio-, and diastereoselective cyclization of allenic diols
PubMed:
Monomeric and dimeric nickel complexes derived from a pincer ligand featuring a secondary amine donor moiety
PubMed:
Elimination of HX (X = Cl, Br) from haloalkenes on the Ru2Q2 (Q = S, Se) core complex
PubMed:
Generation of chiral boron enolates by rhodium-catalyzed asymmetric 1,4-addition of 9-aryl-9-borabicyclo[3.3.1]nonanes (B-Ar-9BBN) to alpha,beta-unsaturated ketones
PubMed:
[bmim][Br] as a solvent and activator for the Ga-mediated Barbier allylation: direct formation of an N-heterocyclic carbene from Ga metal
PubMed:
Syntheses, derivatives, solubility, and interfacial properties of 2-methyl-2-polyfluoroalkenyloxymethyl-1,3-propanediols: potential building blocks for syntheses of amphiphatic macromolecules
PubMed:
Diastereoselection during 1,2-Addition of the Allylindium Reagent to alpha-Thia and alpha-Amino Aldehydes in Aqueous and Organic Solvents
PubMed:
Unique structural properties of 2,4,6-tri-tert-butylanilide: isomerization and switching between separable amide rotamers through the reaction of anilide enolates
PubMed:
Total synthesis of a cuticular hydrocarbon from the cane beetle Antitrogus parvulus: confirmation of the relative stereochemistry
PubMed:
Motilides, macrolides with gastrointestinal motor stimulating activity. II. Quaternary N-substituted derivatives of 8,9-anhydroerythromycin A 6,9-hemiacetal and 9,9-dihydroerythromycin A 6,9-epoxide
PubMed:
Synthesis, structure, and reactions of NH-bridged calix[m]arene[n]pyridines
PubMed:
Synthesis and biological evaluation of (2,5-dihydro-1H-pyrrol-1-yl)-2H-chromen-2-ones as free radical scavengers
PubMed:
Cobalt-Catalyzed Cross-Coupling of Grignards with Allylic and Vinylic Bromides: Use of Sarcosine as a Natural Ligand
PubMed:
Total synthesis and absolute configuration of minalemine A, a guanidine peptide from the marine tunicate Didemnum rodriguesi
PubMed:
Mechanical properties of IIR/OMMT nanocomposites via melt-compounding and solution process
PubMed:
Regiospecifically alpha-13C-labeled porphyrins for studies of ground-state hole transfer in multiporphyrin arrays
PubMed:
Magnesium-Mediated Carbon-Carbon Bond Formation in Aqueous Media: Barbier-Grignard Allylation and Pinacol Coupling of Aldehydes
PubMed:
Biphilic Organophosphorus Catalysis: Regioselective Reductive Transposition of Allylic Bromides via P(III)/P(V) Redox Cycling
PubMed:
Evidence for a rapid degenerate hetero-Cope-type rearrangement in [Cp*W(S)2S-CH2-CH=CH2]
PubMed:
Investigation of the gas phase reactivity of the 1-adamantyl radical using a distonic radical anion approach
PubMed:
Synthesis and structural characterization of mono- and bisfunctional o-carboranes
PubMed:
Indium- or Zinc-Mediated One-Pot Synthesis of Homoallylamines, beta-Amino Esters, and beta-Amino Nitriles
PubMed:
Template synthesis of benzannulated N-heterocyclic carbene ligands
PubMed:
Iron-catalyzed carbometalation of propargylic and homopropargylic alcohols
PubMed:
Aqueous Barbier allylation of aldehydes mediated by tin
PubMed:
Mechanism of alpha-amino acids decomposition in the gas phase. experimental and theoretical study of the elimination kinetics of N-benzyl glycine ethyl ester
PubMed:
Novel and efficient method for the allylation of carbonyl compounds and imines using triallylaluminum
PubMed:
Convenient synthesis of racemic mixed-chain ether glycerophosphocholines from fatty alkyl allyl ethers: useful analogs for biophysical studies
PubMed:
Neighboring group migration in enzyme-mediated halohydrin formation
PubMed:
Joint experimental and theoretical studies of the mechanism for the gas phase elimination kinetics of methyl 2,2-dimethyl-3-hydroxypropionate
PubMed:
Metal-catalyzed cyclization of beta- and gamma-allenols derived from D-glyceraldehyde--synthesis of enantiopure dihydropyrans and tetrahydrooxepines: an experimental and theoretical study
PubMed:
Structure and reactivity of the N-acetyl-cysteine radical cation and anion: does radical migration occur?
PubMed:
Novel vinyl phosphonates and vinyl boronates by halogenation, allylation, and propargylation of alpha-boryl- and alpha-phosphonozirconacyclopentenes
PubMed:
Synthesis, molecular structure and characterization of allylic derivatives of 6-amino-3-methyl-1,2,4-triazolo[3,4-f][1,2,4]-triazin-8(7H)-one
PubMed:
Silicones containing pendant biocides for antifouling coatings
PubMed:
A Facile Generation of a Cyclopropylzinc Compound from an Alkenylzinc Derivative and Its Reaction with Electrophiles
PubMed:
A novel solid phase for selective separation of flavonoid compounds
PubMed:
Stereoselective functionalisation of cis- and trans-2-ferrocenyl-3-pivaloyl-4-alkyl-1,3-oxazolidin-5-ones: asymmetric synthesis of (R)- and (S)-2-alkyl-2-aminopent-4-enoic acids and (2R,3S)-2-amino-2-methy
PubMed:
Synthesis and pharmacological evaluation of enantiomerically pure 4-deoxy-4-fluoromuscarines
PubMed:
Optochemical sensor for an ornidazole assay using 1-amino-4-allyloxyanthraquinone as a fluorescent indicator
PubMed:
Synthesis of ferrocenyl alkenes, dienes, and enynes via samarium diiodide promoted tandem addition and dehydration of ferrocenyl carbonyls with halides
PubMed:
Sequential aza-Baylis-Hillman/ring closing metathesis/aromatization as a novel route for the synthesis of substituted pyrroles
PubMed:
Monoalkylation of C60 and C70 with Zn and active alkyl bromides
PubMed:
Copper-catalysed à-selective allylic alkylation of heteroaryllithium reagents
PubMed:
Synthesis and receptor binding of N-substituted tropane derivatives. High-affinity ligands for the cocaine receptor
PubMed:
[Synthesis and pharmacologic study of 1,5-benzodiazepine-2,4-diones and their alkyl derivatives]
PubMed:
A concise synthetic pathway for trans-metanicotine analogues
PubMed:
New stationary phase for liquid chromatography with chemically bonded pinane ligand: synthesis and characterization by nuclear magnetic resonance and high-performance liquid chromatographic investigations
PubMed:
[Study on the distribution and structure of polyhalides by gas chromatography-mass spectrometry]
PubMed:
Copper-free arylation of 3,3-disubstituted allylic halides with triazene-softened aryl Grignard reagents
PubMed:
Determination of chlorambucil in plasma by GLC with selected-ion monitoring
PubMed:
An electrochemical coupling of organic halide with aldehydes, catalytic in chromium and nickel salts. the Nozaki-Hiyama-Kishi reaction
PubMed:
Highly efficient asymmetric construction of quaternary carbon-containing homoallylic and homopropargylic amines
PubMed:
Stereoselective synthesis of syn and anti 1,2-hydroxyalkyl moieties by Cu-catalyzed asymmetric allylic alkylation
PubMed:
Zn-mediated electrochemical allylation of aldehydes in aqueous ammonia
PubMed:
A simple conductimetric method as an alternative to the colorimetric p-nitrobenzylpyridine test for the measurement of the reactivity of potentially mutagenic alkylating compounds