pivaldehyde

2,2-dimethylpropionaldehyde

CAS: 630-19-3 C5 H10 O MW: 86.13390000

Identification

Namepivaldehyde
IUPAC2,2-dimethylpropanal
CAS Number630-19-3
EINECS211-134-6
FDA UNIISSC20260QW
Molecular FormulaC5 H10 O
Molecular Weight86.13390000
MDL NumberMFCD00006962
Nikkaji NumberJ102.084F
Beilstein506060
XlogP31.10 (est)

Regulatory

Physical Properties

Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Specific Gravity 0.77800 to 0.78500 @ 20.00 °C.
Pounds per Gallon - (est). 6.481 to 6.540
Refractive Index 1.37800 to 1.38100 @ 20.00 °C.
Flash Point 4.00 °F. TCC ( -15.56 °C. )
Soluble in water, 1.209e+004 mg/L @ 25 °C (est)

No sensory data available

Safety Information

Preferred SDSView
Oral/Parenteral ToxicityNot determined
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categorynatural substances and extractives
Recommendation for pivaldehyde usage levels up tonot for fragrance use.
Recommendation for pivaldehyde flavor usage levels up tonot for flavor use.

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Potential Uses

None Found

Natural Occurrence

found in nature

Synonyms

2,2- dimethyl propanal alpha,alpha- dimethyl propanal 2,2- dimethyl propionaldehyde alpha,alpha- dimethyl propionaldehyde 2,2- dimethylpropanal 2,2- dimethylpropionaldehyde neo pentanal pivalic aldehyde propanal, 2,2-dimethyl- trimethyl acetaldehyde PubMed: Chemoselectivity and stereoselectivity of cyclisation pathways leading to bicyclic tetramates controlled by ring-chain tautomerisation in thiazolidines. PubMed: Divinyl BODIPY derivative: Synthesis, photophysical properties, crystal structure, photostability and bioimaging. PubMed: Double stereodifferentiation in the catalytic asymmetric aziridination of imines prepared from α-chiral amines. PubMed: Asymmetric synthesis and evaluation of a hydroxyphenylamide voltage-gated sodium channel blocker in human prostate cancer xenografts. PubMed: Synthesis of P-stereogenic compounds via kinetic deprotonation and dynamic thermodynamic resolution of phosphine sulfides: opposite sense of induction using (-)-sparteine. PubMed: Analysis of an asymmetric addition with a 2:1 mixed lithium amide/n-butyllithium aggregate. PubMed: Diastereomeric Reissert compounds of isoquinoline and 6,7-dimethoxy-3,4-dihydroisoquinoline in stereoselective synthesis. PubMed: Origin of syn/anti diastereoselectivity in aldehyde and ketone crotylation reactions: a combined theoretical and experimental study. PubMed: Gas-phase synthesis and reactivity of the organomagnesates [CH3MgL2]- (L = Cl and O2CCH3): from ligand effects to catalysis. PubMed: Cinchona alkaloid-lewis acid catalyst systems for enantioselective ketene-aldehyde cycloadditions. PubMed: Reactions of superoxo and oxo metal complexes with aldehydes. Radical-specific pathways for cross-disproportionation of superoxometal ions and acylperoxyl radicals. PubMed: Rate acceleration of the Baylis-Hillman reaction in polar solvents (water and formamide). Dominant role of hydrogen bonding, not hydrophobic effects, is implicated. PubMed: Copper(II) complexes of novel N-alkylated derivatives of cis,cis-1,3,5-triaminocyclohexane. 1. Preparation and structure. PubMed: Asymmetric strecker synthesis of alpha-amino acids via a crystallization-induced asymmetric transformation using (R)-phenylglycine amide as chiral auxiliary. PubMed: Synthesis of Homoleptic Neopentoxide and Hydrido-Neopentoxide Trirhenium(III) Clusters.