propargyl alcohol

acetylene carbinol acetylenylcarbinol agrisynth PA ethynyl carbinol ethynylcarbinol 3- hydroxy-1-propyne 1- hydroxy-2-propyne methanol, ethynyl- prop-2-in-1-ol prop-2-yn-1-ol prop-2-yne-1-ol propargylalcohol 2- propyn-1-ol 1- propyn-3-ol 1- propyn-3-yl alcohol 3- propynol propynyl alcohol 2- propynyl alcohol PubMed: trans-Diborylation of Alkynes: pseudo-Intramolecular Strategy utilizing Propargylic Alcohol Unit. PubMed: Total Synthesis of the Biphenyl Alkaloid (-)-Lythranidine. PubMed: EGF Receptor-Targeting Peptide Conjugate Incorporating a Near-IR Fluorescent Dye and a Novel 1,4,7-Triazacyclononane-Based (64)Cu(II) Chelator Assembled via Click Chemistry. PubMed: 6-Triazolyl-6-deoxy-β-cyclodextrin derivatives: synthesis, cellular toxicity, and phase-solubility study. PubMed: Construction of Divergent Fused Heterocycles via an Acid-Promoted Intramolecular ipso-Friedel-Crafts Alkylation of Phenol Derivatives. PubMed: Synthesis of novel 5-(3-alkylquinolin-2-yl)-3-aryl isoxazole derivatives and their cytotoxic activity. PubMed: Tandem Pd/Au-catalyzed route to α-sulfenylated carbonyl compounds from terminal propargylic alcohols and thiols. PubMed: First total synthesis of acetylenic alcohol 15-methyltricosa-2,4-diyne-1, 6-diol (strongylodiol-G) derived from marine sponge. PubMed: Linear propargylic alcohol functionality attached to the indazole-7-carboxamide as a JAK1-specific linear probe group. PubMed: Fluorescence sensor for Cu(II) in the serum sample based on click chemistry. PubMed: Rh(III)-catalyzed coupling of benzamides with propargyl alcohols via hydroarylation-lactonization. PubMed: Increasing the structural span of alkyne metathesis. PubMed: Evaluation of propargyl alcohol toxicity and carcinogenicity in F344/N rats and B6C3F1/N mice following whole-body inhalation exposure. PubMed: Rhodamine-propargylic esters for detection of mitochondrial hydrogen sulfide in living cells. PubMed: Lewis acid catalysis and ligand exchange in the asymmetric binaphthol-catalyzed propargylation of ketones. PubMed: Oxygenation of ruthenium carbene complexes containing naphthothiophene or naphthofuran: spectroscopic and DFT studies. PubMed: Gold meets rhodium: tandem one-pot synthesis of β-disubstituted ketones via Meyer-Schuster rearrangement and asymmetric 1,4-addition. PubMed: Benzyne cycloaddition onto carbon nanohorns. PubMed: Platinum catalysed hydrosilylation of propargylic alcohols. PubMed: New Ag(I)-iminophosphorane coordination polymers as efficient catalysts precursors for the MW-assisted Meyer-Schuster rearrangement of propargylic alcohols in water. PubMed: Lewis acid-catalyzed cyclization of enaminones with propargylic alcohols: regioselective synthesis of multisubstituted 1,2-dihydropyridines. PubMed: Trimerization of β-cyclodextrin through the click reaction. PubMed: Skeletal diversification via heteroatom linkage control: preparation of bicyclic and spirocyclic scaffolds from N-substituted homopropargyl alcohols. PubMed: A novel convenient approach towards pyrrolo[1,2-b]pyridazines through a domino coupling-isomerization-condensation reaction. PubMed: One-pot synthesis of pyrazoles through a four-step cascade sequence. PubMed: Nucleophilic ortho-propargylation of aryl sulfoxides: an interrupted Pummerer/allenyl thio-Claisen rearrangement sequence. PubMed: Hydrophosphination of propargylic alcohols and amines with phosphine boranes. PubMed: Kinetic and dynamic kinetic resolution of secondary alcohols with ionic-surfactant-coated Burkholderia cepacia lipase: substrate scope and enantioselectivity. PubMed: Atom-economical chemoselective synthesis of 1,4-enynes from terminal alkenes and propargylic alcohols catalyzed by Cu(OTf)2. PubMed: Rhodium-catalyzed chemo- and regioselective cross-dimerization of two terminal alkynes. PubMed: Original TDAE strategy using propargylic chloride: rapid access to 1,4-diarylbut-3-ynol derivatives. PubMed: Synthesis of novel 2-alkyl triazole-3-alkyl substituted quinoline derivatives and their cytotoxic activity. PubMed: Catalytic asymmetric enyne addition to aldehdyes and Rh(I)-catalyzed stereoselective domino Pauson-Khand/[4 + 2] cycloaddition. PubMed: Synthesis of 9-alkylated calcitriol and two 1α,25-dihydroxy-9-methylene-10,19-dihydrovitamin D3 analogues with a non-natural triene system by thermal sigmatropic rearrangements. PubMed: Microwave spectroscopic and atoms in molecules theoretical investigations on the Ar···propargyl alcohol complex: Ar···H-O, Ar···π, and Ar···C interactions. PubMed: 1-(2'-Anilinyl)prop-2-yn-1-ol rearrangement for oxindole synthesis. PubMed: Synthesis of indeno[1,2-c]furans via a Pd-catalyzed bicyclization of 2-alkynyliodobenzene and propargylic alcohol. PubMed: Chemoselective synthesis of substituted pyrazoles through AgOTf-catalyzed cascade propargylic substitution-cyclization-aromatization. PubMed: Ruthenium-catalyzed reductive coupling of 1,3-enynes and aldehydes by transfer hydrogenation: anti-diastereoselective carbonyl propargylation. PubMed: Facile synthesis of fully substituted dihydro-β-carbolines via Brønsted acid promoted cascade reactions of α-indolyl propargylic alcohols with nitrones. PubMed: Propargyl hydrazides: synthesis and conversion into pyrazoles through hydroamination. PubMed: Development of Zn-ProPhenol-catalyzed asymmetric alkyne addition: synthesis of chiral propargylic alcohols. PubMed: Ruthenium-catalyzed allylation-cyclization reactions of cyclic 1,3-dicarbonyl compounds with 1-vinyl propargyl alcohols. PubMed: Hypoiodous acid initiated rearrangement of tertiary propargylic alcohols to α-iodoenones. PubMed: A novel fluorescent sensor for mutational p53 DNA sequence detection based on click chemistry. PubMed: Cobalt-mediated synthesis of the tricyclo[5.2.1.0(1,6)]decene framework in solanoeclepin A. PubMed: Regioselective catalytic hydroboration of propargylic species using Cu(I)-NHC complexes. PubMed: Scope and mechanistic analysis of the enantioselective synthesis of allenes by rhodium-catalyzed tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor carbenoids and propargylic alcohols. PubMed: Regioselectivity switch: gold(I)-catalyzed oxidative rearrangement of propargyl alcohols to 1,3-diketones. PubMed: Heteropolyacid-catalyzed direct deoxygenation of propargyl and allyl alcohols. PubMed: Sequential allenylidene/vinylidene cyclization for stereoselective construction of bicyclic carbocycles from propargyl alcohol. PubMed: Kinetic versus thermodynamic stereoselectivity in the hydrostannylation of propargylic alcohol derivatives using AIBN and Et3B as promotors. PubMed: Synthesis of α-allylated α,β-unsaturated carbonyl compounds using vanadium/palladium contemporaneous dual catalysis. PubMed: Enantioselective synthesis of anti- and syn-homopropargyl alcohols via chiral Brønsted acid catalyzed asymmetric allenylboration reactions. PubMed: Highly regioselective synthesis of polysubstituted tetrahydroquinolines by an iodine-induced tandem cyclization reaction from propargylic alcohols and amines. PubMed: Synthesis of electronically modified Ru-based neutral 16 VE allenylidene olefin metathesis precatalysts. PubMed: A gold(I)-catalyzed route to α-sulfenylated carbonyl compounds from propargylic alcohols and aryl thiols. PubMed: Synthesis of a heparan sulfate mimetic library targeting FGF and VEGF via click chemistry on a monosaccharide template. PubMed: Alkyl triazole glycosides (ATGs)--a new class of bio-related surfactants. PubMed: Synthesis of 3,4-dihalogenated furan-2-(5H)-ones by electrophilic cyclization of 4-hydroxy-2-alkynoates. PubMed: Development of a method for the preparation of ruthenium indenylidene-ether olefin metathesis catalysts. PubMed: EXAFS and NRVS reveal a conformational distortion of the FeMo-cofactor in the MoFe nitrogenase propargyl alcohol complex. PubMed: 1,2,3-triazole: unique ligand in promoting iron-catalyzed propargyl alcohol dehydration. PubMed: A convenient approach to β-heteroarylated (C-N bond) ketones from Cs2CO3 promoted reaction between propargyl alcohols and nitrogen-heterocycles. PubMed: Atom-economical synthesis of functionalized cycloalkanes via catalytic redox cycloisomerization of propargyl alcohols. PubMed: Synthesis of allene triazole through iron catalyzed regioselective addition to propargyl alcohols. PubMed: Highly chemoselective calcium-catalyzed propargylic deoxygenation. PubMed: Gold- and silver-catalyzed reactions of propargylic alcohols in the presence of protic additives. PubMed: Cyclization of aromatic propargyl alcohol with a thiophene group yielding naphthothiophene aldehyde induced by a ruthenium complex. PubMed: 1,4-Diazaspiro[2.2]pentanes as a flexible platform for the synthesis of diamine-bearing stereotriads. PubMed: Kinetic resolution of secondary alcohols using amidine-based catalysts. PubMed: Synthesis of tetrasubstituted alkenes through a palladium-catalyzed domino carbopalladation/C-H-activation reaction. PubMed: Brønsted acid catalyzed asymmetric propargylation of aldehydes. PubMed: Convenient synthesis and biological evaluation of modafinil derivatives: benzhydrylsulfanyl and benzhydrylsulfinyl [1,2,3]triazol-4-yl-methyl esters. PubMed: Toxicity of propargylic alcohols on green alga--Pseudokirchneriella subcapitata. PubMed: [Development of environmentally benign transformations via 1,3-transposition of hydroxyl group]. PubMed: Lewis acid-promoted three-component reactions of propargylic alcohols with 2-butynedioates and secondary amines. PubMed: Addition of arylboronic acids to arylpropargyl alcohols en route to indenes and quinolines. PubMed: Lewis acid-catalyzed propargylic etherification and sulfanylation from alcohols in MeNO₂-H₂O. PubMed: Asymmetric synthesis and sensory evaluation of sedanenolide. PubMed: Expeditious entry to novel 2-methylene-2,3-dihydrofuro[3,2-c] chromen-2-ones from 6-chloro-4-hydroxychromen-2-one and propargylic alcohols. PubMed: Applications of propargyl esters of amino acids in solution-phase Peptide synthesis. PubMed: Chiral propargyl alcohols via the enantioselective addition of terminal di- and triynes to aldehydes. PubMed: Intramolecular OH···π interactions in alkenols and alkynols. PubMed: Synthesis of iodo-indoloazepinones in an iodine-mediated three-component domino reaction via a regioselective 7-endo-dig iodo-cyclization pathway. PubMed: Contemporaneous dual catalysis: chemoselective cross-coupling of catalytic vanadium-allenoate and π-allylpalladium intermediates. PubMed: Tandem reaction of propargyl alcohol and N-sulfonylhydrazone: synthesis of dihydropyrazole and its utility in the preparation of 3,3-diarylacrylonitrile. PubMed: S(N)1-type reactions in the presence of water: indium(III)-promoted highly enantioselective organocatalytic propargylation of aldehydes. PubMed: Formal total synthesis of (+)-lysergic acid via zinc(II)-mediated regioselective ring-opening reduction of 2-alkynyl-3-indolyloxirane. PubMed: Preparation of Clickable Poly(3-hydroxyalkanoate) (PHA): Application to Poly(ethylene glycol) (PEG) Graft Copolymers Synthesis. PubMed: Highly selective methods for synthesis of internal (α-) vinylboronates through efficient NHC-Cu-catalyzed hydroboration of terminal alkynes. Utility in chemical synthesis and mechanistic basis for selectivity. PubMed: New quinolin-4-yl-1,2,3-triazoles carrying amides, sulphonamides and amidopiperazines as potential antitubercular agents. PubMed: Synthesis and anti-HIV-1 activity of new fluoro-HEPT analogues: an investigation on fluoro versus hydroxy substituents. PubMed: Propargyl alcohols as β-oxocarbenoid precursors for the ruthenium-catalyzed cyclopropanation of unactivated olefins by redox isomerization. PubMed: Facile oxygenation reactions of ruthenium acetylide complex containing substituted olefinic group. PubMed: Application of Mitsunobu reagents to redox isomerization of CF3-containing propargylic alcohols to (E)-α,β-enones. PubMed: A new and general one-pot synthesis of propargyl alcohols from esters. PubMed: Tandem reaction of propargylic alcohol, sulfonamide, and N-iodosuccinimide: synthesis of N-(2-iodoinden-1-yl)arenesulfonamide. PubMed: A general procedure for the synthesis of enones via gold-catalyzed Meyer-Schuster rearrangement of propargylic alcohols at room temperature. PubMed: Palladium catalyzed bicyclization of 1,8-diiodonaphthalene and tertiary propargylic alcohols to phenalenones and their applications as fluorescent chemosensor for fluoride ions. PubMed: An atom-economical access to β-heteroarylated ketones from propargylic alcohols via tandem ruthenium/indium catalysis. PubMed: Optimization of a ligand immobilization and azide group endcapping concept via "Click-Chemistry" for the preparation of adsorbents for antibody purification. PubMed: Intramolecular Nicholas reactions in the synthesis of dibenzocycloheptanes. Synthesis of allocolchicine NSC 51046 and analogues and the formal synthesis of (-)-allocolchicine. PubMed: Cinchona alkaloid-catalyzed asymmetric trifluoromethylation of alkynyl ketones with trimethylsilyl trifluoromethane. PubMed: Ultrasonic assisted Fischer glycosylation: generating diversity for glycochemistry. PubMed: Catalytic asymmetric synthesis of chiral propargylic alcohols for the intramolecular Pauson-Khand cycloaddition. PubMed: Scandium-catalyzed propargylation of 1,3-diketones with propargyl alcohols bearing sulfur or selenium functional groups: useful transformation to furans and pyrans. PubMed: Brønsted acid catalyzed cyclization of propargylic alcohols with thioamides. Facile synthesis of di- and trisubstituted thiazoles. PubMed: Iron-catalyzed C-O bond activation for the synthesis of propargyl-1,2,3-triazoles and 1,1-bis-triazoles. PubMed: Gold-catalyzed one-step practical synthesis of oxetan-3-ones from readily available propargylic alcohols. PubMed: Facile one-pot synthesis of three different substituted thiazoles from propargylic alcohols. PubMed: Expeditious synthesis of highly substituted indolizinones via a palladium-catalyzed domino sequence. PubMed: Palladium-catalyzed [3,3]-rearrangement for the facile synthesis of allenamides. PubMed: Mitotic arrest induced by a novel family of DNA topoisomerase II inhibitors. PubMed: Diversity-oriented construction of highly substituted indolizinones. PubMed: Synthesis of polysubstituted furans based on a stepwise Sonogashira coupling of (Z)-3-iodoalk-2-en-1-ols with terminal propargylic alcohols and subsequent Au(I)- or Pd(II)-catalyzed cyclization-aromatization via elimination of H2O. PubMed: Highly diastereoselective zinc-catalyzed propargylation of tert-butanesulfinyl imines. PubMed: Improved synthesis of three methyl-branched pheromone components produced by the female lichen moth. PubMed: Photodissociation dynamics of propargyl alcohol at 212 nm: the OH production channel. PubMed: Alkyne- and 1,6-elimination- succinimidyl carbonate - terminated heterobifunctional poly(ethylene glycol) for reversible "Click" PEGylation. PubMed: A striking exception to the chelate model for acyclic diastereocontrol: efficient access to a versatile propargyl alcohol for chemical synthesis. PubMed: Synthesis of azide-alkyne fragments for "click" chemical applications. Part 2. Formation of oligomers from orthogonally protected chiral trialkylsilylhomopropargyl azides and homopropargyl alcohols. PubMed: Cooperativity of regiochemistry control strategies in reductive couplings of propargyl alcohols and aldehydes. PubMed: Synthesis of tetrahydropyrans from propargyl alcohols and 1,1-cyclopropanediesters: a one-pot ring-opening/Conia-ene protocol. PubMed: Preparation of Disubstituted Phenyl Propargyl Alcohols, their Use in Oxathiolene Oxide Synthesis, and Evaluation of the Oxathiolene Oxide Products as Anticarcinogenic Enzyme Inducers. PubMed: Ytterbium(III) triflate catalyzed tandem Friedel-Crafts alkylation/hydroarylation of propargylic alcohols with phenols as an expedient route to indenols. PubMed: Silver(I)-catalyzed dual activation of propargylic alcohol and aziridine/azetidine: triggering ring-opening and endo-selective ring-closing in a cascade. PubMed: Apparent copper(II)-accelerated azide-alkyne cycloaddition. PubMed: An extremely facile synthesis of furans, pyrroles, and thiophenes by the dehydrative cyclization of propargyl alcohols. PubMed: Syntheses of naturally occurring cytotoxic [7.7]paracyclophanes, (-)-cylindrocyclophane A and its enantiomer, and implications for biological activity. PubMed: Enantioselective nucleophilic addition of trimethylsilylacetylene to n-phosphinoylimines promoted by C(2)-symmetric proline-derived beta-amino alcohol. PubMed: Matching active site and substrate structures for an RNA editing reaction. PubMed: Stereospecific synthesis of beta3-amino acid derivatives from propargylic alcohols: efficient solution-phase synthesis of oligopeptides without coupling agents. PubMed: Novel carbon-carbon bond formation from propargylic alcohols and olefin toward five-membered heterocyclic rings catalyzed by AgSbF6. PubMed: Functional group compatibility. Propargyl alcohol reduction in the presence of a vinyl iodide. PubMed: Synthesis of functionalized indenes via cascade reaction of aziridines and propargyl alcohols. PubMed: A versatile route to (E)- and (Z)-2-hydroxy-3,4-unsaturated disubstituted sulfilimines and their haloamidation reaction. PubMed: 'Clicking' on the nanoscale: 1,3-dipolar cycloaddition of terminal acetylenes on azide functionalized, nanometric surface templates with nanometer resolution. PubMed: A simple and versatile re-catalyzed Meyer-Schuster rearrangement of propargylic alcohols to alpha,beta-unsaturated carbonyl compounds. PubMed: Highly enantioselective zinc/amino alcohol-catalyzed alkynylation of aldehydes. PubMed: Tandem ring-opening/closing reactions of N-Ts aziridines and aryl propargyl alcohols promoted by t-BuOK. PubMed: Platinum-catalyzed cycloisomerization reaction of 1,6-enyne coupling with rearrangement of propargylic esters. PubMed: Highly regio- and stereoselective cyclic iodoetherification of 4,5-alkadienols. An efficient preparation of 2-(1'(Z)-iodoalkenyl)tetrahydrofurans. PubMed: A novel feature of intramolecular vibrational redistribution in propargyl alcohol and propargyl amine. PubMed: First synthesis of 1-chlorovinyl allenes via palladium-catalyzed allenylation of alkynoates with propargyl alcohols. PubMed: Toxicology and carcinogenesis studies of propargyl alcohol (CAS No. 107-19-7) in F344/N rats and B6C3F1 mice (inhalation studies). PubMed: Synthesis of naphthalenyl acetate by platinum-catalyzed [1,5]-sigmatropic hydrogen shift of propargylic esters. PubMed: A DFT study on the reaction pathways for carbon-carbon bond-forming reactions between propargylic alcohols and alkenes or ketones catalyzed by thiolate-bridged diruthenium complexes. PubMed: Cascade synthesis of 3-quinolinecarboxylic ester via benzylation/ propargylation-cyclization. PubMed: Gold mediated glycosylations: selective activation of propargyl 1,2-orthoesters in the presence of aglycones containing a propargyl moiety. PubMed: Rationalizing the formation of damascenone: synthesis and hydrolysis of damascenone precursors and their analogues, in both aglycone and glycoconjugate forms. PubMed: An atom-economic and selective ruthenium-catalyzed redox isomerization of propargylic alcohols. An efficient strategy for the synthesis of leukotrienes. PubMed: Controllable one-step synthesis of spirocycles, polycycles, and di- and tetrahydronaphthalenes from aryl-substituted propargylic alcohols. PubMed: Propargylation of 1,3-dicarbonyl compounds with 1,3-diarylpropynes via oxidative cross-coupling between sp3 C-H and sp3 C-H. PubMed: Direct and stereospecific synthesis of allenes via reduction of propargylic alcohols with Cp2Zr(H)Cl. PubMed: A gold(I)-catalyzed intramolecular reaction of propargylic/homopropargylic alcohols with oxirane. PubMed: Ruthenium/TFA-catalyzed coupling of activated secondary propargylic alcohols with cyclic 1,3-diones: furan versus pyran ring formation. PubMed: Efficient and selective syntheses of (all-E)- and (6E,10Z)-2'-O-methylmyxalamides D via Pd-catalyzed alkenylation--carbonyl olefination synergy. PubMed: Aluminum-catalyzed asymmetric alkylations of pyridyl-substituted alkynyl ketones with dialkylzinc reagents. PubMed: Self-assembled thermoreversible gels of nonpolar liquids by racemic propargylic alcohols with fluorinated and nonfluorinated aromatic rings. PubMed: Carbonyl propargylation from the alcohol or aldehyde oxidation level employing 1,3-enynes as surrogates to preformed allenylmetal reagents: a ruthenium-catalyzed C-C bond-forming transfer hydrogenation. PubMed: The proposal of architecture for chemical splitting to optimize QSAR models for aquatic toxicity. PubMed: Directed diastereoselectivity in the asymmetric claisen/metathesis reaction sequence. PubMed: Mo-Au combo catalysis for rapid 1,3-rearrangement of propargyl alcohols into alpha,beta-unsaturated carbonyl compounds. PubMed: Ring opening/fragmentation of dihydropyrones for the synthesis of homopropargyl alcohols. PubMed: Synthesis of 2,4,5-trisubstituted 3-fluorofurans via sequential iodocyclization and cross-coupling of gem-difluorohomopropargyl alcohols. PubMed: Palladium-catalyzed synthesis of indene derivatives via propargylic carbonates with in situ generated organozinc compounds. PubMed: One-step synthesis of substituted dihydro- and tetrahydroisoquinolines by FeCl3.6H2O catalyzed intramolecular Friedel-Crafts reaction of benzylamino-substituted propargylic alcohols. PubMed: Zirconium-promoted epoxide rearrangement-alkynylation sequence. PubMed: Studies on the synthesis of apoptolidin A. 1. Synthesis of the C(1)-C(11) fragment. PubMed: Remarkable effect of N-substituent on enantioselective ruthenium-catalyzed propargylation of indoles with propargylic alcohols. PubMed: Addition of alkynes to aldehydes and activated ketones catalyzed by rhodium-phosphine complexes. PubMed: Synthesis of spirocyclic C-arylglycosides and -ribosides by ruthenium-catalyzed cycloaddition. PubMed: Directed hydrozirconation of propargylic alcohols. PubMed: Highly efficient synthesis of functionalized indolizines and indolizinones by copper-catalyzed cycloisomerizations of propargylic pyridines. PubMed: Lewis acid catalyzed propargylation of arenes with O-propargyl trichloroacetimidates: synthesis of 1,3-diarylpropynes. PubMed: Reductive cyclization of o-nitrophenyl propargyl alcohols: facile synthesis of substituted quinolines. PubMed: Lewis acid-catalyzed conjugate addition-cyclization reactions of ethenetricarboxylates with substituted propargyl alcohols: stereoselectivity in the efficient one-pot synthesis of methylenetetrahydrofurans. PubMed: Copper(I) alkoxide-catalyzed alkynylation of trifluoromethyl ketones. PubMed: Bistrimethylsilylpropargylic ether: a versatile ambident synthon to access substituted allenyne ethers and alpha-substituted bispropargylic alcohols. PubMed: Assembly of conjugated enynes and substituted indoles via CuI/amino acid-catalyzed coupling of 1-alkynes with vinyl iodides and 2-bromotrifluoroacetanilides. PubMed: One-pot synthesis of alpha-iodo-substituted alpha,beta-unsaturated aldehydes from propargylic alcohols. PubMed: Synthesis of terpene and steroid dimers and trimers having cyclobutadienyl-Co and aromatic tethers. PubMed: Chiral ruthenium-allenylidene complexes that bear a fullerene cyclopentadienyl ligand: synthesis, characterization, and remote chirality transfer. PubMed: Ruthenium-catalyzed cycloisomerization-6pi-cyclization: a novel route to pyridines. PubMed: Rhodium-catalyzed asymmetric one-pot transesterification and [2 + 2 + 2] cycloaddition leading to enantioenriched 3,3-disubstituted phthalides. PubMed: Pt-catalyzed cyclization/1,2-migration for the synthesis of indolizines, pyrrolones, and indolizinones. PubMed: Recent developments in the metal-catalyzed reactions of metallocarbenoids from propargylic esters. PubMed: Iron-catalyzed carbometalation of propargylic and homopropargylic alcohols. PubMed: A general and efficient FeCl3-catalyzed nucleophilic substitution of propargylic alcohols. PubMed: Mono- and dinuclear oxovanadium(V)calixarene complexes and their activity as oxidation catalysts. PubMed: Coupling-isomerization synthesis of chalcones. PubMed: B-allenyl- and B-(gamma-trimethylsilylpropargyl)-10-phenyl-9-borabicyclo[3.3.2]decanes: asymmetric synthesis of propargyl and alpha-allenyl 3-degree-carbinols from ketones. PubMed: trans-hydroalumination/alkylation: one-pot synthesis of trisubstituted allylic alcohols. PubMed: Vanadium-catalyzed addition of propargyl alcohols and imines. PubMed: Synthesis of spirocyclic C-arylribosides via cyclotrimerization. PubMed: Supramolecular assemblies of chiral propargylic alcohols. PubMed: A highly efficient preparative method of alpha-ylidene-beta-diketones via Au(III)-catalyzed acyl migration of propargylic esters. PubMed: The nicholas approach to natural product hybrids. PubMed: Zinc- and indium-promoted conjugate addition-cyclization reactions of ethenetricarboxylates with propargylamines and alcohol: novel methylenepyrrolidine and methylenetetrahydrofuran syntheses. PubMed: Enhanced diastereoselectivity in beta-mannopyranosylation through the use of sterically minimal propargyl ether protecting groups. PubMed: Acetylenic TACE inhibitors. Part 3: Thiomorpholine sulfonamide hydroxamates. PubMed: Synthesis of a NO-releasing prodrug of rofecoxib. PubMed: [1,3]-Transfer of chirality during the Nicholas reaction in gamma-benzyloxy propargylic alcohols. PubMed: Alkyne hydrosilylation catalyzed by a cationic ruthenium complex: efficient and general trans addition. PubMed: Carbon 1s excitation spectroscopy of propyne, trifluoropropyne, and propargyl alcohol. PubMed: Electron inventory, kinetic assignment (E(n)), structure, and bonding of nitrogenase turnover intermediates with C2H2 and CO. PubMed: Gold(III)-catalyzed nucleophilic substitution of propargylic alcohols. PubMed: Reactivity of alkynes containing alpha-hydrogen atoms with a triruthenium hydrido carbonyl cluster: alkenyl versus allyl cluster derivatives. PubMed: Phototransformation of clodinafop-propargyl. PubMed: Synergistic dimetallic effects in propargylic substitution reaction catalyzed by thiolate-bridged diruthenium complex. PubMed: Highly stereoselective one-pot procedure to prepare bis- and tris-chalcogenide alkenes via addition of disulfides and diselenides to terminal alkynes. PubMed: Ruthenium-catalyzed cycloisomerizations of diynols. PubMed: Substrate interactions with the nitrogenase active site. PubMed: Synthesis of diindeno-fused 4H-cyclopenta[def]phenanthren-4-ones and related compounds via benzannulated enediynyl propargylic alcohols. PubMed: Reaction of alpha-(N-carbamoyl)alkylcuprates with propargyl substrates: synthetic route to alpha-amino allenes and delta3-pyrrolines. PubMed: Antinociceptive properties of acetylenic thiophene and furan derivatives: evidence for the mechanism of action. PubMed: Oxathiolene oxide synthesis via chelation-controlled addition of organometallic reagents to alkynols followed by addition of sulfur electrophiles and evaluation of oxathiolene oxides as anticarcinogenic enzyme inducers. PubMed: Aryl annulation of cyclic ketones via a magnesium carbometalation-6-pi- electrocyclization protocol. PubMed: Meerwein-Ponndorf-Verley alkynylation of aldehydes: essential modification of aluminium alkoxides for rate acceleration and asymmetric synthesis. PubMed: Regioselectivity control in a ruthenium-catalyzed cycloisomerization of diyne-ols. PubMed: Silicon-assisted propargylic transfer to aldehydes. PubMed: Substrate interaction at an iron-sulfur face of the FeMo-cofactor during nitrogenase catalysis. PubMed: The mechanism of nitrogenase. Computed details of the site and geometry of binding of alkyne and alkene substrates and intermediates. PubMed: Synthesis of deuterated fatty acids to investigate the biosynthetic pathway of disparlure, the sex pheromone of the gypsy moth, Lymantria dispar. PubMed: An organometallic intermediate during alkyne reduction by nitrogenase. PubMed: (+)-3-{(4S,5S)-5-[1,1-Dimethyl-2-(phenylthio)ethyl]-2,2-dimethyl-1,3-dioxolan-4-yl}prop-2-yn-1-ol. PubMed: Localization of a catalytic intermediate bound to the FeMo-cofactor of nitrogenase. PubMed: Zn(II)/amine-catalyzed coupling reaction of alkylidenemalonates with propargyl alcohol: a one-pot synthesis of methylenetetrahydrofurans. PubMed: B(C6F5)3-catalyzed allylation of propargyl acetates with allylsilanes. PubMed: Rhenium-catalyzed aromatic propargylation. PubMed: Coupling-isomerization-coupling sequences switched on by propargyl alcohol-enone-isomerization. PubMed: Construction of azacycles based on endo-mode cyclization of allenes. PubMed: Ru(II)-catalyzed chemo- and regioselective cyclotrimerization of three unsymmetrical alkynes through boron temporary tether. One-pot four-component coupling via cyclotrimerization/Suzuki-Miyaura coupling. PubMed: Phosphorylated 1,6-diphenyl-1,3,5-hexatriene. PubMed: Rhenium-catalyzed coupling of propargyl alcohols and allyl silanes. PubMed: Facile one-pot synthesis of photochromic pyrans. PubMed: A mechanistic dichotomy in ruthenium-catalyzed propargyl alcohol reactivity: a novel hydrative diyne cyclization. PubMed: Localization of a substrate binding site on the FeMo-cofactor in nitrogenase: trapping propargyl alcohol with an alpha-70-substituted MoFe protein. PubMed: Clotrimazole, ketoconazole, and clodinafop-propargyl as potent growth inhibitors of equine Babesia parasites during in vitro culture. PubMed: Application of selectively acylated glycosides for the alpha-galactosidase-catalyzed synthesis of disaccharides. PubMed: A Rh(I)-catalyzed cycloisomerization of homo- and bis-homopropargylic alcohols. PubMed: A mild C-O bond formation catalyzed by a rhenium-oxo complex. PubMed: Ruthenium-catalyzed alkyne-propargyl alcohol addition. An asymmetric total synthesis of (+)-alpha-kainic acid. PubMed: A mechanism for the formation of bis-glutathione conjugates of propargyl alcohol. PubMed: Characterization of propargyl bromide transformation in soil. 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PubMed: Mechanism-based inactivation of thymidylate synthase by 5-(3-fluoropropyn-1-yl)-2'-deoxyuridine 5'-phosphate. PubMed: Identification of metabolites of [1,2,3-(13)C]Propargyl alcohol in rat urine by (13)C NMR and mass spectrometry. PubMed: Unusual propargylic oxidations catalyzed by chloroperoxidase. PubMed: Sex attractants of geometrid and noctuid moths: Chemical characterization and field test of monoepoxides of 6,9-dienes and related compounds. PubMed: Hybrid molecules containing propargylic sulfones and DNA minor groove-binding lexitropsins: synthesis, sequence specificity of reaction with DNA and biological evaluation. PubMed: Comparative oxidation of 2-propyn-1-ol with other low molecular weight unsaturated and saturated primary alcohols by bovine liver catalase in vitro. PubMed: Mutagenic activity of 3 industrial chemicals in a battery of in vitro and in vivo tests. PubMed: Vinylstannylated alkylating agents as prosthetic groups for radioiodination of small molecules: design, synthesis, and application to iodoallyl analogues of spiperone and diprenorphine. PubMed: Zinc-activated alcohols in ternary complexes of liver alcohol dehydrogenase. PubMed: Evidence that enzyme-generated aromatic Michael acceptors covalently modify the nucleotide-binding site of 3 alpha-hydroxysteroid dehydrogenase. PubMed: Fluorinated androgens and progestins: molecular probes for androgen and progesterone receptors with potential use in positron emission tomography. PubMed: Flavin-dependent alcohol oxidase from yeast. Studies on the catalytic mechanism and inactivation during turnover. PubMed: Role of propiolaldehyde and other metabolites in the pargyline inhibition of rat liver aldehyde dehydrogenase. PubMed: Two geometrical isomers of linoleic acid: improved total syntheses. PubMed: Acute oral toxicity as LD50 (mg/kg) of propargyl alcohol to male and female rats. PubMed: Penitricin, a new class of antibiotic produced by Penicillium aculeatum. III. Structural confirmation by chemical synthesis and biological activity. PubMed: Sex pheromone of the European grapevine moth,Lobesia botrana Schiff. (Lepidoptera: Tortricidae): Synthesis and effect of isomeric purity on biological activity. PubMed: Irreversible inactivation of the flavoenzyme alcohol, oxidase with acetylenic alcohols. PubMed: Inhibition of aldehyde dehydrogenase by propiolaldehyde, a possible metabolite of pargyline. PubMed: An approach to the synthesis of C18 tri-insaturated fatty acids. PubMed: C-nucleoside studies. Part 6. Synthesis of 3-[2,3,5-tri-O-benzyl-beta-(and alpha)-D-ribofuranosyl]prop-2-yn-1-ol and related compounds; a new synthesis of 3(5)-(2,3,5-tri-O-benzyl-beta-D-ribofuranosyl)pyrazole. PubMed: [Synthesis of sulfazine from propargyl alcohol].