palladium(II) acetate

acetic acid, palladium(2+) salt (2:1)

CAS: 3375-31-3 C4 H6 O4 Pd MW: 224.50862000

Identification

Namepalladium(II) acetate
CAS Number3375-31-3
EINECS222-164-4
FDA UNII0LTG3460Y5
Molecular FormulaC4 H6 O4 Pd
Molecular Weight224.50862000
MDL NumberMFCD00012453
Nikkaji NumberJ10.642I
Beilstein6086766

Regulatory

Physical Properties

Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Melting Point 205.00 °C. @ 760.00 mm Hg
Boiling Point 117.10 °C. @ 760.00 mm Hg (est)
Vapor Pressure 13.900000 mmHg @ 25.00 °C. (est)
Flash Point 104.00 °F. TCC ( 40.00 °C. ) (est)
logP (o/w) -0.285 (est)

No sensory data available

Safety Information

Preferred SDSView
Oral/Parenteral Toxicityoral-mouse LD50 2100 mg/kg
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryfood contact resinous and polymeric coatings
Recommendation for palladium(II) acetate usage levels up tonot for fragrance use.
Recommendation for palladium(II) acetate flavor usage levels up tonot for flavor use.

BOC Sciences

Best of Chemicals Supplier

Quality supplier of research chemicals and biochemicals including inhibitors, building blocks, GMP Products, impurities and metabolites, APIs for Veterinary, Natural Compounds, ADCs, Stem Cell Molecul...

View All Website 1-631-485-4226 account@bocsci.com

TCI AMERICA

Moving Your Chemistry Forward

We continuously strive to advance our technology.

View All Website 1-800-423-8616 Sales-US@TCIchemicals.com;

Potential Uses

None Found

Natural Occurrence

not found in nature

Synonyms

acetic acid palladium(2+) salt (2:1) acetic acid palladium(II) salt acetic acid, palladium(2+) salt (2:1) diacetatopalladium palladium(2+) acetate palladium(2+) diacetate palladous acetate PubMed: Organo-palladium(ii) complexes bearing unsymmetrical N,N,N-pincer ligands: synthesis, structures and oxidatively induced coupling reactions. PubMed: O,N,N-Pincer ligand effects on oxidatively induced carbon-chlorine coupling reactions at palladium. PubMed: Regioselective direct C-3 arylation of imidazo[1,2-a]pyridines with aryl tosylates and mesylates promoted by palladium-phosphine complexes. PubMed: Synthesis and metalation of dimethoxybenziporphyrins, thiabenziporphyrins, and dibenziporphyrins. PubMed: Chiral palladacycle catalysts generated on a single-handed helical polymer skeleton for asymmetric arylative ring opening of 1,4-epoxy-1,4-dihydronaphthalene. PubMed: Mechanochemical C-H bond activation: rapid and regioselective double cyclopalladation monitored by in situ Raman spectroscopy. PubMed: Synthesis and reactivity of carbachlorins and carbaporphyrins. PubMed: ortho-Metallated triphenylphosphine chalcogenide complexes of platinum and palladium: synthesis and catalytic activity. PubMed: Palladium-catalyzed direct C2 arylation of N-substituted indoles with 1-aryltriazenes. PubMed: Facile preparation of Pd nanoparticles supported on single-layer graphene oxide and application for the Suzuki-Miyaura cross-coupling reaction. PubMed: Synthesis of an adj-dicarbaporphyrin and the formation of an unprecedented tripalladium sandwich complex. PubMed: Synthesis, structural characterization, aromatic characteristics, and metalation of neo-confused porphyrins, a newly discovered class of porphyrin isomers. PubMed: Synthesis, crystal structure, fluorescence and electrochemical studies of a new tridentate Schiff base ligand and its nickel(II) and palladium(II) complexes. PubMed: Synthesis of multi-substituted pyrroles using enamides and alkynes catalyzed by Pd(OAc)2 with molecular oxygen as an oxidant. PubMed: 6-Oxopyriphlorins. PubMed: Synthesis of dienyl ketones via palladium(II)-catalyzed direct cross-coupling reactions between simple alkenes and vinyl ketones: application to the synthesis of vitamin A1 and bornelone. PubMed: Synthesis of benziporphyrins and heterobenziporphyrins and an assessment of the diatropic characteristics of the protonated species. PubMed: Pd(OAc)2-catalyzed C-H activation/C-O cyclization: mechanism, role of oxidant-probed by density functional theory. PubMed: Palladium(II)-catalyzed synthesis of 2H,3'H-spiro[benzofuran-3,2'-naphthoquinones]. PubMed: 2-Tosyl-2,3,3a,4,9,9a-hexa-hydro-1H-benzo[f]isoindol-1-one. PubMed: C-H functionalization logic enables synthesis of (+)-hongoquercin A and related compounds. PubMed: Microwave assisted Suzuki-Miyaura and Ullmann type homocoupling reactions of 2- and 3-halopyridines using a Pd(OAc)2/benzimidazolium salt and base catalyst system. PubMed: N,N-Chelate-control on the regioselectivity in acetate-assisted C-H activation. PubMed: Grafting control of mainstay terpyridine self-assembled monolayers for the preparation of planar silicon surfaces with variable catalytic loadings. PubMed: Pd(OAc)2 catalyzed direct arylation of electron-deficient arenes without ligands or with monoprotected amino acid assistance. PubMed: Palladium(II) acetate mediated oxidative cyclization of ω-unsaturated α-cyano ketones for facile construction of methylenecyclohexane ring system. PubMed: Theoretical analysis of the mechanism of palladium(II) acetate-catalyzed oxidative Heck coupling of electron-deficient arenes with alkenes: effects of the pyridine-type ancillary ligand and origins of the meta-regioselectivity. PubMed: Palladium-catalyzed hydroacyloxylation of ynamides. PubMed: Palladium-catalyzed synthesis of dibenzophosphole oxides via intramolecular dehydrogenative cyclization. PubMed: Unexpected alkyl group migration in palladium(II) benzocarbaporphyrins. PubMed: Regioselective orthopalladation of (Z)-2-aryl-4-arylidene-5(4H)-oxazolones: scope, kinetico-mechanistic, and density functional theory studies of the C-H bond activation. PubMed: Pyrazole analogues of porphyrins and oxophlorins. PubMed: Ethyl 4-acetyl-5-oxo-3-phenyl-hexa-noate. PubMed: Synthesis and antibacterial activity of 2, 3-dehydro-3-O-(3-aryl-E-prop-2-enyl)-10, 11-anhydroclarithromycin derivatives. PubMed: Isostructural Pd(II) and Pt(II) pyrophosphato complexes: polymorphism and unusual bond character in d8-d8 systems. PubMed: Tetrasubstituted furans by Pd(II)/Cu(I)-cocatalyzed three-component domino reactions of 2-(1-alkynyl)-2-alken-1-ones, nucleophiles and diaryliodonium salts. PubMed: Efficient assembly of 1-methylene-1H-indenes via palladium-catalyzed tandem reaction of 1-(2,2-dibromovinyl)-2-alkenylbenzene with arylboronic acid. PubMed: Direct oxidative coupling of benzenes with acrylonitriles to cinnamonitriles catalyzed by Pd(OAc)(2)/HPMoV/O(2) system. PubMed: Alkyne hydroarylation in ionic liquids catalyzed by palladium(II) complexes. PubMed: Controlling the coordination modes of a new and highly flexible ligand bearing two N-heterocyclic carbene moieties at a bipyridine backbone. PubMed: Selective Heck arylation of cyclohexene with homogeneous and heterogeneous palladium catalysts. PubMed: Efficient synthesis of alkyl aryl ketones & ketals via palladium-catalyzed regioselective arylation of vinyl ethers. PubMed: Pd(OAc)(2) catalyzed olefination of highly electron-deficient perfluoroarenes. PubMed: Spontaneous product segregation from reactions in ionic liquids: application in Pd-catalyzed aliphatic alcohol oxidation. PubMed: Synthesis of alpha-cyanocinnamaldehydes from acrylonitrile and benzaldehydes catalyzed by Pd(OAc)(2)/HPMoV/FeCl(3)/O(2) system. PubMed: Palladium(II) acetate catalyzed tandem cycloisomerization and oxidation of arylvinylcyclopropenes using p-benzoquinone as oxidant and pro-nucleophile. PubMed: Cyclometallation of amino-imines on palladium complexes. The effect of the solvent on the experimental and calculated mechanism. PubMed: Synthesis of novel 3,5-dichloro-2-arylpyridines by palladium acetate-catalyzed ligand-free Suzuki reactions in aqueous media. PubMed: 31P NMR study of the stoichiometry, stability and thermodynamics of complex formation between palladium(II) acetate and bis(diphenylphosphino)ferrocene. PubMed: Fluorogenic derivatization of aryl halides based on the formation of biphenyl by Suzuki coupling reaction with phenylboronic acid. PubMed: Efficient syntheses of phosphonylated isochromenes by regioselective 6-endo-dig addition to carbon-carbon triple bond catalyzed by Pd(OAc)2. PubMed: Total synthesis of dehydroaltenuene A. Revision of the structure and total synthesis of dihydroaltenuene B. PubMed: Palladium catalysts supported on mesoporous molecular sieves bearing nitrogen donor groups: preparation and use in Heck and Suzuki C-C bond-forming reactions. PubMed: Dendrimer-encapsulated Pd nanoparticles versus palladium acetate as catalytic precursors in the stille reaction in water. PubMed: Synthesis and reactivity of N-methyl and N-phenyl meso-unsubstituted N-confused porphyrins. PubMed: Palladium(II) complexes of unsymmetrical CNN pincer ligands. PubMed: Palladium(II)-catalyzed direct arylation of enaminones using organotrifluoroborates. PubMed: A general synthesis of diarylketones by means of a three-component cross-coupling of aryl and heteroaryl bromides, carbon monoxide, and boronic acids. PubMed: Stabilized spherical aggregate of palladium nanoparticles prepared by reduction of palladium acetate in octa(3-aminopropyl)octasilsesquioxane as a rigid template. PubMed: Enantiospecific syntheses of copper cubanes, double-stranded copper/palladium helicates, and a (dilithium)-dinickel coronate from enantiomerically pure bis-1,3-diketones--solid-state self-organization towards wirelike copper/palladium strands. PubMed: Synthesis, stability, and complexation behavior of isolable salen-type N2S2 and N2SO ligands based on thiol and oxime functionalities. PubMed: "Click" dendrimers: synthesis, redox sensing of Pd(OAc)2, and remarkable catalytic hydrogenation activity of precise Pd nanoparticles stabilized by 1,2,3-triazole-containing dendrimers. PubMed: Synthesis of substituted furoates from acrylates and aldehydes by Pd(OAc)(2)/HPMoV/CeCl(3)/O(2) system. PubMed: Syntheses and reactivity of meso-unsubstituted azuliporphyrins derived from 6-tert-butyl- and 6-phenylazulene. PubMed: [The synthesis of 2alpha,3alpha-isopropylidenedioxy-6,6-ethylenedioxy-5alpha-androst-15-en-17-one and its 2beta,3beta-isomer]. PubMed: Alkoxy- and amidocarbonylation of functionalised aryl and heteroaryl halides catalysed by a Bedford palladacycle and dppf: a comparison with the primary Pd(II) precursors (PhCN)2PdCl2 and Pd(OAc)2. PubMed: Palladium-catalyzed coupling of allenylphosphonates, phenylallenes, and allenyl esters: remarkable salt effect and routes to novel benzofurans and isocoumarins. PubMed: Remarkably efficient hydrolysis of methylparathion catalyzed by [2-(2-pyridyl)phenyl-C,N]palladium(II) complexes. PubMed: Unexpected roles of molecular sieves in palladium-catalyzed aerobic alcohol oxidation. PubMed: Stereochemical investigations of a novel class of chiral phosphapalladacycle complexes derived from 1-[(2,5-dimethyl)phenyl]ethyldiphenylphosphine. PubMed: Pd-catalyzed silicon hydride reductions of aromatic and aliphatic nitro groups. PubMed: Suzuki-Miyaura cross-coupling of benzylic phosphates with arylboronic acids. PubMed: Non-trivial behavior of palladium(II) acetate. PubMed: Mono- and beta,beta-double-Heck reactions of alpha,beta-unsaturated carbonyl compounds in aqueous media. PubMed: Efficient batch and continuous flow Suzuki cross-coupling reactions under mild conditions, catalysed by polyurea-encapsulated palladium (II) acetate and tetra-n-butylammonium salts. PubMed: Palladium(II) acetate in pyridine as an effective catalyst for highly regioselective hydroselenation of alkynes. PubMed: Diacetato-kappa2O-bis[(S)-1-(4-fluorophenyl)ethylamine-kappaN]palladium(II) and di-mu-acetato-kappa4O:O'-bis[[(S)-2-(1-aminoethyl)-5-fluorophenyl-kappa2C1,N]palladium(II)] benzene hemisolvate. PubMed: Potassium hexacyanoferrate(II)--a new cyanating agent for the palladium-catalyzed cyanation of aryl halides. PubMed: Palladium(II) acetate mediated oxidative cyclization of omega-unsaturated alpha-cyano ketones. A facile methylenecyclopentane annulation process. PubMed: Organometallic chemistry of azuliporphyrins: synthesis, spectroscopy, electrochemistry, and structural characterization of nickel(II), palladium(II), and platinum(II) complexes of azuliporphyrins. PubMed: Transfer hydrogenation using recyclable polyurea-encapsulated palladium: efficient and chemoselective reduction of aryl ketones. PubMed: A modified synthesis of iodoazidoaryl prazosin. PubMed: Organometallic chemistry of carbaporphyrinoids: synthesis and characterization of nickel(II) and palladium(II) azuliporphyrins. PubMed: Polyurea-encapsulated palladium(II) acetate: a robust and recyclable catalyst for use in conventional and supercritical media. PubMed: Encapsulation of palladium in polyurea microcapsules. PubMed: Palladium-imidazolium carbene catalyzed Mizoroki-Heck coupling with aryl diazonium ions. PubMed: Intramolecular palladium(II)-mediated alkoxy carbonylation as a route to functionalized tetrahydropyrans. Synthesis of the C9-C32 segment of phorboxazole A. PubMed: Preparation of vinylogous 2-sulfonylindolines by the palladium-catalyzed heteroannulation of o-iodoanilines with dienyl sulfones and their further transformation to indoles and carbazoles. PubMed: Palladium-imidazolium carbene catalyzed aryl, vinyl, and alkyl Suzuki-Miyaura cross coupling. PubMed: Synthesis of Enantiomerically Pure Cyclopropanes from Cyclopropylboronic Acids. PubMed: Synthesis of Phthalideisoquinoline and Protoberberine Alkaloids and Indolo[2,1-a]isoquinolines in a Divergent Route Involving Palladium(0)-Catalyzed Carbonylation(1). PubMed: Palladium(II) Acetate-Tris(triphenylphosphine)rhodium(I) Chloride: A Novel Catalytic Couple for the Intramolecular Heck Reaction. PubMed: Pd(ii)-hydrotalcite-catalyzed oxidation of alcohols to aldehydes and ketones using atmospheric pressure of air. PubMed: Palladium(II) acetate catalyzed stereoselective C-glycosidation of peracetylated glycals with arylboronic acids. PubMed: Improvements in cross coupling reactions of hypervalent siloxane derivatives. PubMed: Tetrapyrroles as pi Donors: A Pd(2)(2+) Unit Sandwiched between Two Helical Bilindione-Palladium Moieties. PubMed: Novel tetranuclear orthometalated complexes of Pd(II) and Pt(II) derived from p-isopropylbenzaldehyde thiosemicarbazone with cytotoxic activity in cis-DDP resistant tumor cell lines. Interaction of these complexes with DNA. PubMed: Pd.H-C Interactions. Preparation and Structure of Orthometalated Tetranuclear Complexes of Palladium(II) and Platinum(II). PubMed: Synthesis and bioassay of LHRH-antagonists with N-Ac-D-O-phenyltyrosine and N-Ac-D-3-(2-dibenzofuranyl)alanine in position 1. PubMed: Palladium (II)-catalyzed olefin-coupling reactions of kainic acid: effects of substitution on the isopropenyl group on receptor binding.