isopropenyl acetate

prop-1-en-2-yl acetate

CAS: 108-22-5 C5 H8 O2 MW: 100.11716000 fruity ethereal

Identification

Nameisopropenyl acetate
IUPACprop-1-en-2-yl acetate
CAS Number108-22-5
EINECS203-562-7
FDA UNII4AR9LAS337
Molecular FormulaC5 H8 O2
Molecular Weight100.11716000
MDL NumberMFCD00008709
Nikkaji NumberJ35.907F
Beilstein1280347

Regulatory

JECFA Food Flavoring1835 isopropenyl acetate
DG SANTE Food Flavourings09.822 isopropenyl acetate
FEMA Number4152
FDANo longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF)108-22-5 ; ISOPROPENYL ACETATE

Physical Properties

Appearance colorless to pale yellow clear liquid (est)
Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Specific Gravity 0.91700 to 0.92300 @ 25.00 °C.
Pounds per Gallon - (est). 7.630 to 7.680
Refractive Index 1.39700 to 1.40300 @ 20.00 °C.
Boiling Point 94.00 to 95.00 °C. @ 760.00 mm Hg
Vapor Pressure 42.505001 mmHg @ 25.00 °C. (est)
Flash Point 66.00 °F. TCC ( 18.89 °C. )
logP (o/w) 1.048 (est)
Soluble in alcohol
Insoluble in water

Organoleptic Properties

Odor Strength medium ,
Substantivity < 1 hour(s) at 100.00 %
Odor Description at 100.00 %.
Odor sample from Sigma-Aldrich
Taste Description at 25.00 ppm in water.

Safety Information

Preferred SDSView
European informationMost important hazard(s):
Oral/Parenteral Toxicityoral-rat LD50 3000 mg/kg
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavor and fragrance agents
RIFM Fragrance Material Safety AssessmentSearch
Recommendation for isopropenyl acetate usage levels up to0.1000 % in the fragrance concentrate.
Maximised Survey-derived Daily Intakes (MSDI-EU)0.012 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA)19.00 (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI)2300 (μg/person/day)
Threshold of Concern1800 (μg/person/day)
Structure ClassI
baked goods10.00000
beverages(nonalcoholic)5.00000
beverages(alcoholic)-
breakfast cereal5.00000
cheese7.00000
chewing gum-
condiments / relishes5.00000
confectionery froastings10.00000
egg products-
fats / oils5.00000
fish products2.00000
frozen dairy7.00000
fruit ices10.00000
gelatins / puddings5.00000
granulated sugar-
gravies20.00000
hard candy-
imitation dairy7.00000
instant coffee / tea-
jams / jellies5.00000
meat products2.00000
milk products7.00000
nut products-
other grains5.00000
poultry2.00000
processed fruits7.00000
processed vegetables-
reconstituted vegetables-
seasonings / flavors5.00000
snack foods10.00000
soft candy-
soups5.00000
sugar substitutes-
sweet sauces5.00000
Dairy products, excluding products of category 02.0 (01.0)7.00000
Fats and oils, and fat emulsions (type water-in-oil) (02.0)5.00000
Edible ices, including sherbet and sorbet (03.0)10.00000
Processed fruit (04.1)7.00000
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2)-
Confectionery (05.0)10.00000
Chewing gum (05.3)-
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0)5.00000
Bakery wares (07.0)10.00000
Meat and meat products, including poultry and game (08.0)2.00000
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0)2.00000
Eggs and egg products (10.0)-
Sweeteners, including honey (11.0)-
Salts, spices, soups, sauces, salads, protein products, etc. (12.0)5.00000
Foodstuffs intended for particular nutritional uses (13.0)10.00000
Non-alcoholic ("soft") beverages, excl. dairy products (14.1)-
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2)10.00000
Ready-to-eat savouries (15.0)20.00000
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0)5.00000

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Potential Uses

FR berry FL cheese FL fruit tropical fruit FL vegetable

Natural Occurrence

cheese PMC

Synonyms

acetic acid isopropenyl ester acetic acid, isopropenyl ester 1- acetoxy-1-methyl ethylene 1- acetoxy-1-methylethylene 2- acetoxypropene 2- acetoxypropylene 1- methyl vinyl acetate 1- methylethenyl acetate 1- methylvinyl acetate prop-1-en-2-yl acetate iso propen-1-yl acetate 1- propen-2-ol acetate 1- propen-2-ol, acetate 1- propen-2-yl acetate US Patents: 3,931,270 - Process for producing 2-thia substituted 1,4 diones US Patents: 3,958,029 - Novel flavoring compositions and products comprising 2,5-dimethyl-3-thioisovaleryl furan