zinc bromide

zinc dibromide

CAS: 7699-45-8 Br2 Zn MW: 225.18800000

Identification

Namezinc bromide
IUPACdibromozinc
CAS Number7699-45-8
EINECS231-718-4
FDA UNIIOO7ZBU9703
Molecular FormulaBr2 Zn
Molecular Weight225.18800000
MDL NumberMFCD00011294

Regulatory

Physical Properties

Appearance white crystalline noncombustible solid (est)
Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Specific Gravity 4.20100 @ 25.00 °C.
Flash Point 32.00 °F. TCC ( 0.00 °C. ) (est)

No sensory data available

Safety Information

Preferred SDSView
Oral/Parenteral ToxicityNot determined
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryinformation only not used for fragrances or flavors
Recommendation for zinc bromide usage levels up tonot for fragrance use.
Recommendation for zinc bromide flavor usage levels up tonot for flavor use.

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Potential Uses

None Found

Natural Occurrence

not found in nature

Synonyms

dibromozinc zinc bromide (ZnBr2) zinc dibromide PubMed: Formation of four different aromatic scaffolds from nitriles through tandem divergent catalysis. PubMed: Geminal silicon/zinc reagent as an equivalent of difluoromethylene bis-carbanion. PubMed: An efficient method for the construction of polysubstituted 4-pyridones via self-condensation of β-keto amides mediated by P2O5 and catalyzed by zinc bromide. PubMed: Tertiary amines as synthetic equivalents of vinyl cations: zinc bromide promoted coupling of propargylamines with α-isocyanoacetamides to give 2,4,5-trisubstituted oxazoles initiated by an internal redox process. PubMed: The 3,7-diazabicyclo[3.3.1]nonane scaffold for subtype selective nicotinic acetylcholine receptor (nAChR) ligands. Part 1: the influence of different hydrogen bond acceptor systems on alkyl and (hetero)aryl substituents. PubMed: The 3,7-diazabicyclo[3.3.1]nonane scaffold for subtype selective nicotinic acetylcholine receptor ligands. Part 2: carboxamide derivatives with different spacer motifs. PubMed: Zinc bromide promoted coupling of isonitriles with carboxylic acids to form 2,4,5-trisubstituted oxazoles. PubMed: The chain-like polynuclear coordination compounds (ZnBr2)n(18-crown-6)2 (n = 4, 6, 8, 10) and [Zn5Br9][N(Tf2)]. PubMed: Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2)N,N')zinc. PubMed: Room temperature syntheses of entirely diverse substituted β-fluorofurans. PubMed: 8-Hy-droxy-2-methyl-quinolinium dibromido(2-methyl-quinolin-8-olato-κN,O)zincate acetonitrile mono-solvate. PubMed: Direct synthesis of alkynylstannanes: ZnBr2 catalyst for the reaction of tributyltin methoxide and terminal alkynes. PubMed: Synthesis of tri- or tetrasubstituted pyrimidine derivatives through the [5+1] annulation of enamidines with either N,N-dimethylformamide dialkyl acetals or orthoesters and their application in a ring transformation of pyrimidines to pyrido[2,3-d]pyrimidin-5-one derivatives. 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PubMed: Halogeno(triazolyl)zinc complexes as molecular building blocks for metal-organic frameworks. PubMed: Asymmetric Rh-catalyzed intermolecular hydroacylation of 1,5-hexadiene with salicylaldehyde. PubMed: Tandem Blaise-alkenylation with unactivated alkynes: one-pot synthesis of alpha-vinylated beta-enaminoesters from nitriles. PubMed: Diastereodivergent addition of allenylzincs to aryl glyoxylates. PubMed: Insights into palladium-catalyzed cyanation of bromobenzene: additive effects on the rate-limiting step. PubMed: The first chemoselective tandem acylation of the Blaise reaction intermediate: a novel method for the synthesis of alpha-acyl-beta-enamino esters, key intermediate for pyrazoles. PubMed: Hydrous zinc halide-catalyzed aminosulfonation of hydrocarbons. PubMed: Nicotine aerosol generation from thermally reversible zinc halide complexes using the Staccato system. PubMed: Stereoselective glycosylations using benzoylated glucosyl halides with inexpensive promoters. PubMed: Highly regioselective synthesis of trisubstituted allenes via lithiation of 1-aryl-3-alkylpropadiene, subsequent transmetalation, and Pd-catalyzed Negishi coupling reaction. PubMed: (2S)-Ethyl 2-[(S(s))-benzyl-sulfinyl-amino]-3,3-dimethylbutanoate. PubMed: Nickel-catalyzed carboannulation reaction of o-bromobenzyl zinc bromide with unsaturated compounds. PubMed: Synthetic strategies to epoxydiynes and a key synthon of the neocarzinostatin chromophore. PubMed: An Efficient one-pot Biginelli condensation of aliphatic aldehydes catalyzed by zinc bromide under solvent-free conditions. PubMed: Toward a total synthesis of amphidinolide X and Y. The tetrahydrofuran-containing fragment C12-C21. PubMed: An efficient synthesis of epoxydiynes and a key fragment of neocarzinostatin chromophore. PubMed: The transthyretin-related protein: structural investigation of a novel protein family. PubMed: Synthesis of the multisubstituted halogenated olefins via cross-coupling of dihaloalkenes with alkylzinc bromides. PubMed: Silyl protecting groups for oligonucleotide synthesis removed by a ZnBr2 treatment. PubMed: Synthesis and photodynamic activity of novel asymmetrically substituted fluorinated phthalocyanines. PubMed: Small angle x-ray scattering of a supercritical electrolyte solution: the effect of density fluctuations on the hydration of ions. PubMed: Lewis acid catalysis in heterolysis reactions of glycol ether radicals mimicking diol dehydratase-catalyzed reactions. PubMed: Selective tert-butyl ester deprotection in the presence of acid labile protecting groups with use of ZnBr2. PubMed: Benzotriazolyl-mediated 1,2-shifts of electron-rich heterocycles. PubMed: Diastereoselective additions of chiral vinylzinc reagents to alpha-chiral aldehydes. PubMed: General and efficient insertion of carbons carrying benzotriazole. PubMed: Zinc- and indium-mediated ring-expansion reaction of alpha-halomethyl cyclic beta-keto esters in aqueous alcohol. PubMed: Mechanism of the electrochemical conversion of aryl halides to arylzinc compounds by cobalt catalysis in DMF/pyridine. PubMed: Metal-catalyzed silacyclopropanation of mono- and disubstituted alkenes. PubMed: An expedient route to the tetrazole analogues of alpha-amino acids. PubMed: Synthesis of 3,4-dihydro-2H-1,3,5-thiadiazines. PubMed: Synthesis and antimicrobial activities of N-substituted imides. PubMed: A facile synthesis of enantiopure 2-aziridinesulfinimines and their highly diastereoselective reactions with phosphite anions. PubMed: Preparations of Trisubstituted Hydrazines and Pyrazolidines from N-(1-Benzotriazolylalkyl)hydrazines. PubMed: Enantiopure N-Acyldihydropyridones as Synthetic Intermediates: Asymmetric Synthesis of (-)-Septicine and (-)-Tylophorine. PubMed: Sulfanyl- and selanyldifluoromethylphosphonates as a source of phosphonodifluoromethyl radicals and their addition onto alkenes. PubMed: Convenient syntheses of 6-methylpurine and related nucleosides. PubMed: alpha,alpha-gem-Difluorination of alpha-(alkylthio)acetophenone derivatives with N-fluoropyridinium salts. PubMed: An efficient synthesis of a 4'-phosphonodifluoromethyl-3'-formyl-phenylalanine containing SRC SH2 ligand. PubMed: [Halogenated anesthetic vaporizers: importance of maintenance regulations]. PubMed: General and Efficient Insertions of Carbons Carrying Aryl and Heteroaryl Groups: Synthesis of alpha-Aryl- and alpha-Heteroaryl-Substituted Ketones. PubMed: Novel and Efficient Insertions of Carbons Carrying O-, S-, and N-Linked Substituents: Synthesis of alpha-Alkoxyalkyl, alpha-(Alkylthio)alkyl, and alpha-(Carbazol-9-yl)alkyl Ketones. PubMed: Efficient Syntheses of Substituted Carbazoles and Cyclopent[b]indoles from 1-Methyl-3-(benzotriazol-1-ylmethyl)indole. PubMed: Facile preparation of phenyl 1-thioglycosides of partially methylated maltooligosaccharides by restricted thiolysis of fully methylated cyclodextrins. PubMed: Need for environmental quality guidelines based on ambient freshwater quality criteria in natural waters--case study "zinc". PubMed: Action of acid on oligoribonucleotide phosphotriester intermediates. Effect of released vicinal hydroxy functions. PubMed: Studies on transfer ribonucleic acids and related compounds. XLV. Block condensation of ribooligonucleotides containing 2'-O-tetrahydrofuranyl-5'-O-dimethoxytritylnucleosides. PubMed: Silica gel: an improved support for the solid-phase phosphotriester synthesis of oligonucleotides. PubMed: A TRANSLUCENT MEDIUM FOR BIOLOGICAL SHIELDING: ZINC BROMIDE FOR A TREATMENT-ROOM WINDOW. PubMed: THE METABOLISM OF THE VOLATILE AMINES: V. THE SPONTANEOUS FORMATION OF AMMONIA IN SHED BLOOD ON STANDING. PubMed: An improved zinc bromide shielding window.