benzyl disulfide

dibenzyl disulfide

CAS: 150-60-7 C14 H14 S2 MW: 246.39558000 smoky

Identification

Namebenzyl disulfide
IUPACbenzyldisulfanylmethylbenzene
CAS Number150-60-7
EINECS205-764-0
FDA UNIIBG7680605N
Molecular FormulaC14 H14 S2
Molecular Weight246.39558000
MDL NumberMFCD00004783
Nikkaji NumberJ60.275B
Beilstein1110443

Regulatory

JECFA Food Flavoring579 benzyl disulfide
DG SANTE Food Flavourings12.081 dibenzyl disulfide
FEMA Number3617
FDANo longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF)150-60-7 ; BENZYL DISULFIDE
FDA RegulationFDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION

Physical Properties

Appearance pale yellow crystalline leaflet (est)
Assay 98.00 to 100.00
Food Chemicals Codex Listed No
Melting Point 71.00 to 73.00 °C. @ 760.00 mm Hg
Boiling Point 270.00 °C. @ 760.00 mm Hg
Vapor Pressure 0.000020 mmHg @ 25.00 °C. (est)
Flash Point 423.00 °F. TCC ( 217.20 °C. ) (est)
logP (o/w) 4.951 (est)
Soluble in ether, hot
Similar Items note

Organoleptic Properties

Odor Description at 0.10 % in propylene glycol.

Safety Information

Preferred SDSView
European informationMost important hazard(s):
Oral/Parenteral ToxicityNot determined
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavoring agents
Recommendation for benzyl disulfide usage levels up tonot for fragrance use.
Maximised Survey-derived Daily Intakes (MSDI-EU)0.012 (μg/capita/day)
Structure ClassII
baked goods-
beverages(nonalcoholic)-
beverages(alcoholic)-
breakfast cereal-
cheese-
chewing gum-
condiments / relishes-
confectionery froastings-
egg products-
fats / oils-
fish products-
frozen dairy-
fruit ices-
gelatins / puddings-
granulated sugar-
gravies-
hard candy-
imitation dairy-
instant coffee / tea-
jams / jellies-
meat products-
milk products-
nut products-
other grains-
poultry-
processed fruits-
processed vegetables-
reconstituted vegetables-
seasonings / flavors-
snack foods-
soft candy-
soups-
sugar substitutes-
sweet sauces-

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Potential Uses

FL caramel FL smoke

Natural Occurrence

cocoa roasted cocoa onion

Synonyms

benzyl disulphide alpha-( benzyl dithio) toluene alpha- benzyl dithiotoluene benzyldisulfanylmethylbenzene a-( benzyldithio)toluene di(phenyl methyl) disulfide di(phenylmethyl) disulfide di(phenylmethyl)disulfide dibenzyl disulfide dibenzyl disulphide dibenzyldisulfide diphenyl methyl disulfide 1,4- diphenyl-1,2,3-dithiobutane 1,4- diphenyl-2,3-dithiabutane 1,4- diphenyl-2,3-dithiobutane diphenylmethyl disulfide 1,1'-[ disulfanediylbis(methylene)]dibenzene 1,1'-( disulfanediyldimethanediyl)dibenzene disulfide, bis(phenylmethyl) disulfide, dibenzyl 1,1'-[ dithiobis(methylene)]dibenzene bis( phenyl methyl) disulfide bis( phenylmethyl) disulfide phenylmethyldisulfanylmethylbenzene PubMed: Sulfur-doped porous reduced graphene oxide hollow nanosphere frameworks as metal-free electrocatalysts for oxygen reduction reaction and as supercapacitor electrode materials. PubMed: Organometallic synthesis, structure determination, shape evolution, and formation mechanism of hexapod-like ternary PbSe(x)S(1-x) nanostructures with tunable compositions. PubMed: A Petiveria alliacea standardized fraction induces breast adenocarcinoma cell death by modulating glycolytic metabolism. PubMed: Fluxional cyclic seleninate ester: NMR and computational studies, glutathione peroxidase-like behavior, and unexpected rearrangement. PubMed: Simultaneous liquid-liquid extraction of dibenzyl disulfide, 2,6-di-tert-butyl-p-cresol, and 1,2,3-benzotriazole from power transformer oil prior to GC and HPLC determination. PubMed: Functional groups and sulfur K-edge XANES spectra: divalent sulfur and disulfides. PubMed: A fragment-based approach to probing adenosine recognition sites by using dynamic combinatorial chemistry. PubMed: [Determination of bis (p-fluorobenzyl) trisulfide and bis (p-fluoro-benzyl) disulfide in lungs of rat by HPLC]. PubMed: Antioxidant activity of the new thiosulfinate derivative, S-benzyl phenylmethanethiosulfinate, from Petiveria alliacea L. PubMed: Patch testing with components of water-based metalworking fluids: results of a multicentre study with a second series. PubMed: Aromatic derivatives and tellurium analogues of cyclic seleninate esters and spirodioxyselenuranes that act as glutathione peroxidase mimetics. PubMed: Synthesis of radioiodine labeled dibenzyl disulfide for evaluation of tumor cell uptake. PubMed: Diselenides and allyl selenides as glutathione peroxidase mimetics. Remarkable activity of cyclic seleninates produced in situ by the oxidation of allyl omega-hydroxyalkyl selenides. PubMed: Sulfur compounds reduce potato toxins during extrusion cooking. PubMed: Fungal cleavage of thioether bond found in Yperite. PubMed: Degradation of organic sulfur compounds by a coal-solubilizing fungus. PubMed: Acetyl benzyl disulfide. PubMed: Chemical transformation of S-benzyl O-ethyl phenylphosphonothiolate (Inezin) by ultraviolet light. PubMed: Alteration of O,O-dimethyl S-[alpha-(carboethoxy)benzyl] phosphorodithioate (phenthoate) in citrus, water, and upon exposure to air and sunlight. PubMed: Movement and metabolism of S-benzyl O,O-diisopropyl phosphorothiolate (Kitazin P) and O-ethyl S,S-diphenyl phosphorodithiolate (edifenphos) in various types of soils.