triphenyl bismuth

bismuth, triphenyl-

CAS: 603-33-8 C18 H15 Bi MW: 440.29795000

Identification

Nametriphenyl bismuth
IUPACtriphenylbismuthane
CAS Number603-33-8
EINECS210-033-4
FDA UNIIR18732F41W
Molecular FormulaC18 H15 Bi
Molecular Weight440.29795000
MDL NumberMFCD00014064
Beilstein3905930

Regulatory

Physical Properties

Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Melting Point 77.60 °C. @ 760.00 mm Hg
Flash Point 32.00 °F. TCC ( 0.00 °C. ) (est)
Soluble in water, 0.01237 mg/L @ 25 °C (est)

No sensory data available

Safety Information

Preferred SDSView
Oral/Parenteral Toxicityintravenous-mouse LD50 180 mg/kg
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements', 'U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#01712']

Safety in Use

Categorypharmaceuticals / chemical synthisis
Recommendation for triphenyl bismuth usage levels up tonot for fragrance use.
Recommendation for triphenyl bismuth flavor usage levels up tonot for flavor use.

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Potential Uses

None Found

Natural Occurrence

not found in nature

Synonyms

aerotex bismuth, triphenyl- bismuthine, triphenyl- triphenylbismuth triphenylbismuthane PubMed: Photoreductive generation of amorphous bismuth nanoparticles using polysaccharides--bismuth-cellulose nanocomposites. PubMed: Novel triphenylantimony(V) and triphenylbismuth(V) complexes with benzoic acid derivatives: structural characterization, in vitro antileishmanial and antibacterial activities and cytotoxicity against macrophages. PubMed: Vascular alterations in the sprague-dawley rat mandible during intravenous bisphosphonate therapy. PubMed: Formation of bismuth(V) thiolates: protolysis and oxidation of triphenylbismuth(III) with heterocyclic thiols. PubMed: Relativistic effects in triphenylbismuth and their influence on molecular structure and spectroscopic properties. PubMed: Bismuth-ferrocene carboxylates: synthesis and structure. PubMed: Structural motifs in phenylbismuth heterocyclic carboxylates--secondary interactions leading to oligomers. PubMed: Photochemical synthesis of bismuth selenide nanocrystals in an aqueous micellar solution. PubMed: Multiferroic BiFeO3 thin films for multifunctional devices. PubMed: Structural and solution studies of phenylbismuth(III) sulfonate complexes and their activity against Helicobacter pylori. PubMed: A new resin-bonded retrograde filling material. PubMed: Inhibition of jack bean urease by organobismuth compounds. PubMed: Osteolytic potential of triphenyl bismuth as an alternative contrast medium in acrylic bone cement. PubMed: Effect of triphenyl bismuth on glass transition temperature and residual monomer content of acrylic bone cements. PubMed: Upon the intriguing stereoselective formation of organobismuth(V) complexes. PubMed: Molecular precursors for ferroelectric materials: synthesis and characterization of Bi2M2(mu-O)(sal)4(Hsal)4(OEt)2 and BiM4(mu-O)4(sal)4(Hsal)3(O(i)Pr)4 (sal = O2CC6H4O, Hsal = O2CC6H4OH) (M = Nb, Ta). PubMed: Cytotoxic effects of triphenylbismuth on rat thymocytes: comparisons with bismuth chloride and triphenyltin chloride. PubMed: The first bismuth phosphonate cluster. X-ray single crystal structure of [(ButPO3)10(ButPO3H)2Bi14O(10).3C6H(6).4H2O]. PubMed: Heterobimetallic bismuth-transition metal salicylate complexes as molecular precursors for ferroelectric materials. Synthesis and structure of Bi(2)M(2)(sal)(4)(Hsal)(4)(OR) (4) (M = Nb, Ta; R = CH(2)CH(3), CH(CH(3))(2)), Bi(2)Ti(3)(sal)(8)(Hsal)(2), and Bi(2)Ti(4)(O(i)Pr)(sal)(10)(Hsal) (sal = O(2)CC(6)H(4)-2-O; Hsal = O(2)CC(6)H(4)-2-OH). PubMed: Radiopacity in bone cements using an organo-bismuth compound. PubMed: The effect of triphenylbismuth on the radiopacity and performance properties of compression- and injection-molded denture resins. PubMed: Thermomechanical investigation of poly(methylmethacrylate) containing an organobismuth radiopacifying additive. PubMed: Development of a radiopaque, autopolymerizing dental acrylic resin. PubMed: Cytotoxicity evaluation of a new radiopaque resin additive--triphenyl bismuth. PubMed: [ON THE LABELLING OF TRIPHENYL-BISMUTH BY RADIOACTIVE BISMUTH: CHROMATOGRAPHIC STUDY].