harmaline

1-methyl-7-methoxy-3,4-dihydro-b-carboline

CAS: 304-21-2 C13 H14 N2 O MW: 214.26778000

Identification

Nameharmaline
IUPAC7-methoxy-1-methyl-3,4-dihydro-2H-pyrido[3,4-b]indole
CAS Number304-21-2
EINECS206-152-6
FDA UNIICN58I4TOET
Molecular FormulaC13 H14 N2 O
Molecular Weight214.26778000
MDL NumberMFCD00004955
Nikkaji NumberJ11.607F
Beilstein0207310

Regulatory

Physical Properties

Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Melting Point 239.00 to 241.00 °C. @ 760.00 mm Hg
Boiling Point 426.42 °C. @ 760.00 mm Hg (est)
Flash Point 413.00 °F. TCC ( 211.70 °C. ) (est)
logP (o/w) 2.251 (est)
Soluble in water, 4.051 mg/L @ 25 °C (est)

No sensory data available

Safety Information

Preferred SDSView
Oral/Parenteral Toxicityintravenous-rabbit LDLo 20 mg/kg
Dermal Toxicitysubcutaneous-mouse LD50 120 mg/kg
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categorynatural substances and extractives
Recommendation for harmaline usage levels up tonot for fragrance use.
Recommendation for harmaline flavor usage levels up tonot for flavor use.

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Potential Uses

None Found

Natural Occurrence

apricot wild apricot rue wild rue seeds

Synonyms

4,9- dihydro-7-methoxy-1-methyl-3H-pyrido(3,4-b)indole 3,4- dihydro-7-methoxy-1-methyl-9-pyrid(3,4-b)indole 3,4- dihydro-7-methoxy-1-methyl-9-pyrid[3,4-b]indole 3,4- dihydro-7-methoxy-1-methyl-9-pyrido(3,4-b)indole dihydroharmine 3,4- dihydroharmine harmidine harmine, dihydro- 7- methoxy-1-methyl-3,4-dihydro-2H-pyrido[3,4-b]indole 7- methoxy-1-methyl-4,9-dihydro-3H-b-carboline 1- methyl-7-methoxy-3,4-dihydro-b-carboline O- methylharmalol 3H- pyrido(3,4-b)indole, 4,9-dihydro-7-methoxy-1-methyl- 2H- pyrido[3,4-b]indole, 3,4-dihydro-7-methoxy-1-methyl- (9CI) 3H- pyrido[3,4-b]indole, 4, 9-dihydro-7-methoxy-1-methyl- 3H- pyrido[3,4-b]indole, 4,9-dihydro-7-methoxy-1-methyl- PubMed: Inhibition of monoamine oxidase (MAO) by β-carbolines and their interactions in live neuronal (PC12) and liver (HuH-7 and MH1C1) cells. PubMed: Metabolic pathways of the psychotropic-carboline alkaloids, harmaline and harmine, by liquid chromatography/mass spectrometry and NMR spectroscopy. PubMed: Harmaline and harmalol inhibit the carcinogen-activating enzyme CYP1A1 via transcriptional and posttranslational mechanisms. PubMed: Inhibition of the bioactivation of the neurotoxin MPTP by antioxidants, redox agents and monoamine oxidase inhibitors. PubMed: beta-Carboline alkaloids in Peganum harmala and inhibition of human monoamine oxidase (MAO). PubMed: Determination of beta-carboline alkaloids in foods and beverages by high-performance liquid chromatography with electrochemical detection at a glassy carbon electrode modified with carbon nanotubes. PubMed: Toxicological evaluation of the staircase test for assessing fine motor movements. PubMed: Mutagenicities of nitrosated carboline derivatives. PubMed: Food-borne amines and amides as potential precursors of endogenous carcinogens. PubMed: Beta-carbolines, psychoactive compounds in the mammalian body. Part I: Occurrence, origin and metabolism.