(Z)-3-hexenal

cis-3-hexenal

CAS: 6789-80-6 C6 H10 O MW: 98.14490000 green green

Identification

Name(Z)-3-hexenal
IUPAC(Z)-hex-3-enal
CAS Number6789-80-6
EINECS229-854-4
FDA UNII6V54TKA96C
Molecular FormulaC6 H10 O
Molecular Weight98.14490000
MDL NumberMFCD00065446
Nikkaji NumberJ59.820H
Beilstein1720171
CoE Number2008

Regulatory

JECFA Food Flavoring316 cis-3-hexenal
DG SANTE Food Flavourings05.075 hex-3(cis)-enal
FEMA Number2561
FDANo longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF)6789-80-6 ; CIS-3-HEXENAL

Physical Properties

Appearance colorless clear liquid (est)
Assay 92.00 to 100.00 sum of isomers
Food Chemicals Codex Listed No
Specific Gravity 0.97600 to 0.98600 @ 25.00 °C.
Pounds per Gallon - (est). 8.121 to 8.205
Refractive Index 1.42700 to 1.43500 @ 20.00 °C.
Boiling Point 20.00 °C. @ 0.20 mm Hg
Vapor Pressure 11.202000 mmHg @ 25.00 °C. (est)
Flash Point 111.00 °F. TCC ( 43.89 °C. )
logP (o/w) 1.432 (est)
Soluble in alcohol

Cosmetic Information

CosIngcosmetic data
Cosmetic Usesperfuming agents

Organoleptic Properties

Odor Strength high ,
Substantivity 240 hour(s) at 100.00 %
Odor Description
at 1.00 % in dipropylene glycol.
powerful green, grassy, apple-like
apple; grape; lilac; orange; floral; pear; pineapple; strawberry; green; vegetable
Odor sample from Bedoukian Research, Inc.
Taste Description
sharp green grassy cooked apple apple skin
Sharp, green, grassy
apple

Safety Information

Preferred SDSView
European informationMost important hazard(s):
Oral/Parenteral Toxicitygavage-rat LD50 [sex: M/F] 1560 mg/kg
Dermal Toxicityskin-rabbit LD50 3700 mg/kg
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavor and fragrance agents
RIFM Fragrance Material Safety AssessmentSearch
Recommendation for (Z)-3-hexenal usage levels up to0.5000 % in the fragrance concentrate.
Maximised Survey-derived Daily Intakes (MSDI-EU)4.10 (μg/capita/day)
Structure ClassI
baked goods-
beverages(nonalcoholic)-
beverages(alcoholic)-
breakfast cereal-
cheese-
chewing gum-
condiments / relishes-
confectionery froastings-
egg products-
fats / oils-
fish products-
frozen dairy-
fruit ices-
gelatins / puddings-
granulated sugar-
gravies-
hard candy-
imitation dairy-
instant coffee / tea-
jams / jellies-
meat products-
milk products-
nut products-
other grains-
poultry-
processed fruits-
processed vegetables-
reconstituted vegetables-
seasonings / flavors-
snack foods-
soft candy-
soups-
sugar substitutes-
sweet sauces-

Advanced Biotech. Inc.

Inspired by Nature

A diverse range of products, all meeting our stringent commitment to quality.

View All Website 973-339-6242 info@adv-bio.com

Bedoukian Research, Inc.

Perfecting the Art of Chemistry

Working closely with our customers to meet their requirements.

View All Website 1-203-830-4000 customerservice@bedoukian.com

BOC Sciences

Best of Chemicals Supplier

Quality supplier of research chemicals and biochemicals including inhibitors, building blocks, GMP Products, impurities and metabolites, APIs for Veterinary, Natural Compounds, ADCs, Stem Cell Molecul...

View All Website 1-631-485-4226 account@bocsci.com

CJ Latta & Associates, LLC

Extensive Line

Aromatic Chemicals and Organic Acids.

View All Website (630) 240-8079 chiplatta@msn.com

M&U International LLC

Steady supply & demand

Meeting customers increasing demands at home as well as abroad.

View All Website 908-359-9000 sales@mu-intel.com

Penta International Corporation

Chemistry innovation

At Penta, our products and services help businesses do business better.

View All Website (973) 740-2300 lisaa@pentamfg.com

Sigma-Aldrich

Complete Supply Chain

The perfect blend of products and services that bring your creativity to life.

View All Website 800-244-1173 ff@sial.com

Synerzine, Inc.

Innovation. Customization. Aroma Ingredients.

Synerzine is a leading supplier of flavor and fragrance ingredients.

View All Website (404) 524-6744 info@synerzine.com

R C Treatt and Co Ltd

Innovative ingredient solutions

World-leading innovative ingredient solutions provider for the flavour, fragrance and FMCG industries.

View All Website +1 863 668 9500 enquiries@treatt.com

Potential Uses

FR apple FR banana FR berry FR blackberry FR currant red currant FR grape grass FR green FR hyacinth leaf FL leek FR lilac FL pea green pea FR plum strawberry leaf FR tea green tea FR tomato leaf trassi

Natural Occurrence

apple fruit PMC banana fruit 469 ppm PMC blackberry fruit PMC capsicum currant red currant fruit endive ginger grape guava fruit headspace reunion @ 2.00% Data lallemantia peltata (l.) fisch. et mey. oil turkey @ 8.30% Data leek lovage leaf malus sieversii PbMd mango fruit plum fruit potato chip PMC raspberry red raspberry fruit strawberry wild strawberry fruit tea black tea tea green tea tea rooibos tea tomato tomato 1063 ppm trassi cooked trassi

Synonyms

(Z)- hex-3-en-1-al (3Z)- hex-3-enal (Z)- hex-3-enal hex-3(cis)-enal (Z)-3- hexen-1-al cis-3- hexen-1-al cis-3- hexen-1-al (50% in triacetin) cis-3- hexen-1-al (neat) (Z)-3- hexenal 3-(Z)- hexenal cis-3- hexenal cis-3- hexenal (50% in triacetin) cis-3- hexenal pure 3- hexenal, (3Z)- 3- hexenal, (Z)- 3- hexenal, cis- (Z)-beta,gamma- hexylenic aldehyde Info: cis-3-HEXENAL, trans-2-HEXENAL and 'GREEN GRASS' SMELL US Patents: Derivatives of cis-3-hexenol and process for producing compositions of matter containing cis-3-hexenal and products produced thereby and organoleptic uses thereof PubMed: Key volatile aroma compounds of three black velvet tamarind (Dialium) fruit species. Info: Volatile Flavor Components in Bogyojosaeng and Suhong Cultivars of Strawberry (Fragaria ananassa Duch.) US Patents: Uses of hexenol derivatives in augementing or enhancing the aroma or taste of smoking tobacco compositions and smoking tobacco articles PubMed: Characterization of the most aroma-active compounds in cherry tomato by application of the aroma extract dilution analysis. US Patents: Compositions of matter containing cis-3-hexenal PubMed: Comparative analysis of aroma compounds and sensorial features of strawberry and lemon guavas (Psidium cattleianum Sabine). PubMed: The 9-lipoxygenase Osr9-LOX1 interacts with the 13-lipoxygenase-mediated pathway to regulate resistance to chewing and piercing-sucking herbivores in rice. PubMed: Model studies on the key aroma compounds formed by an oxidative degradation of ω-3 fatty acids initiated by either copper(II) ions or lipoxygenase. PubMed: Analyzing blends of herbivore-induced volatile organic compounds with factor analysis: revisiting "cotton plant, Gossypium hirsutum L., defense in response to nitrogen fertilization". PubMed: Influence of phenols mass fraction in olive (Olea europaea L.) paste on volatile compounds in Buža cultivar virgin olive oil. PubMed: Production of phenolics and the emission of volatile organic compounds by perennial ryegrass (Lolium perenne L.)/Neotyphodium lolii association as a response to infection by Fusarium poae. PubMed: Odour-active compounds in guava (Psidium guajava L. cv. Red Suprema). PubMed: Plasma membrane potential depolarization and cytosolic calcium flux are early events involved in tomato (Solanum lycopersicon) plant-to-plant communication. PubMed: Kinetic study of the daytime atmospheric fate of (Z)-3-hexenal. PubMed: Volatile generation in bell peppers during frozen storage and thawing using selected ion flow tube mass spectrometry (SIFT-MS). PubMed: Differential metabolisms of green leaf volatiles in injured and intact parts of a wounded leaf meet distinct ecophysiological requirements. PubMed: Quality evaluation of olive oil by statistical analysis of multicomponent stable isotope dilution assay data of aroma active compounds. PubMed: Gastrophysa polygoni herbivory on Rumex confertus: single leaf VOC induction and dose dependent herbivore attraction/repellence to individual compounds. PubMed: Volatile composition of four southern highbush blueberry cultivars and effect of growing location and harvest date. PubMed: Effect of enzymes on strawberry volatiles during storage, at different ripeness level, in different cultivars, and during eating. PubMed: Effect of enzyme activity and frozen storage on jalapeño pepper volatiles by selected ion flow tube-mass spectrometry. PubMed: Fusarium infection in maize: volatile induction of infected and neighboring uninfected plants has the potential to attract a pest cereal leaf beetle, Oulema melanopus. PubMed: Specific regulation of pyrethrin biosynthesis in Chrysanthemum cinerariaefolium by a blend of volatiles emitted from artificially damaged conspecific plants. PubMed: Cereal crop volatile organic compound induction after mechanical injury, beetle herbivory (Oulema spp.), or fungal infection (Fusarium spp.). PubMed: Effects of n-hexanal on dopamine release in the striatum of living rats. PubMed: Microdistillation and analysis of volatiles from eight ornamental Salvia taxa. PubMed: Relation between developmental stage, sensory properties, and volatile content of organically and conventionally grown pac choi (Brassica rapa var. Mei Qing Choi). PubMed: Comparison of volatile release in tomatillo and different varieties of tomato during chewing. PubMed: Comparison of tomatillo and tomato volatile compounds in the headspace by selected ion flow tube mass spectrometry (SIFT-MS). PubMed: The tea weevil, Myllocerinus aurolineatus, is attracted to volatiles induced by conspecifics. PubMed: Characteristic aroma-active compounds of Korean perilla (Perilla frutescens Britton) leaf. PubMed: Characterization of the key aroma compounds in pink guava (Psidium guajava L.) by means of aroma re-engineering experiments and omission tests. PubMed: In situ investigation of leaf water status by portable unilateral nuclear magnetic resonance. PubMed: Direct fungicidal activities of C6-aldehydes are important constituents for defense responses in Arabidopsis against Botrytis cinerea. PubMed: Characterization of the aroma-active compounds in pink guava (Psidium guajava, L.) by application of the aroma extract dilution analysis. PubMed: Characterization of odor-active compounds in extracts obtained by simultaneous extraction/distillation from moroccan black olives. PubMed: A novel lipoxygenase gene from developing rice seeds confers dual position specificity and responds to wounding and insect attack. PubMed: Cut-induced VOC emissions from agricultural grasslands. PubMed: Genetic diversity of volatile components in Xinjiang Wild Apple (Malus sieversii). PubMed: The atmospheric photolysis of E-2-hexenal, Z-3-hexenal and E,E-2,4-hexadienal. PubMed: ETR1-, JAR1- and PAD2-dependent signaling pathways are involved in C6-aldehyde-induced defense responses of Arabidopsis. PubMed: Role of the lipoxygenase/lyase pathway of host-food plants in the host searching behavior of two parasitoid species, Cotesia glomerata and Cotesia plutellae. PubMed: Potent odorants characterize the aroma quality of leaves and stalks in raw and boiled celery. PubMed: Comparison of volatile constituents of Persicaria odorata(Lour.) Soják (Polygonum odoratum Lour.) and Persicaria hydropiper L. Spach (Polygonum hydropiper L.). PubMed: Characterization of (E,E,Z)-2,4,6-nonatrienal as a character impact aroma compound of oat flakes. PubMed: Volatile C6-aldehydes and Allo-ocimene activate defense genes and induce resistance against Botrytis cinerea in Arabidopsis thaliana. PubMed: Rapid determination of C6-aldehydes in tomato plant emission by gas chromatography-mass spectrometry and solid-phase microextraction with on-fiber derivatization. PubMed: Screening for key odorants in Moroccan green olives by gas chromatography-olfactometry/aroma extract dilution analysis. PubMed: Some unusual minor volatile components of tomato. PubMed: Stimulation of the lipoxygenase pathway is associated with systemic resistance induced in bean by a nonpathogenic Pseudomonas strain. PubMed: Volatile constituents and key odorants in leaves, buds, flowers, and fruits of Laurus nobilis L. PubMed: Airborne signals prime plants against insect herbivore attack. PubMed: Flux of organic compounds from grass measured by relaxed eddy accumulation technique. PubMed: Volatile constituents of uncooked rhubarb (Rheum rhabarbarum L.) stalks. PubMed: Odor-active compounds of Iberian hams with different aroma characteristics. PubMed: Character impact odorants of the apple cultivars Elstar and Cox Orange. PubMed: Application of the porapak q column extraction method for tomato flavor volatile analysis. PubMed: Characterization of the most odor-active compounds of Iberian ham headspace. PubMed: The homolytic and heterolytic fatty acid hydroperoxide lyase-like activities of hematin. PubMed: On-line analysis of reactive VOCs from urban lawn mowing. PubMed: Evaluation of aroma differences between hand-squeezed juices from Valencia late and Navel oranges by quantitation of key odorants and flavor reconstitution experiments. PubMed: Potato tubers exhibit both homolytic and heterolytic hydroperoxide fatty acid-cleaving activities. PubMed: Comparison of the most odor-active compounds in fresh and dried hop cones (Humulus lupulus L. variety spalter select) based on GC-olfactometry and odor dilution techniques. PubMed: Characterization of the most odor-active volatiles in fresh, hand-squeezed juice of grapefruit (Citrus paradisi Macfayden). PubMed: Aroma chemicals isolated and identified from leaves of Aloe arborescens Mill. Var. Natalensis Berger. PubMed: Overexpression of a cytoplasm-localized allene oxide synthase promotes the wound-induced accumulation of jasmonic acid in transgenic tobacco. PubMed: Molecular cloning and expression of Arabidopsis fatty acid hydroperoxide lyase. PubMed: Characterization of aroma volatiles in tomatoes by sensory analyses. PubMed: Photosynthetic photon flux, photoperiod, and temperature effects on emissions of (Z)-3-hexenal, (Z)-3-hexenol, and (Z)-3-hexenyl acetate from lettuce. PubMed: A system and methodology for measuring volatile organic compounds produced by hydroponic lettuce in a controlled environment. PubMed: Diurnal cycle of emission of induced volatile terpenoids by herbivore-injured cotton plant. PubMed: Isolation and identification of allelochemicals that attract the larval parasitoid,Cotesia marginiventris (Cresson), to the microhabitat of one of its hosts.