Identification

Namebenzyl formate
IUPACbenzyl formate
CAS Number104-57-4
EINECS203-214-4
FDA UNII79GJF97O0Y
Molecular FormulaC8 H8 O2
Molecular Weight136.15016000
MDL NumberMFCD00014128
Nikkaji NumberJ53.979A
Beilstein2041319
CoE Number344

Regulatory

JECFA Food Flavoring841 benzyl formate
DG SANTE Food Flavourings09.077 benzyl formate
FEMA Number2145
FDANo longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF)104-57-4 ; BENZYL FORMATE
FDA RegulationFDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION

Physical Properties

Appearance colorless to pale yellow clear liquid (est)
Assay 95.00 to 100.00
Food Chemicals Codex Listed Yes
Specific Gravity 1.08400 to 1.09200 @ 25.00 °C., 1.08500 to 1.09300 @ 20.00 °C.
Pounds per Gallon - (est). 9.020 to 9.087
Pounds per Gallon - est. 9.039 to 9.105
Refractive Index 1.50900 to 1.51400 @ 20.00 °C.
Boiling Point 202.00 to 203.00 °C. @ 760.00 mm Hg
Acid Value 1.00 max. KOH/g
Vapor Pressure 0.273000 mmHg @ 25.00 °C. (est)
Flash Point 180.00 °F. TCC ( 82.22 °C. )
logP (o/w) 1.363 (est)
Shelf Life 24.00 month(s) or longer if stored properly.
Storage store in cool, dry place in tightly sealed containers, protected from heat and light.
Soluble in alcohol
Similar Items note

Cosmetic Information

CosIngcosmetic data
Cosmetic Usesperfuming agents

Organoleptic Properties

Odor Strength medium
Substantivity 8 hour(s) at 100.00 %
Odor Description
at 100.00 %.
Chemical with a cherry fruity almond nuance
strong, floral, jasmine-like, black tea, fruity, blackberry
apricot; meaty; floral; fruity; pineapple; sweet.
sweet, fruity; rasp- and blueberry-like
Odor sample from Harrmann & Reimer Corporation
Taste Description
at 10.00 ppm.
sweet, fruity, raspberry, blueberry
fresh cherry berry strawberry fruity
fruity; raspberry, blueberry nuance

Safety Information

Preferred SDSView
European informationMost important hazard(s):
Human Experience10 % solution: no irritation or sensitization.
Oral/Parenteral Toxicityoral-rat LD50 1400 mg/kg
Dermal Toxicityskin-rabbit LD50 2000 mg/kg
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavor and fragrance agents
RIFM Fragrance Material Safety AssessmentSearch
Recommendation for benzyl formate usage levels up to1.0000 % in the fragrance concentrate.
Maximised Survey-derived Daily Intakes (MSDI-EU)35.00 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA)17000.00 (μg/capita/day)
Structure ClassI
baked goods-
beverages(nonalcoholic)-
beverages(alcoholic)-
breakfast cereal-
cheese-
chewing gum-
condiments / relishes-
confectionery froastings-
egg products-
fats / oils-
fish products-
frozen dairy-
fruit ices-
gelatins / puddings-
granulated sugar-
gravies-
hard candy-
imitation dairy-
instant coffee / tea-
jams / jellies-
meat products-
milk products-
nut products-
other grains-
poultry-
processed fruits-
processed vegetables-
reconstituted vegetables-
seasonings / flavors-
snack foods-
soft candy-
soups-
sugar substitutes-
sweet sauces-

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Potential Uses

FR aldehydic FR apple FR apricot FR balsam FR cherry FR cinnamon FR cranberry FR grape FR heliotrope FR jasmin FR jonesia FR orange FR pineapple FR plum FR prune FR quince FR raspberry FR rose FR strawberry FR tuberose FR woodruff

Natural Occurrence

champaca concrete @ 0.10% Data chestnut horse-chestnut coffee PMC cranberry fruit lily amazon water lily oregon grape-holly osmanthus absolute @ 0.02% Data rosa rugosa oil tea

Synonyms

ameisensaeurebenzylester benzyl alcohol formate benzyl alcohol, formate benzyl formate FCC benzyl formate natural benzyl methanoate formic acid (phenylmethyl) ester formic acid benzyl ester formic acid phenyl methyl ester formic acid phenylmethyl ester formic acid, benzyl ester formic acid, phenylmethyl ester phenyl methyl formate phenylmethyl formate phenylmethyl) methanoate PubMed: Determination of the 18O content of formic acid as benzyl formate.