chelidonic acid

4-oxo-4H-pyran-2,6-dicarboxylic acid

CAS: 99-32-1 C7 H4 O6 MW: 184.10408000

Identification

Namechelidonic acid
IUPAC4-oxopyran-2,6-dicarboxylic acid
CAS Number99-32-1
EINECS202-749-0
FDA UNIIT33U4W5K6O
Molecular FormulaC7 H4 O6
Molecular Weight184.10408000
MDL NumberMFCD00006577
Nikkaji NumberJ4.968I
Beilstein0163607

Regulatory

Physical Properties

Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Melting Point 262.00 °C. @ 760.00 mm Hg
Boiling Point 471.34 °C. @ 760.00 mm Hg (est)
Flash Point 399.00 °F. TCC ( 204.10 °C. ) (est)
logP (o/w) -0.746 (est)
Soluble in water, 7111 mg/L @ 25 °C (est)

No sensory data available

Safety Information

Preferred SDSView
Oral/Parenteral Toxicityintraperitoneal-mouse LDLo 500 mg/kg
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categorynatural substances and extractives
Recommendation for chelidonic acid usage levels up tonot for fragrance use.
Recommendation for chelidonic acid flavor usage levels up tonot for flavor use.

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Potential Uses

None Found

Natural Occurrence

asparagus corn root corn shoot

Synonyms

chelidonicacid 2,6- dicarboxyl-4-pyrone jerva acid jervaic acid jervasic acid 4-oxo pyran-2,6-dicarboxylic acid 4-oxo-1,4- pyran-2,6-dicarboxylic acid 4-oxo-4H- pyran-2,6-dicarboxylic acid 4H- pyran-2,6-dicarboxylic acid, 4-oxo- PubMed: The therapeutic effect of chelidonic acid on ulcerative colitis. PubMed: Statistically disordered short hydrogen bonds in (pipzH2)(cdoH)2 and a comparison with (pipzH2)(cdo)·H2O (pipz is piperazine and cdoH2 is chelidonic acid). PubMed: Inhibitory effects of chelidonic acid on IL-6 production by blocking NF-κB and caspase-1 in HMC-1 cells. PubMed: Beneficial effects of chelidonic acid on a model of allergic rhinitis. PubMed: Cationic, neutral and anionic metal(II) complexes derived from 4-oxo-4H-pyran-2,6-dicarboxylic acid (chelidonic acid). PubMed: Tracer studies with 13C-labeled carbohydrates in cultured plant cells. Retrobiosynthetic analysis of chelidonic acid biosynthesis. PubMed: An investigation of the irritant and allergenic properties of daffodils (Narcissus pseudonarcissus L., Amaryllidaceae). A review of daffodil dermatitis. PubMed: Chelidonic acid and other conformationally restricted substrate analogues as inhibitors of rat brain glutamate decarboxylase. PubMed: [Reaction of chelidonic acid with o-phenylenediamine]. PubMed: The biosynthesis of chelidonic acid. PubMed: Biosynthesis of chelidonic acid. I. Preliminary observation on the precursors of chelidonic acid in Convallaria majalis L. PubMed: [Reactions with chelidonic acid. 3. On re-arrangements of pyranylidene-carbonic acid derivatives with diamines. 10. Studies on gamma-pyrones]. PubMed: [CONSTITUENTS OF CONVALLARIA. 3. ISOLATION OF CHELIDONIC ACID]. PubMed: [REACTIONS WITH CHELIDONIC ACID. II. 9. ON STUDIES ON GAMMA-PYRONES]. PubMed: Dissociation constants of certain gamma-pyrone dicarboxylic acids. Meconic acid and chelidonic acid. PubMed: [Possible analytical determination of chelidonic acid in vegetable material]. PubMed: [Occurrence and distribution of chelidonic acid in various plant families]. PubMed: [Tannic acid microreactions of meconic acid alkaloids of opium and of chelidonic acid celandine alkaloids; their differentiation and application].