isobutyl methacrylate

methacrylic acid, isobutyl ester

CAS: 97-86-9 C8 H14 O2 MW: 142.19798000

Identification

Nameisobutyl methacrylate
IUPAC2-methylpropyl 2-methylprop-2-enoate
CAS Number97-86-9
EINECS202-613-0
FDA UNIIV11534UYZ0
Molecular FormulaC8 H14 O2
Molecular Weight142.19798000
MDL NumberMFCD00008931
Nikkaji NumberJ47.810E
Beilstein1747595
XlogP32.70 (est)

Regulatory

DG SANTE Food Flavourings09.586 methacrylic acid, isobutyl ester
DG SANTE Food Contact Materialsmethacrylic acid, isobutyl ester
FDA Mainterm (IAUFC)97-86-9 ; ISOBUTYL METHACRYLATE

Physical Properties

Appearance colorless clear liquid (est)
Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Specific Gravity 0.88200 to 0.88800 @ 25.00 °C.
Pounds per Gallon - (est). 7.339 to 7.389
Refractive Index 1.40900 to 1.41500 @ 20.00 °C.
Boiling Point 155.00 °C. @ 760.00 mm Hg
Vapor Pressure 3.630000 mmHg @ 25.00 °C.
Vapor Density 3.8 ( Air = 1 )
Flash Point 111.00 °F. TCC ( 43.89 °C. )
logP (o/w) 2.660
Soluble in alcohol
Insoluble in water

Cosmetic Information

CosIngcosmetic data
Cosmetic Usesfilm formers

No sensory data available

Safety Information

Preferred SDSView
European informationMost important hazard(s):
Oral/Parenteral Toxicityoral-mouse LD50 11990 mg/kg
Dermal ToxicityNot determined
Inhalation Toxicityinhalation-mouse LCLo 29740 mg/m3/5H

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryfilm forming agents
Recommendation for isobutyl methacrylate usage levels up tonot for fragrance use.
Maximised Survey-derived Daily Intakes (MSDI-EU)0.012 (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI)3900 (μg/person/day)
Threshold of Concern540 (μg/person/day)
Structure ClassII
Dairy products, excluding products of category 02.0 (01.0)7.00000
Fats and oils, and fat emulsions (type water-in-oil) (02.0)5.00000
Edible ices, including sherbet and sorbet (03.0)10.00000
Processed fruit (04.1)7.00000
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2)-
Confectionery (05.0)10.00000
Chewing gum (05.3)-
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0)5.00000
Bakery wares (07.0)10.00000
Meat and meat products, including poultry and game (08.0)2.00000
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0)2.00000
Eggs and egg products (10.0)-
Sweeteners, including honey (11.0)-
Salts, spices, soups, sauces, salads, protein products, etc. (12.0)5.00000
Foodstuffs intended for particular nutritional uses (13.0)10.00000
Non-alcoholic ("soft") beverages, excl. dairy products (14.1)5.00000
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2)10.00000
Ready-to-eat savouries (15.0)20.00000
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0)5.00000

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Potential Uses

film formers

Natural Occurrence

chamomile flower oil roman @ 0.33% Data

Synonyms

iso butyl 2-methyl prop-2-enoate iso butyl 2-methyl-2-propenoate iso butyl 2-methylacrylate iso butyl 2-methylprop-2-enoate iso butyl alpha-methacrylate iso butyl methacrylate, inhibited [UN2283] [Flammable liquid] methacrylic acid isobutyl ester methacrylic acid, isobutyl ester 2- methyl-2-propenoic acid 2-methyl ester 2- methylpropyl 2-methyl-2-propenoate 2- methylpropyl 2-methylprop-2-enoate 2- methylpropyl 2-methylpropenoate 2- methylpropyl methacrylate 2- propenoic acid, 2-methyl-, 2-methylpropyl ester propenoic acid, 2-methyl, isobutyl ester PubMed: Assessment of the skin sensitising potency of the lower alkyl methacrylate esters. PubMed: Investigation of bonding properties of denture bases to silicone-based soft denture liner immersed in isobutyl methacrylate and 2-hydroxyethyl methacrylate. PubMed: Cytotoxicity of monomers, plasticizer and degradation by-products released from dental hard chairside reline resins. PubMed: Direct patterning of intrinsically electron beam sensitive polymer brushes. PubMed: Chain end distribution of block copolymer in two-dimensional microphase-separated structure studied by scanning near-field optical microscopy. PubMed: Conformation of single block copolymer chain in two-dimensional microphase-separated structure studied by scanning near-field optical microscopy. PubMed: Optical CO(2) sensor of the combination of colorimetric change of alpha-naphtholphthalein in poly(isobutyl methacrylate) and fluorescent porphyrin in polystyrene. PubMed: Effect of molecular mobility of polymeric implants on soft tissue reactions: an in vivo study in rats. PubMed: Self-assembled treelike patterns from an evaporating binary solution. PubMed: Fabrication of hydroxyapatite-poly(epsilon-caprolactone) scaffolds by a combination of the extrusion and bi-axial lamination processes. PubMed: Final report of the safety assessment of methacrylate ester monomers used in nail enhancement products. PubMed: Development and application of methods for determination of residual monomer in dental acrylic resins using high performance liquid chromatography. PubMed: Cytotoxic effects of dental resin liquids on primary gingival fibroblasts and periodontal ligament cells in vitro. PubMed: Confinement and processing effects on glass transition temperature and physical aging in ultrathin polymer films: novel fluorescence measurements. PubMed: Bonding strength between a hard chairside reline resin and a denture base material as influenced by surface treatment. PubMed: Reinforcement of acrylic resins for provisional fixed restorations. Part I: Mechanical properties. PubMed: A denture base resin with low water absorption. PubMed: Carbohydrate-specific cell adhesion directly to glycosphingolipids separated on thin-layer chromatography plates. PubMed: The mechanism of interaction between chlorhexidine digluconate and poly(2-hydroxyethyl methacrylate). PubMed: PRESERVATION OF BIOLOGICAL SPECIMENS WITH ISOBUTYL METHACRYLATE POLYMER. PubMed: EVALUATION OF ISOBUTYL METHACRYLATE POLYMER AS A MOUNTING MEDIUM. PubMed: ISOBUTYL METHACRYLATE AS A MOUNTING MEDIUM FOR HISTOLOGICAL PREPARATIONS. PubMed: A PLASTIC COVER GLASS, ISOBUTYL METHACRYLATE.