tert-butyl acrylate
acrylic acid, tert-butyl ester
Identification
| Name | tert-butyl acrylate |
| CAS Number | 1663-39-4 |
| EINECS | 216-768-7 |
| FDA UNII | 92M2CD1O3G |
| Molecular Formula | C7 H12 O2 |
| Molecular Weight | 128.17104000 |
| MDL Number | MFCD00008809 |
| Nikkaji Number | J82.107A |
| Beilstein | 1742329 |
Regulatory
| DG SANTE Food Contact Materials | acrylic acid, tert-butyl ester |
| FDA Mainterm (IAUFC) | 1663-39-4 ; TERT-BUTYL ACRYLATE |
Physical Properties
| Assay | 95.00 to 100.00 |
| Food Chemicals Codex Listed | No |
| Specific Gravity | 0.87500 @ 25.00 °C. |
| Boiling Point | 133.01 °C. @ 760.00 mm Hg (est) |
| Vapor Pressure | 8.637000 mmHg @ 25.00 °C. (est) |
| Flash Point | 63.00 °F. TCC ( 17.22 °C. ) |
| logP (o/w) | 2.062 (est) |
| Soluble in | water, 1534 mg/L @ 25 °C (est) |
No sensory data available
Safety Information
| Preferred SDS | View |
| Oral/Parenteral Toxicity | Not determined |
| Dermal Toxicity | Not determined |
| Inhalation Toxicity | Not determined |
GHS Classification
['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']
Safety in Use
| Category | indirect food additives: adhesives and components of coatings |
| Recommendation for tert-butyl acrylate usage levels up to | not for fragrance use. |
| Recommendation for tert-butyl acrylate flavor usage levels up to | not for flavor use. |
Potential Uses
Natural Occurrence
Synonyms
acrylic acid t-butyl ester
acrylic acid tert-butyl ester
acrylic acid, tert-butyl ester
acrylic acid, tert-butyl ester (8CI)
t-
butyl acrylate
tert-
butyl prop-2-enoate
tert-
butyl propenoate
2-
methyl-2-propanyl acrylate
2-
propenoic acid, 1,1-dimethylethyl ester
PubMed:
Functional Brush-Decorated Poly(globalide) Films by ARGET-ATRP for Bioconjugation.
PubMed:
High-speed atomic force microscope imaging: adaptive multiloop mode.
PubMed:
Toward pH-responsive coating materials--high-throughput study of (meth)acrylic copolymers.
PubMed:
Micro and macrorheology at fluid-fluid interfaces.
PubMed:
Rapid and quantitative detection of prostate specific antigen with a quantum dot nanobeads-based immunochromatography test strip.
PubMed:
Antimicrobial activity of poly(acrylic acid) block copolymers.
PubMed:
Monolithic silica rods grafted with thermoresponsive anionic polymer brushes for high-speed separation of basic biomolecules and peptides.
PubMed:
Copper(II)/tertiary amine synergy in photoinduced living radical polymerization: accelerated synthesis of Ï-functional and α,Ï-heterofunctional poly(acrylates).
PubMed:
Synthetic scope and DFT analysis of the chiral binap-gold(I) complex-catalyzed 1,3-dipolar cycloaddition of azlactones with alkenes.
PubMed:
Divergent dendrimer synthesis via the Passerini three-component reaction and olefin cross-metathesis.
PubMed:
Revival of the R-group approach: a "CTA-shuttled" grafting from approach for well-defined cylindrical polymer brushes via RAFT polymerization.
PubMed:
Nanoparticle Formation from Hybrid, Multiblock Copolymers of Poly(Acrylic Acid) and VPGVG Peptide.
PubMed:
Separation and composition distribution determination of triblock copolymers by thermal field-flow fractionation.
PubMed:
Tunable self-assembly of triazole-linked porphyrin-polymer conjugates.
PubMed:
Pentablock copolymers of pluronic F127 and modified poly(2-dimethyl amino)ethyl methacrylate for internalization mechanism and gene transfection studies.
PubMed:
A novel biocompatible bicephalous dianionic surfactant from oleic acid for solid lipid nanoparticles.
PubMed:
Photoinduced disorder in strongly segregated block copolymer composite films for hierarchical pattern formation.
PubMed:
Protein immobilization onto poly(acrylic acid) functional macroporous polyHIPE obtained by surface-initiated ARGET ATRP.
PubMed:
Preparation of copolymer paclitaxel covalently linked via a disulfide bond and its application on controlled drug delivery.
PubMed:
Simultaneous coating of silica particles by two diblock copolymers.
PubMed:
Pressure-sensitive adhesion system using acrylate block copolymers in response to photoirradiation and postbaking as the dual external stimuli for on-demand dismantling.
PubMed:
Surface-grafted poly(acrylic acid) brushes as a precursor layer for biosensing applications: effect of graft density and swellability on the detection efficiency.
PubMed:
Mimicking conjugated polymer thin-film photophysics with a well-defined triblock copolymer in solution.
PubMed:
Oleic acid based heterolipid synthesis, characterization and application in self-microemulsifying drug delivery system.
PubMed:
Functional polyolefins: poly(ethylene)-graft-poly(tert-butyl acrylate) via atom transfer radical polymerization from a polybrominated alkane.
PubMed:
Planar chiral (η6-arene)Cr(CO)3 containing carboxylic acid derivatives: synthesis and use in the preparation of organometallic analogues of the antibiotic platensimycin.
PubMed:
Scanning thermal lithography of tailored tert-butyl ester protected carboxylic acid functionalized (meth)acrylate polymer platforms.
PubMed:
Chiral gold(I) vs chiral silver complexes as catalysts for the enantioselective synthesis of the second generation GSK-hepatitis C virus inhibitor.
PubMed:
Thiol-alkyne chemistry for the preparation of micelles with glycopolymer corona: dendritic surfaces versus linear glycopolymer in their ability to bind to lectins.
PubMed:
Theoretical studies on the mechanism and stereoselectivity of Rh(Phebox)-catalyzed asymmetric reductive aldol reaction.
PubMed:
Facile synthesis of thick films of poly(methyl methacrylate), poly(styrene), and poly(vinyl pyridine) from Au surfaces.
PubMed:
Chemical surface modification of parylene C for enhanced protein immobilization and cell proliferation.
PubMed:
Synthesis of drug/dye-incorporated polymer-protein hybrids.
PubMed:
Development of a new open-tubular capillary electrochromatography method for in vitro monitoring of toxic aromatic amines distribution in rat blood.
PubMed:
Poly(Acrylic Acid-b-Styrene) Amphiphilic Multiblock Copolymers as Building Blocks for the Assembly of Discrete Nanoparticles.
PubMed:
Diels-Alder reactions as an efficient route to high purity cyclic polymers.
PubMed:
Introducing surface-tethered poly(acrylic acid) brushes as 3D functional thin film for biosensing applications.
PubMed:
Chiral imprinting of diblock copolymer single-chain particles.
PubMed:
Temperature and pH dual-responsive cross-linked polymeric nanocapsules with controllable structures via surface-initiated atom transfer radical polymerization from templates.
PubMed:
Molecular friction dissipation and mode coupling in organic monolayers and polymer films.
PubMed:
Hybrid rigid/soft and biologic/synthetic materials: polymers grafted onto cellulose microcrystals.
PubMed:
A novel hyperbranched poly(acrylic acid) for improved resin-modified glass-ionomer restoratives.
PubMed:
A novel amphipathic block copolymer coating forming micelle-like aggregates for separation of steroids in open tubular capillary electrochromatography.
PubMed:
Rheological properties of aqueous micellar gels of a thermo- and pH-sensitive ABA triblock copolymer.
PubMed:
RAFT "grafting-through" approach to surface-anchored polymers: Electrodeposition of an electroactive methacrylate monomer.
PubMed:
Temperature-responsive ionic-crosslinked polymeric nanocapsules via 'self-templating' approach.
PubMed:
Star-shaped nano-conjugates of cisplatin with high drug payload.
PubMed:
Water-soluble organo-silica hybrid nanotubes templated by cylindrical polymer brushes.
PubMed:
Investigation of thermally responsive block copolymer thin film morphologies using gradients.
PubMed:
Amphiphilic polyethylenes leading to surfactant-free thermoresponsive nanoparticles.
PubMed:
Hyperbranched alternating block copolymers using thiol-yne chemistry: materials with tuneable properties.
PubMed:
Synthesis and solution self-assembly of side-chain cobaltocenium-containing block copolymers.
PubMed:
SiO2 nanodot arrays using functionalized block copolymer templates and selective silylation.
PubMed:
Shaping gold nanocomposites with tunable optical properties.
PubMed:
Perfluorocarbon-loaded Shell Crosslinked Knedel-like Nanoparticles: Lessons regarding polymer mobility and self assembly.
PubMed:
High density scaffolding of functional polymer brushes: surface initiated atom transfer radical polymerization of active esters.
PubMed:
Inkless microcontact printing on SAMs of Boc- and TBS-protected thiols.
PubMed:
A general methodology toward drug/dye incorporated living copolymer-protein hybrids: (NIRF dye-glucose) copolymer-avidin/BSA conjugates as prototypes.
PubMed:
Dual patterning and sequential functionalization of block copolymers using photocrosslinkable random copolymer film.
PubMed:
N-heterocycle carbene (NHC)-ligated cyclopalladated N,N-dimethylbenzylamine: a highly active, practical and versatile catalyst for the Heck-Mizoroki reaction.
PubMed:
Polymer brush covalently attached to OH-functionalized mica surface via surface-initiated ATRP: control of grafting density and polymer chain length.
PubMed:
Coating and structural locking of dipolar chains of cobalt nanoparticles.
PubMed:
Gold nanoparticles protected with thiol-derivatized amphiphilic poly(epsilon-caprolactone)-b-poly(acrylic acid).
PubMed:
19F- and fluorescently labeled micelles as nanoscopic assemblies for chemotherapeutic delivery.
PubMed:
ATRP from an amino acid-based initiator: A facile approach for α-functionalized polymers.
PubMed:
Adsorption of well-defined fluorine-containing polymers onto poly(tetrafluoroethylene).
PubMed:
Amphiphilic hyperbranched fluoropolymers as nanoscopic 19F magnetic resonance imaging agent assemblies.
PubMed:
Atomic force microscopy based thermal lithography of poly(tert-butyl acrylate) block copolymer films for bioconjugation.
PubMed:
Amphiphilic Janus gold nanoparticles via combining "solid-state grafting-to" and "grafting-from" methods.
PubMed:
Fabrication of block copolymer monolayers by adsorption from supercritical fluids: a versatile concept for modification and functionalization of polymer surfaces.
PubMed:
Synthesis of dense poly(acrylic acid) brushes and their interaction with amine-functional silsesquioxane nanoparticles.
PubMed:
Inverted microcontact printing on polystyrene-block-poly(tert-butyl acrylate) films: a versatile approach to fabricate structured biointerfaces across the length scales.
PubMed:
Noncovalently connected micelles, nanoparticles, and metal-functionalized nanocages using supramolecular self-assembly.
PubMed:
Phase separation in poly(tert-butyl acrylate)/polyhedral oligomeric silsesquioxane (POSS) thin film blends.
PubMed:
A Proximal Bisnitroxide Initiator: Studies in Low-Temperature Nitroxide-Mediated Polymerizations.
PubMed:
Patterning on nonplanar substrates: flexible honeycomb films from a range of self-assembling star copolymers.
PubMed:
Unprecedented covalently attached ATRP initiator onto OH-functionalized mica surfaces.
PubMed:
Thermomechanical formation and recovery of nanoindents in a shape memory polymer studied using a heated tip.
PubMed:
Comb polymers prepared by ATRP from hydroxypropyl cellulose.
PubMed:
Polystyrene-b-poly(tert-butyl acrylate) and polystyrene-b-poly(acrylic acid) dendrimer-like copolymers: two-dimensional self-assembly at the air-water interface.
PubMed:
Unconstrained recovery characterization of shape-memory polymer networks for cardiovascular applications.
PubMed:
Stille-Heck coupling sequences applied in a versatile new access to steroid skeletons.
PubMed:
Reactive microCP on ultrathin block copolymer films: investigation of the microCP mechanism and application to sub-microm (bio)molecular patterning.
PubMed:
Dip-pen nanolithography on (bio)reactive monolayer and block-copolymer platforms: deposition of lines of single macromolecules.
PubMed:
Synthesis and aggregation behavior of four-arm star amphiphilic block copolymers in water.
PubMed:
Interactions of poly(tert-butyl acrylate)-poly(styrene) diblock copolymers with lipids at the air-water interface.
PubMed:
Self-assembly of well-defined mono and dual end-capped C(60) containing polyacrylic acids in aqueous solution.
PubMed:
Pattern formation in dewetting poly(tert-butyl acrylate)/polyhedral oligomeric silsesquioxane (POSS) bilayer films.
PubMed:
Rapid growth of polymer brushes from immobilized initiators.
PubMed:
Tandem synthesis of core-shell brush copolymers and their transformation to peripherally cross-linked and hollowed nanostructures.
PubMed:
Synthesis of degradable model networks via ATRP and click chemistry.
PubMed:
High-capacity binding of proteins by poly(acrylic acid) brushes and their derivatives.
PubMed:
Nanoscale phase separation in mixed poly(tert-butyl acrylate)/polystyrene brushes on silica nanoparticles under equilibrium melt conditions.
PubMed:
Reversible stimuli-responsive nanostructures assembled from amphiphilic block copolymers.
PubMed:
Preparation of platinum nanoparticles using star-block copolymer with a carboxylic core.
PubMed:
Copper(I) and -(II) complexes of neutral and deprotonated N-(2,6-diisopropylphenyl)-3-[bis(2-pyridylmethyl)amino]propanamide.
PubMed:
Self-assembly of pODMA-b-ptBA-b-pODMA triblock copolymers in bulk and on surfaces. A quantitative SAXS/AFM comparison.
PubMed:
Directed assembly of cylinder-forming block copolymer films and thermochemically induced cylinder to sphere transition: a hierarchical route to linear arrays of nanodots.
PubMed:
Antigen-decorated shell cross-linked nanoparticles: synthesis, characterization, and antibody interactions.
PubMed:
Stimuli-responsive mixed grafted polymer films with gradually changing properties: direct determination of chemical composition.
PubMed:
Mono- and beta,beta-double-Heck reactions of alpha,beta-unsaturated carbonyl compounds in aqueous media.
PubMed:
Environmentally responsive "hairy" nanoparticles: mixed homopolymer brushes on silica nanoparticles synthesized by living radical polymerization techniques.
PubMed:
Three-dimensionally ordered porous membranes prepared via self-assembly and reverse micelle formation from well-defined amphiphilic block copolymers.
PubMed:
Photochemical modification and patterning of polymer surfaces by surface adsorption of photoactive block copolymers.
PubMed:
Thermomechanics of the shape memory effect in polymers for biomedical applications.
PubMed:
Interfacial reactions in confinement: kinetics and temperature dependence of the surface hydrolysis of polystyrene-block-poly(tert-butyl acrylate) thin films.
PubMed:
Interactions between brushlike polyacrylic acid side chains on a polyacrylate backbone in dioxane-water.
PubMed:
Synthesis and characterization of polyester dendrimers from acetoacetate and acrylate.
PubMed:
Monitoring surface thermal transitions of ABA triblock copolymers with crystalline segments using phase contrast tapping mode atomic force microscopy.
PubMed:
Synthesis of tethered-polymer brush by atom transfer radical polymerization from a plasma-polymerized-film-coated quartz crystal microbalance and its application for immunosensors.
PubMed:
Metalloinitiation routes to biocompatible poly(lactic acid) and poly(acrylic acid) stars with luminescent ruthenium tris(bipyridine) cores.
PubMed:
Polymerization from the surface of single-walled carbon nanotubes - preparation and characterization of nanocomposites.
PubMed:
Y-shaped amphiphilic brushes with switchable micellar surface structures.
PubMed:
Use of highly active palladium-phosphinous acid catalysts in Stille, Heck, amination, and thiation reactions of chloroquinolines.
PubMed:
Synthesis of poly(tert-butyl acrylate)-block-polystyrene-block-poly(4-vinylpyridine) by living anionic polymerization.
PubMed:
Synthesis and characterization of luminescent rod-coil block copolymers by atom transfer radical polymerization: utilization of novel end-functionalized terfluorenes as macroinitiators.
PubMed:
Water-soluble fluorescent diblock nanospheres.
PubMed:
Amphiphilic block copolymers as bile acid sorbents: 1. Synthesis of polystyrene-b-poly(N,N,N-trimethylammoniumethylene acrylamide chloride).
PubMed:
An improved synthesis of a trifurcated newkome-type monomer and orthogonally protected two-generation dendrons.
PubMed:
Patterning of hyperbranched polymer films.
PubMed:
Metal- and Ligand-Accelerated Catalysis of the Baylis-Hillman Reaction.
PubMed:
Block Copolymer Nanotubes.
PubMed:
Ultrathin films of a polyelectrolyte with layered architecture
PubMed:
Photochemistry of Dihydrido(hydrotris(3,5-dimethylpyrazolyl)borato)(Z-cyclooctene)iridium. Synthetic Intermediates and Mechanism of the Photochemical Formation of Hydridophenyl(hydrotris(3,5-dimethylpyrazolyl)borato)(trimethyl phosphite)iridium.