methyl magnesium chloride

chloro(methyl)magnesium

CAS: 676-58-4 C H3 Cl Mg MW: 74.79191000

Identification

Namemethyl magnesium chloride
IUPACmagnesium;carbanide;chloride
CAS Number676-58-4
EINECS211-629-7
FDA UNIIM5E1132G4W
Molecular FormulaC H3 Cl Mg
Molecular Weight74.79191000
MDL NumberMFCD00000468

Regulatory

Physical Properties

Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Specific Gravity 1.01300 @ 25.00 °C.
Flash Point 1.00 °F. TCC ( -17.22 °C. )
Soluble in water, 7.598e+004 mg/L @ 25 °C (est)

No sensory data available

Safety Information

Preferred SDSView
Oral/Parenteral ToxicityNot determined
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryinformation only not used for fragrances or flavors
Recommendation for methyl magnesium chloride usage levels up tonot for fragrance use.
Recommendation for methyl magnesium chloride flavor usage levels up tonot for flavor use.

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Potential Uses

None Found

Natural Occurrence

not found in nature

Synonyms

chloro(methyl)magnesium chloromethylmagnesium magnesium, chloromethyl- magnesium;carbanide;chloride methylmagnesium chloride US Patents: 7,927,643 - Compositions of oxo-terpene derivatives and process for preparing the same PubMed: Validation of methane measurement using headspace-GC-MS and quantification by a stable isotope-labeled internal standard generated in situ. PubMed: Chemoselective quantum control of carbonyl bonds in Grignard reactions using shaped laser pulses. PubMed: Development of an automated modular system for the synthesis of [11C]acetate. PubMed: C-F bond-cleavage reactions of fluoroalkanes with magnesium reagents and without metal catalysts. PubMed: A simple Tracerlab module modification for automated on-column [11C]methylation and [11C]carboxylation. PubMed: Synthesis of a naphthyridone p38 MAP kinase inhibitor. PubMed: Air-assisted addition of grignard reagents to olefins. A simple protocol for a three-component coupling process yielding alcohols. PubMed: Synthesis of 1-tert-butyl-4-chloropiperidine: generation of an N-tert-butyl group by the reaction of a dimethyliminium salt with methylmagnesium chloride. PubMed: Accurate determinations of the extent to which the SE2' reactions of allyl-, allenyl- and propargylsilanes are stereospecifically anti. PubMed: An efficient synthesis of 2-substituted 6-methylpurine bases and nucleosides by Fe- or Pd-catalyzed cross-coupling reactions of 2,6-dichloropurines. PubMed: A computational study on addition of Grignard reagents to carbonyl compounds. PubMed: An improvement of 11C acetate synthesis--non-radioactive contaminants by irradiation-induced species emanating from the 11C carbon dioxide production target. PubMed: Synthesis, structural characterization, and transmetalation reactions of a tetranuclear magnesium silsesquioxane complex. PubMed: A one-step C-linked disaccharide synthesis from carbohydrate allylsilanes and tri-O-acetyl-D-glucal.