dehydroxylinalool oxide

5-isopropenyl-2-methyl-2-vinyltetrahydrofuran

CAS: 13679-86-2 C10 H16 O MW: 152.23672000 herbal woody

Identification

Namedehydroxylinalool oxide
IUPAC2-ethenyl-2-methyl-5-prop-1-en-2-yloxolane
CAS Number13679-86-2
EINECS237-184-9
FDA UNIIF2S8JZM40P
Molecular FormulaC10 H16 O
Molecular Weight152.23672000
MDL NumberMFCD00065422
Nikkaji NumberJ277.988I
CoE Number11944

Regulatory

JECFA Food Flavoring1455 5-isopropenyl-2-methyl-2-vinyltetrahydrofuran
DG SANTE Food Flavourings13.097 anhydrolinalool oxide (5)
FEMA Number3759
FDANo longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF)13679-86-2 ; 5-ISOPROPENYL-2-METHYL-2-VINYLTETRAHYDROFURAN

Physical Properties

Appearance colorless clear liquid (est)
Assay 97.00 to 100.00 sum of isomers
Food Chemicals Codex Listed No
Specific Gravity 0.87400 to 0.87800 @ 25.00 °C.
Pounds per Gallon - (est). 7.273 to 7.306
Refractive Index 1.44900 to 1.45400 @ 20.00 °C.
Boiling Point 167.00 to 168.00 °C. @ 760.00 mm Hg, 70.00 °C. @ 23.00 mm Hg
Acid Value 2.00 max. KOH/g
Vapor Pressure 13.400000 mmHg @ 25.00 °C.
Vapor Density >1 ( Air = 1 )
Flash Point 115.00 °F. TCC ( 46.11 °C. )
logP (o/w) 2.929 (est)
Soluble in alcohol
Insoluble in water

Cosmetic Information

CosIngcosmetic data
Cosmetic Usesperfuming agents

Organoleptic Properties

Odor Strength medium
Substantivity > 4 hour(s) at 100.00 %
Odor Description
at 100.00 %.
Green, cooling spice, herbaceous, with a terpy and minty nuance
A green, cooling, spicy, herbaceous odor with a mint nuance
Odor sample from Dragoco Inc.
Taste Description
Woody, piney, spicy, minty with a green citrus nuance
Lemon/lime character similar to lemon/lime carbonated soft drink, with green bean aftertaste

Safety Information

Preferred SDSView
European informationMost important hazard(s):
Oral/Parenteral Toxicityoral-mouse LD50 1000 - 2000 mg/kg
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavor and fragrance agents
RIFM Fragrance Material Safety AssessmentSearch
Recommendation for dehydroxylinalool oxide usage levels up to5.0000 % in the fragrance concentrate.
Maximised Survey-derived Daily Intakes (MSDI-EU)0.90 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA)0.03 (μg/capita/day)
Structure ClassII
baked goods-
beverages(nonalcoholic)-
beverages(alcoholic)-
breakfast cereal-
cheese-
chewing gum-
condiments / relishes-
confectionery froastings-
egg products-
fats / oils-
fish products-
frozen dairy-
fruit ices-
gelatins / puddings-
granulated sugar-
gravies-
hard candy-
imitation dairy-
instant coffee / tea-
jams / jellies-
meat products-
milk products-
nut products-
other grains-
poultry-
processed fruits-
processed vegetables-
reconstituted vegetables-
seasonings / flavors-
snack foods-
soft candy-
soups-
sugar substitutes-
sweet sauces-

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Potential Uses

FR aldehydic FR berry FR berry FR blueberry FR citrus FR eucalyptus oil replacer FR grape FR green FR herbal FR lime FR mango FR mint FR pepper FR pine FR spice FL tea topnotes FL tropical FR woody

Natural Occurrence

brandy PMC buchu oil cherimoya coffee PMC coriander oil grape muscat grape juice PMC grapefruit juice honey PMC loganberry fruit osmanthus papaya fruit passion fruit petitgrain oil @ 0.10% Data sage clary sage sage clary sage wine white wine PMC

Synonyms

anhydrolinalool oxide anhydrolinalool oxide (5) dehydroxy linalool oxide dehydroxylinalool oxide desoxide 2- ethenyl tetrahydro-2-methyl-5-(1-methyl ethenyl) furan 2- ethenyl-2-methyl-5-(1-methyl ethenyl) tetrahydrofuran 2- ethenyl-2-methyl-5-(1-methylethenyl)tetrahydrofuran 2- ethenyl-2-methyl-5-(prop-1-en-2-yl)tetrahydrofuran 2- ethenyl-2-methyl-5-prop-1-en-2-yloxolane 2- ethenyltetrahydro-2-methyl-5-(1-methylethenyl)furan furan, 2-ethenyltetrahydro-2-methyl-5-(1-methylethenyl)- furan, tetrahydro-5-isopropenyl-2-methyl-2-vinyl- herboxide 2- methyl-2-vinyl-5-isopropenyl tetrahydrofuran 2- methyl-2-vinyl-5-isopropenyltetrahydrofuran 2- methyl-5-(prop-1-en-2-yl)-2-vinyltetrahydrofuran 5-iso prenyl-2-methyl-2-vinyl tetrahydrofurane 5-iso prenyl-2-methyl-2-vinyltetrahydrofurane 5-iso propenyl-2-methyl-2-vinyl tetrahydrofuran 5-iso propenyl-2-methyl-2-vinyltetrahydrofuran 2-iso propenyl-5-methyl-5-vinyltetrahydrofuran tetrahydro-5-isopropenyl-2-methyl-2-vinyl furan tetrahydro-5-isopropenyl-2-methyl-2-vinylfuran Try the PubMed Search.