stannic chloride
stannane, tetrachloro-
Identification
| Name | stannic chloride |
| IUPAC | tetrachlorostannane |
| CAS Number | 7646-78-8 |
| EINECS | 231-588-9 |
| FDA UNII | 67H76LFL3V |
| Molecular Formula | Cl4 Sn |
| Molecular Weight | 260.51800000 |
| MDL Number | MFCD00011242 |
Regulatory
| FDA Mainterm (SATF) | 7646-78-8 ; STANNIC CHLORIDE |
Physical Properties
| Assay | 95.00 to 100.00 |
| Food Chemicals Codex Listed | No |
| Specific Gravity | 2.22600 @ 25.00 °C. |
| Boiling Point | 114.00 to 115.00 °C. @ 760.00 mm Hg (est) |
| Vapor Pressure | 23.923000 mmHg @ 25.00 °C. (est) |
| Flash Point | 32.00 °F. TCC ( 0.00 °C. ) (est) |
| logP (o/w) | -0.733 (est) |
| Soluble in | water, 4.188e+005 mg/L @ 25 °C (est) |
No sensory data available
Safety Information
| Preferred SDS | View |
| Oral/Parenteral Toxicity | intraperitoneal-mouse LD50 99 mg/kg |
| Dermal Toxicity | Not determined |
| Inhalation Toxicity | inhalation-rat LC50 2300 mg/m3/10M |
GHS Classification
['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']
Safety in Use
| Category | information only not used for fragrances or flavors |
| Recommendation for stannic chloride usage levels up to | not for fragrance use. |
| Recommendation for stannic chloride flavor usage levels up to | not for flavor use. |
Potential Uses
Natural Occurrence
Synonyms
stannane, tetrachloro-
tetrachlorostannane
tin chloride (1:4)
tin perchloride
tin(IV) chloride
tin(IV) tetrachloride
PubMed:
Synthesis of quinoxalines or quinolin-8-amines from N-propargyl aniline derivatives employing tin and indium chlorides.
PubMed:
Synthesis of 1-(β-D-Galactopyranosyl)Thymine-6'-O-Triphosphate - A Potential Probe to Generate Reactive Dialdehyde for DNA-Enzyme Cross-Linking.
PubMed:
Stannic chloride-para toluene sulfonic acid as a novel catalyst-co-catalyst system for the designing of hydroxyl terminated polyepichlorohydrin polymer: Synthesis and characterization.
PubMed:
Synthesis and pharmacological studies of new pyrazole analogues of podophyllotoxin.
PubMed:
Catalysis and chemodivergence in the interrupted, formal homo-Nazarov cyclization using allylsilanes.
PubMed:
Regiospecific anomerisation of acylated glycosyl azides and benzoylated disaccharides by using TiCl4.
PubMed:
Characterization of an array of Love-wave gas sensors developed using electrospinning technique to deposit nanofibers as sensitive layers.
PubMed:
The enhanced photocatalytic and bactericidal activities of carbon microsphere-assisted solvothermally synthesized cocoon-shaped Sn(4+)-doped ZnO nanoparticles.
PubMed:
Tm2.22Co6Sn20 and TmLi2Co6Sn20 stannides as disordered derivatives of the Cr23C6 structure type.
PubMed:
Two-dimensional infrared spectroscopy reveals the structure of an Evans auxiliary derivative and its SnCl4 Lewis acid complex.
PubMed:
4-(Dimethyl-amino)-pyridinium tetra-chlorido(pyridine-2-carboxyl-ato-κ(2)N,O)stannate(IV).
PubMed:
10-Hy-droxy-benzo[h]quinolin-1-ium tetra-chlorido(pyridine-2-carboxyl-ato-κ(2)N,O)stannate(IV) methanol monosolvate.
PubMed:
8-Hy-droxy-2-methyl-quinolinium tetra-chlorido(quinolin-8-olato-κ(2)N,O)stan-nate(IV).
PubMed:
Sc(OTf)3-catalyzed synthesis of indoles and SnCl4-mediated regioselective hydrochlorination of 5-(arylamino)pent-3-yn-2-ones.
PubMed:
Solid state synthesis of tin-doped ZnO at room temperature: characterization and its enhanced gas sensing and photocatalytic properties.
PubMed:
8-Hy-droxy-2-methyl-quinolinium tetra-chlorido(quinolin-2-olato-κN,O)stannate(IV) methanol disolvate.
PubMed:
8-Hy-droxy-2-methyl-quinolinium tetra-chlorido(pyridine-2-carboxyl-ato-κN,O)stannate(IV).
PubMed:
2-Meth-oxy-carbonyl-pyridinium tetra-chlorido(pyridine-2-carboxyl-ato-κN,O)stannate(IV).
PubMed:
3-Meth-oxy-carbonyl-1-methyl-pyrazinium tetra-chlorido(pyrazine-2-carboxyl-ato-κN,O)stannate(IV).
PubMed:
Transformation of methyltin chlorides and stannic chloride under simulated landfill conditions.
PubMed:
Anthrax letters in an open office environment: effects of selected CDC response guidelines on personal exposure and building contamination.
PubMed:
SnCl4 · 5H2O-catalyzed synthesis of β-amino carbonyl compounds via a direct Mannich-type reaction.
PubMed:
A simple method to deposit palladium doped SnO2 thin films using plasma enhanced chemical vapor deposition technique.
PubMed:
SnCl(4)- and TiCl(4)-catalyzed anomerization of acylated O- and S-glycosides: analysis of factors that lead to higher α:β anomer ratios and reaction rates.
PubMed:
An efficient deprotection of N-trimethylsilylethoxymethyl (SEM) groups from dinucleosides and dinucleotides.
PubMed:
Variations on the SnCl4 and CF3CO2Ag-promoted glycosidation of sugar acetates: a direct, versatile and apparently simple method with either alpha or beta stereocontrol.
PubMed:
Thiodisaccharides with galactofuranose or arabinofuranose as terminal units: synthesis and inhibitory activity of an exo beta-D-galactofuranosidase.
PubMed:
A facile preparation of peracylated alpha-aldopyranosyl chlorides with thionyl chloride and tin tetrachloride.
PubMed:
A second generation formal synthesis of (-)-cephalotaxine.
PubMed:
Ultrastructural changes in regressing equine sarcoid tumours--mysterious role of mitochondria.
PubMed:
Bioinspired polyene cyclization promoted by intermolecular chiral acetal-SnCl4 or chiral N-acetal-TiCl4: investigation of the mechanism and identification of the key intermediates.
PubMed:
Catalytic enantioselective allyl- and crotylboration of aldehydes using chiral diol x SnCl4 complexes. optimization, substrate scope and mechanistic investigations.
PubMed:
Glucose sensor based on nano-baskets of tin oxide templated in porous alumina by plasma enhanced CVD.
PubMed:
Bio-inspired polyene cyclization: synthesis of tetracyclic terpenoids promoted by steroidal acetal-SnCl4.
PubMed:
Synthesis, docking and anti-tumor activity of beta-L-1,3-thiazolidine pyrimidine nucleoside analogues.
PubMed:
An expedient one-pot synthesis of para-tert-butylcalix[8]- and [9]arene.
PubMed:
Glycosidation-anomerisation reactions of 6,1-anhydroglucopyranuronic acid and anomerisation of beta-D-glucopyranosiduronic acids promoted by SnCl(4).
PubMed:
Interplay of structure and reactivity in a most unusual furan Diels-Alder reaction.
PubMed:
Design, synthesis and antibacterial activity of novel 1,3-thiazolidine pyrimidine nucleoside analogues.
PubMed:
Depositional characteristics of metal coating on single-crystal TiO2 nanowires.
PubMed:
Lewis acid-promoted rearrangement of 2,3-epoxy alcohol derivatives: stereochemical control and selective formation of two types of chiral quaternary carbon centers from the single carbon skeleton.
PubMed:
Imposex induction in the mud snail, Ilyanassa obsoleta by three tin compounds.
PubMed:
Study of the factors that control the ratio of the products between 5-fluorouracil, uracil, and tetrahydrobenzoxazepine O,O-acetals bearing electron-withdrawing groups on the nitrogen atom.
PubMed:
A one-pot synthesis of 1-alpha- and 1-beta-D-arabinofuranosyl-2-nitroimidazoles: synthons to the markers of tumor hypoxia.
PubMed:
Synthesis and DNA topoisomerase-II inhibitory activity of unnatural nucleosides.
PubMed:
Stereochemical features of Lewis acid-promoted glycosidations involving 4'-spiroannulated DNA building blocks.
PubMed:
Prolactin increases HO-1 expression and induces VEGF production in human macrophages.
PubMed:
Glycosidation reactions of silyl ethers with conformationally inverted donors derived from glucuronic acid: stereoselective synthesis of glycosides and 2-deoxyglycosides.
PubMed:
Imino-C-nucleoside synthesis: heteroaryl lithium carbanion additions to a carbohydrate cyclic imine and nitrone.
PubMed:
Conformational restriction of nucleosides by spirocyclic annulation at C4' including synthesis of the complementary dideoxy and didehydrodideoxy analogues.
PubMed:
Synthesis and structural characterization of 1-(D-glycosyloxy)phthalazines.
PubMed:
EXAFS study of Sn(IV) immobilization by hardened cement paste and calcium silicate hydrates.
PubMed:
[The effects of fluoride-containing trace element agents on the growth of mutants of S. mutans].
PubMed:
Diels-Alder reactions of quinol lactones: a change of regioselectivity with stannic chloride catalysis.
PubMed:
Protective effect of HO-1 against oxidative stress in human hepatoma cell line (HepG2) is independent of telomerase enzyme activity.
PubMed:
Formation of vinyl halides via a ruthenium-catalyzed three-component coupling.
PubMed:
Stereoselective additions of chiral (E)-crotylsilanes to thionium ions: asymmetric synthesis of homoallylic thioethers.
PubMed:
Synthesis of 1,4-Phenanthrenequinones via Stannic Chloride-Induced Cyclizations.
PubMed:
Acylation of indole under Friedel-Crafts conditions-an improved method to obtain 3-acylindoles regioselectively.
PubMed:
Synthesis, conformational analysis, and biological activity of C-thioribonucleosides related to tiazofurin.
PubMed:
Synthesis of beta-D-Galf-(1-3)-D-GlcNAc by the trichloroacetamidate method and of beta-D-Galf-(1-6)-D-GlcNAc by SnCl4-promoted glycosylation.
PubMed:
Convenient synthesis of 2,3,9,10-tetraoxygenated protoberberine alkaloids and their 13-methyl alkaloids.
PubMed:
Synthesis and antitumor evaluation of cis-(1,2-diaminoethane) dichloroplatinum (II) complexes linked to 5- and 6-methyleneuracil and -uridine analogues.
PubMed:
Action of inorganic tin and organotins on a hydrocarbon-using yeast, Candida maltosa.
PubMed:
Determination of methylmercury in food commodities by gas-liquid chromatography with atomic emission detection.
PubMed:
Synthesis, structure, and antiproliferative activity of selenophenfurin, an inosine 5'-monophosphate dehydrogenase inhibitor analogue of selenazofurin.
PubMed:
Contact allergy to dental restorative materials in patients with oral lichenoid lesions.
PubMed:
Diastereoselectivity in the Mukaiyama-Michael Reaction Employing alpha-Acyl beta,gamma-Unsaturated Phosphonates.
PubMed:
Synthesis of sulfated octadecyl ribo-oligosaccharides with potent anti-AIDS virus activity by ring-opening polymerization of a 1,4-anhydroribose derivative.
PubMed:
Furanfurin and thiophenfurin: two novel tiazofurin analogues. Synthesis, structure, antitumor activity, and interactions with inosine monophosphate dehydrogenase.
PubMed:
Differential heme oxygenase induction by stannous and stannic ions in the heart.
PubMed:
[4'-Branched nucleosides. II. Synthesis of 4'-hydroxymethyl derivatives of 2',3'-anhydronucleosides of the ribo- and lyxo-series].
PubMed:
Gas chromatographic determination of inorganic tin in rat urine after a single oral administration of stannous chloride and mono-, di-, and triphenyltin chloride.
PubMed:
Tin tetrachloride interaction with human hemoglobin.
PubMed:
[4'-Branched nucleosides. I. Synthesis of 3'-deoxy-3'-amino-4'-hydroxymethylnucleosides].
PubMed:
Cell division, chromosomal aberration, and micronuclei formation in human peripheral blood lymphocytes. Effect of stannic chloride on donor's age.
PubMed:
Cytotoxicity of tin on human peripheral lymphocytes in vitro.
PubMed:
De novo synthesis of carbohydrates by stereoselective aldol reaction: L-cladinose.
PubMed:
Transport of lead-203 at the blood-brain barrier during short cerebrovascular perfusion with saline in the rat.
PubMed:
Synthesis of N-beta-D-glucopyranosyl derivatives of barbital, phenobarbital, metharbital, and mephobarbital.
PubMed:
Synthesis of acyclonucleoside hydroxamic acids as inhibitors of ribonucleotide reductase.
PubMed:
Synthesis of galactofuranose disaccharides of biological significance.
PubMed:
Effects of stannic chloride on human leucocytes in vitro.
PubMed:
Improved synthesis and antitumor activity of 1-deazaadenosine.
PubMed:
Synthesis and antiherpes virus activity of phosphate and phosphonate derivatives of 9-[(1,3-dihydroxy-2-propoxy)methyl]guanine.
PubMed:
Synthesis of pyrrolidine derivatives with pharmacological activity. XI. The Lora-Tamayo reaction of 3-methyl-1,1-diphenyl-1,4-butanediol with acetonitrile-stannic chloride complex. Synthesis of 1,2,5-trimethyl-3-diphenylmethylenepyrrolidines.
PubMed:
Synthesis and antiviral evaluation of nucleosides of 5-methylimidazole-4-carboxamide.
PubMed:
Respiratory symptoms among glass bottle makers exposed to stannic chloride solution and other potentially hazardous substances.
PubMed:
Synthesis of 1-beta-D-ribofuranosyl-1,2-dihydropyrimidin-2-one derivatives and their biological activities.
PubMed:
Butyltin compounds in vitro inhibition of human platelet epinephrine-induced aggregation and blockade of epinephrine binding to platelets.
PubMed:
Comparison of methods to measure acute metal and organometal toxicity to natural aquatic microbial communities.
PubMed:
Adenosine deaminase inhibitors. Synthesis and biological evaluation of (+/-)-3,6,7,8-tetrahydro-3-[(2-hydroxyethoxy)methyl]imidazo[4,5-d] [1,3]diazepin-8-ol and some selected C-5 homologues of pentostatin.
PubMed:
The effect of stannous and stannic (tin) chloride on DNA in Chinese hamster ovary cells.
PubMed:
Potential radiosensitizing agents. 4. 2-Nitroimidazole nucleosides.
PubMed:
Synthesis of pyridazine analogues of the naturally occurring nucleosides cytidine, uridine, deoxycytidine, and deoxyuridine.
PubMed:
Synthesis and biological activity of 2'-deoxy-6-methyl-5-azacytidine and its alpha-D-anomer.
PubMed:
Imidazo[1,2-a]-s-triazine nucleosides. Synthesis and antiviral activity of the N-bridgehead guanine, guanosine, and guanosine monophosphate analogues of imidazo[1,2-a]-s-triazine.
PubMed:
Absorption, distribution and excretion of triphenyltin acetate and stannic chloride in the guinea pig.
PubMed:
[Studies on poisonous metals. IV. Absorption of stannic chloride from rat alimentary tract and effect of various food components on its absorption (author's transl)].
PubMed:
A general synthesis of N-glycosides. 6. On the mechanism of the stannic chloride catalyzed silyl Hilbert-Johnson reaction.
PubMed:
Synthesis and biological studies of 3-(beta-D-ribofuranosyl)-2,3,-dihydro-6H-1,3-oxazine-2,6-dione, a new pyrimidine nucleoside analog related to uridine.
PubMed:
A facile O-glycosidation using stannic chloride.
PubMed:
[Effect of stannic chloride on the behavior of heat-altered erythrocytes].
PubMed:
Synthesis and ion-exchange properties of thermally stable stannic selenite.
PubMed:
Stannic chloride treatment of infusion-fluid bottles to improve their mechanical strength.
PubMed:
[Superficial membrane of high molecular fluids; model studies on polyvinylpyrrolidone and dextran solutions after addition of stannic chloride].
PubMed:
[Toxicity of medical dose of stannic chloride in guinea pigs, rabbits and mice].
PubMed:
Systematic approach to the identification of toxic organic compounds isolated from tissues and fluids. III. Aquo-ferriate and stannic chloride tests.
PubMed:
SOME EFFECTS OF STANNOUS SULPHATE AND STANNIC CHLORIDE ON SEVERAL HERBACEOUS PLANTS.