Identification

Namebutyl levulinate
IUPACbutyl 4-oxopentanoate
CAS Number2052-15-5
EINECS218-143-4
FDA UNIIOI56208RTB
Molecular FormulaC9 H16 O3
Molecular Weight172.22412000
MDL NumberMFCD00009449
Nikkaji NumberJ95.002E
Beilstein1768453
CoE Number374

Regulatory

JECFA Food Flavoring608 butyl levulinate
DG SANTE Food Flavourings09.436 butyl 4-oxovalerate
FEMA Number2207
FDANo longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF)2052-15-5 ; BUTYL LEVULINATE
FDA RegulationFDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION

Physical Properties

Appearance colorless to pale yellow clear liquid (est)
Assay 97.00 to 100.00
Food Chemicals Codex Listed No
Boiling Point 106.00 to 108.00 °C. @ 5.50 mm Hg, 237.50 °C. @ 760.00 mm Hg
Acid Value 2.00 max. KOH/g
Vapor Pressure 0.038000 mmHg @ 25.00 °C. (est)
Flash Point 198.00 °F. TCC ( 92.22 °C. )
logP (o/w) 1.457 (est)
Soluble in alcohol
Similar Items note

Cosmetic Information

CosIngcosmetic data
Cosmetic Usesperfuming agents

Organoleptic Properties

Odor Description
at 100.00 %.
An herbaceous, waxy, fatty odor with savory applications
Taste Description
herbal
herbal

Safety Information

Preferred SDSView
European informationMost important hazard(s):
Human Experience4 % solution: no irritation or sensitization.
Oral/Parenteral Toxicityoral-rat LD50 > 5000 mg/kg
Dermal Toxicityskin-rabbit LD50 > 5000 mg/kg
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavor and fragrance agents
RIFM Fragrance Material Safety AssessmentSearch
Recommendation for butyl levulinate usage levels up to4.0000 % in the fragrance concentrate.
Maximised Survey-derived Daily Intakes (MSDI-EU)ND (μg/capita/day)
baked goods-
beverages(nonalcoholic)0.20000
beverages(alcoholic)-
breakfast cereal-
cheese-
chewing gum-
condiments / relishes-
confectionery froastings-
egg products-
fats / oils-
fish products-
frozen dairy-
fruit ices-
gelatins / puddings-
granulated sugar-
gravies-
hard candy-
imitation dairy-
instant coffee / tea-
jams / jellies-
meat products-
milk products-
nut products-
other grains-
poultry-
processed fruits-
processed vegetables-
reconstituted vegetables-
seasonings / flavors-
snack foods-
soft candy-
soups-
sugar substitutes-
sweet sauces-

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Potential Uses

FL bacon FR butter FR cherry FL chocolate cocoa FR fruit FR herbal FR honeydew waxy

Natural Occurrence

not found in nature

Synonyms

butyl 4-ketovalerate butyl 4-oxopentanoate N- butyl 4-oxopentanoate butyl 4-oxovalerate N- butyl acetopropionate butyl acetyl propionate butyl gamma-butyrolactone butyl laevulinate N- butyl laevulinate N- butyl levulinate levulinic acid butyl ester levulinic acid, butyl ester 4-keto pentanoic acid butyl ester pentanoic acid, 4-oxo-, butyl ester Google Patents: Process for the manufacture of levulinic acid and esters PubMed: Enhanced heterogeneous catalytic conversion of furfuryl alcohol into butyl levulinate. PubMed: Conversion of biomass-derived levulinate and formate esters into γ-valerolactone over supported gold catalysts. PubMed: Efficient conversion of furfuryl alcohol into alkyl levulinates catalyzed by an organic-inorganic hybrid solid acid catalyst. PubMed: Influences of metal cations on the determination of the alpha-oxocarboxylates as the methyl esters of the O-(2,3,4,5,6-pentafluorobenzyl)oximes by gas chromatography: the importance of accounting for matrix effects. PubMed: Comparative methodology in the determination of alpha-oxocarboxylates in aqueous solution ion chromatography versus gas chromatography after oximation, extraction and esterification.