alpha-chloralose

1,2-O-(2,2,2-trichloroethylidene)-alpha-D-glucofuranose

CAS: 15879-93-3 C8 H11 Cl3 O6 MW: 309.52687000

Identification

Namealpha-chloralose
IUPAC1-[(2R,5R,6S,6aR)-6-hydroxy-2-(trichloromethyl)-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl]ethane-1,2-diol
CAS Number15879-93-3
EINECS240-016-7
FDA UNII238BZ29MUE
Molecular FormulaC8 H11 Cl3 O6
Molecular Weight309.52687000
MDL NumberMFCD00005542
Beilstein0085418
XlogP31.00 (est)

Regulatory

Physical Properties

Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Melting Point 182.00 °C. @ 760.00 mm Hg
Boiling Point 504.41 °C. @ 760.00 mm Hg (est)
Flash Point 498.00 °F. TCC ( 258.90 °C. ) (est)
logP (o/w) 1.020
Soluble in water, 4440 mg/L @ 15 °C (exp)

No sensory data available

Safety Information

Preferred SDSView
Oral/Parenteral Toxicityoral-bird - wild LD50 9 mg/kg
Dermal Toxicitysubcutaneous-rat LDLo 200 mg/kg
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryherbicides / pesticides
Recommendation for alpha-chloralose usage levels up tonot for fragrance use.
Recommendation for alpha-chloralose flavor usage levels up tonot for flavor use.

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Potential Uses

None Found

Natural Occurrence

not found in nature

Synonyms

anhydroglucochloral (R)-1-((2R,3aR,5R,6S,6aR)-6- hydroxy-2-(trichloromethyl)tetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethane-1,2-diol 1,2-O-(2,2,2- trichloroethylidene)-alpha-D-glucofuranose 1-[(2R,5R,6S,6aR)-6-hydroxy-2-( trichloromethyl)-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl]ethane-1,2-diol PubMed: Hyponeophagia: a measure of anxiety in the mouse. PubMed: On the use of α-chloralose for repeated BOLD fMRI measurements in rats. PubMed: Acute inhibition of the hypothalamic paraventricular nucleus decreases renal sympathetic nerve activity and arterial blood pressure in water-deprived rats. PubMed: Alpha-chloralose immobilization of rock doves in Ohio. PubMed: Isolation of bilobalide and ginkgolide A from Ginkgo biloba L. shorten the sleeping time induced in mice by anesthetics. PubMed: Adrenal sympathetic efferent nerve and catecholamine secretion excitation caused by capsaicin in rats. PubMed: Effect of capsaicin pretreatment on capsaicin-induced catecholamine secretion from the adrenal medulla in rats. PubMed: The effects of chronic two-fold dietary vitamin E supplementation on subarachnoid hemorrhage-induced brain hypoperfusion.