allyl methacrylate
methacrylic acid, allyl ester
Identification
| Name | allyl methacrylate |
| IUPAC | prop-2-enyl 2-methylprop-2-enoate |
| CAS Number | 96-05-9 |
| EINECS | 202-473-0 |
| FDA UNII | G2IG50653Z |
| Molecular Formula | C7 H10 O2 |
| Molecular Weight | 126.15510000 |
| MDL Number | MFCD00008592 |
| Nikkaji Number | J38.884J |
| Beilstein | 1747406 |
Regulatory
| DG SANTE Food Contact Materials | methacrylic acid, allyl ester |
| FDA Mainterm (IAUFC) | 96-05-9 ; ALLYL METHACRYLATE |
Physical Properties
| Assay | 95.00 to 100.00 |
| Food Chemicals Codex Listed | No |
| Specific Gravity | 0.93800 @ 25.00 °C. |
| Boiling Point | 138.59 °C. @ 760.00 mm Hg (est) |
| Vapor Pressure | 6.682000 mmHg @ 25.00 °C. (est) |
| Flash Point | 93.00 °F. TCC ( 33.89 °C. ) |
| logP (o/w) | 1.567 (est) |
| Soluble in | water, 1470 mg/L @ 25 °C (est) |
No sensory data available
Safety Information
| Preferred SDS | View |
| Oral/Parenteral Toxicity | oral-mouse LD50 57 mg/kg |
| Dermal Toxicity | skin-rabbit LD50 500 uL/kg |
| Inhalation Toxicity | inhalation-mouse LC50 5500 mg/m3 |
GHS Classification
['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']
Safety in Use
| Category | indirect food additives: adhesives and components of coatings |
| IFRA Purity Specification | < 0.1% free allyl alcohol |
| Recommendation for allyl methacrylate usage levels up to | not for fragrance use. |
| Recommendation for allyl methacrylate flavor usage levels up to | not for flavor use. |
Potential Uses
Natural Occurrence
Synonyms
allylmethacrylate
methacrylic acid allyl ester
methacrylic acid, allyl ester
methacrylic acid, allyl ester (8CI)
2-
methyl-2-propenoic acid 2-propenyl ester
2-
methyl-2-propenyl methacrylate
prop-2-en-1-yl 2-methylprop-2-enoate
prop-2-enyl 2-methylprop-2-enoate
2-
propenoic acid, 2-methyl-, 2-propen-1-yl ester
2-
propenoic acid, 2-methyl-, 2-propenyl ester
PubMed:
Poly(allyl methacrylate) functionalized hydroxyapatite nanocrystals via the combination of surface-initiated RAFT polymerization and thiol-ene protocol: a potential anticancer drug nanocarrier
PubMed:
Developmental toxicities of methacrylic acid, ethyl methacrylate, n-butyl methacrylate, and allyl methacrylate in rats following inhalation exposure
PubMed:
Enrichment and Distribution of Pb(2+) Ions in Zwitterionic Poly(cysteine methacrylate) Brushes at the Solid-Liquid Interface
PubMed:
Skin sensitization potential of allyl methacrylate in guinea pigs
PubMed:
The effect of heterobifunctional crosslinkers on HEMA hydrogel modulus and toughness
PubMed:
Thermoresponsive amperometric glucose biosensor
PubMed:
Functionalization of Metal Surface via Thiol-Ene Click Chemistry: Synthesis, Adsorption Behavior, and Postfunctionalization of a Catechol- and Allyl-Containing Copolymer
PubMed:
Photochemical Synthesis and Versatile Functionalization Method of a Robust Porous Poly(ethylene glycol methacrylate-co-allyl methacrylate) Monolith Dedicated to Radiochemical Separation in a Centrifugal Microfl
PubMed:
Synthesis of an Aqueous Self-Matting Acrylic Resin with Low Gloss and High Transparency via Controlling Surface Morphology
PubMed:
Dye-Loaded Mechanochromic and pH-Responsive Elastomeric Opal Films
PubMed:
Chemoselective Polymerization of Polar Divinyl Monomers with Rare-Earth/Phosphine Lewis Pairs
PubMed:
Novel Anti-Biofouling Soft Contact Lens: l-Cysteine Conjugated Amphiphilic Conetworks via RAFT and Thiol-Ene Click Chemistry
PubMed:
Subchronic dermal toxicity study of allyl methacrylate in rabbits
PubMed:
Functional-Polymer Library through Post-Polymerization Modification of Copolymers Having Oleate and Pentafluorophenyl Pendants
PubMed:
Chemoselective, Stereospecific, and Living Polymerization of Polar Divinyl Monomers by Chiral Zirconocenium Catalysts
PubMed:
Preparation and evaluation of a contact lens vehicle for puerarin delivery
PubMed:
Functionalised polysiloxanes as injectable, in situ curable accommodating intraocular lenses
PubMed:
Towards a functional radiopaque hydrogel for nucleus pulposus replacement
PubMed:
Prediction of the reduced glutathione (GSH) reactivity of dental methacrylate monomers using NMR spectra - Relationship between toxicity and GSH reactivity
PubMed:
'Clickable' hydrogels for all: facile fabrication and functionalization
PubMed:
A decontamination system for chemical weapons agents using a liquid solution on a solid sorbent
PubMed:
Facile Preparation of Crosslinked PAN Membranes Based on Thiol-Ene Photopolymerization
PubMed:
Study of pH-responsive microgels containing methacrylic acid: effects of particle composition and added calcium
PubMed:
[Irritation and allergy to acrylates and methacrylates. - Part I: Common monoacrylates and monomethacrylates (author's transl)]
PubMed:
Combination of Surface Initiated Reversible Addition Fragmentation Chain Transfer Polymerization, Thiol-Ene Click Chemistry and Coordination Chemistry for the Fabrication of a Novel Photoluminescent Hydroxyapat
PubMed:
Robust Cross-Linked Stereocomplexes and C60 Inclusion Complexes of Vinyl-Functionalized Stereoregular Polymers Derived from Chemo/Stereoselective Coordination Polymerization
PubMed:
Some new methods for affixing sections to glass slides. II. Organic-solvent based adhesives
PubMed:
Synthesis of a mesoporous functional copolymer bead carrier and its properties for glucoamylase immobilization
PubMed:
Inverse microemulsion polymerization of sterically stabilized polyampholyte microgels
PubMed:
Glutathione depletion in rat hepatocytes: a mixture toxicity study with alpha, beta-unsaturated esters