Identification

Namebutyl acetoacetate
IUPACbutyl 3-oxobutanoate
CAS Number591-60-6
EINECS209-722-2
FDA UNII2W08J7H74O
Molecular FormulaC8 H14 O3
Molecular Weight158.19718000
MDL NumberMFCD00059252
Nikkaji NumberJ74.804H
Beilstein1761408
CoE Number241
XlogP31.10 (est)

Regulatory

JECFA Food Flavoring596 butyl acetoacetate
DG SANTE Food Flavourings09.403 butyl acetoacetate
FEMA Number2176
FDANo longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF)591-60-6 ; BUTYL ACETOACETATE
FDA RegulationFDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION

Physical Properties

Appearance colorless clear liquid (est)
Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Specific Gravity 0.98100 to 0.98500 @ 20.00 °C.
Pounds per Gallon - (est). 8.172 to 8.206
Refractive Index 1.42500 to 1.42900 @ 20.00 °C.
Melting Point -35.60 °C. @ 760.00 mm Hg
Boiling Point 100.00 to 103.00 °C. @ 16.00 mm Hg, 205.00 °C. @ 760.00 mm Hg
Vapor Pressure 0.243000 mmHg @ 25.00 °C. (est)
Flash Point 175.00 °F. TCC ( 79.44 °C. )
logP (o/w) 1.386 (est)
Soluble in alcohol
Insoluble in water
Similar Items note

Organoleptic Properties

Odor Description at 10.00 % in dipropylene glycol.

Safety Information

Preferred SDSView
Oral/Parenteral Toxicitygavage-rat LD50 [sex: F] 11260 mg/kg
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavor and fragrance agents
RIFM Fragrance Material Safety AssessmentSearch
Recommendation for butyl acetoacetate usage levels up to2.0000 % in the fragrance concentrate.
Maximised Survey-derived Daily Intakes (MSDI-EU)63.00 (μg/capita/day)
baked goods-
beverages(nonalcoholic)-
beverages(alcoholic)-
breakfast cereal-
cheese-
chewing gum-
condiments / relishes-
confectionery froastings-
egg products-
fats / oils-
fish products-
frozen dairy-
fruit ices-
gelatins / puddings-
granulated sugar-
gravies-
hard candy-
imitation dairy-
instant coffee / tea-
jams / jellies-
meat products-
milk products-
nut products-
other grains-
poultry-
processed fruits-
processed vegetables-
reconstituted vegetables-
seasonings / flavors-
snack foods-
soft candy-
soups-
sugar substitutes-
sweet sauces-

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Potential Uses

FR banana blossom blossom tropical blossom FR cherry FR floral FR fruit FL fruit tropical fruit FR jasmin FR wine FL yeast

Natural Occurrence

not found in nature

Synonyms

acetoacetic acid butyl ester 3-oxo- butanoic acid butyl ester butanoic acid, 3-oxo-, butyl ester butyl 3-ketobutanoate butyl 3-ketobutyrate butyl 3-oxobutanoate butyl 3-oxobutyrate N- butyl acetoacetate Try the PubMed Search.