meta-toluidine
benzenamine, 3-methyl-
Identification
| Name | meta-toluidine |
| CAS Number | 108-44-1 |
| EINECS | 203-597-8 |
| FDA UNII | 006FKQ96T3 |
| Molecular Formula | C7 H9 N |
| Molecular Weight | 107.15573000 |
| MDL Number | MFCD00007808 |
| Nikkaji Number | J3.249B |
| Beilstein | 0635944 |
| XlogP3 | 1.40 (est) |
Regulatory
Physical Properties
| Appearance | colorless to pale yellow clear liquid (est) |
| Assay | 95.00 to 100.00 |
| Food Chemicals Codex Listed | No |
| Boiling Point | 203.00 to 204.00 °C. @ 760.00 mm Hg, 119.00 to 120.00 °C. @ 50.00 mm Hg |
| Vapor Pressure | 0.303000 mmHg @ 25.00 °C. (est) |
| Flash Point | 186.00 °F. TCC ( 85.60 °C. ) (est) |
| logP (o/w) | 1.400 |
| Soluble in | water, 7085 mg/L @ 25 °C (est) |
No sensory data available
Safety Information
| Preferred SDS | View |
| Oral/Parenteral Toxicity | oral-bird - wild LD50 242 mg/kg |
| Dermal Toxicity | skin-rabbit LD50 3250 mg/kg |
| Inhalation Toxicity | Not determined |
GHS Classification
['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']
Safety in Use
| Category | pharmaceuticals / chemical synthisis |
| Recommendation for meta-toluidine usage levels up to | not for fragrance use. |
| Recommendation for meta-toluidine flavor usage levels up to | not for flavor use. |
Potential Uses
Natural Occurrence
Synonyms
3-
amino-1-methylbenzene
3-
aminotoluene
m-
aminotoluene
benzenamine, 3-methyl-
3-
methylalanine
3-
methylaniline
3-
methylbenzenamine
3-
methylphenylamine
3-
toluidine
m-
toluidine
m-
tolylamine
PubMed:
Quantification of Nitrogen compounds in diesel fuel samples by comprehensive two-dimensional gas chromatography coupled with quadrupole mass spectrometry.
PubMed:
Exposure of hairdressers to ortho- and meta-toluidine in hair dyes.
PubMed:
Microscopically based calculations of the free energy barrier and dynamic length scale in supercooled liquids: the comparative role of configurational entropy and elasticity.
PubMed:
Optical storage in azobenzene-containing epoxy polymers processed as Langmuir Blodgett films.
PubMed:
Density and confinement effects of glass forming m-toluidine in nanoporous Vycor investigated by depolarized dynamic light scattering.
PubMed:
Factors affecting the selectivity of the photocatalytic conversion of nitroaromatic compounds over TiO2 to valuable nitrogen-containing organic compounds.
PubMed:
Laser therapy as an effective method for implant surface decontamination: a histomorphometric study in rats.
PubMed:
Evaluation of the Dyre shoving model using dynamic data near the glass temperature.
PubMed:
Comparative studies of the dynamics in viscous liquids by means of dielectric spectroscopy and field cycling NMR.
PubMed:
Adsorption and separation of reactive aromatic isomers and generation and stabilization of their radicals within cadmium(II)-triazole metal-organic confined space in a single-crystal-to-single-crystal fashion.
PubMed:
Synthesis, characterization and cytotoxicity of iodo-bridged binuclear platinum(II) complexes.
PubMed:
High resolution electronic spectroscopy of o- and m-toluidine in the gas phase. barrier height determinations for the methyl group torsional motions.
PubMed:
A direct test of the correlation between elastic parameters and fragility of ten glass formers and their relationship to elastic models of the glass transition.
PubMed:
Comparison of methods for identifying ano-genital injury after consensual intercourse.
PubMed:
Tuning the supramolecular chirality of polyaniline by methyl substitution.
PubMed:
The measurement of mechanical properties of glycerol, m-toluidine, and sucrose benzoate under consideration of corrected rheometer compliance: an in-depth study and review.
PubMed:
Monoarylamines in the general population--a cross-sectional population-based study including 1004 Bavarian subjects.
PubMed:
Analysis of a heterodyne-detected transient-grating experiment on a molecular supercooled liquid. II. Application to m-toluidine.
PubMed:
Structure-property relationships of DEAEM-containing bone cements: effect of the substitution of a methylene group by an aromatic ring.
PubMed:
On the correlation between fragility and stretching in glass-forming liquids.
PubMed:
2-[(1S,3S)-3-Acetyl-2,2-dimethyl-cyclo-butyl]-N-(m-tol-yl)acetamide.
PubMed:
Dynamic shear modulus of glycerol: corrections due to instrument compliance.
PubMed:
Tuning the structure of SDS micelles by substituted anilinium ions.
PubMed:
Shear stress relaxation and physical aging study on simple glass-forming materials.
PubMed:
Effect of dietary fat on selected parameters of toxicity following 1- or 3-month exposure of rats to toluidine isomers.
PubMed:
Ergodic to nonergodic transition in liquids with a local order: the case of m-toluidine.
PubMed:
Slow dynamics of supercooled m-toluidine investigated by mechanical spectroscopy.
PubMed:
Dynamics of glassy and liquid m-toluidine investigated by high-resolution dielectric spectroscopy.
PubMed:
Two biologically active thiophene-3-carboxamide derivatives.
PubMed:
Study of charge transfer complexes of menadione (vitamin K3) with a series of anilines.
PubMed:
New one-dimensional azido-bridged manganese(II) coordination polymers exhibiting alternating ferromagnetic-antiferromagnetic interactions: structural and magnetic studies.
PubMed:
Analysis of some aromatic amines by means of derivative spectrophotometry.
PubMed:
Solid-phase microextraction of monocyclic aromatic amines using novel fibers coated with crown ether.
PubMed:
Liquid chromatographic/mass spectrometric determination of desmedipham and phenmedipham and their metabolites in soil.
PubMed:
Haemoglobin adducts from aromatic amines in children in relation to area of residence and exposure to environmental tobacco smoke.
PubMed:
Structures of mutagens produced by the co-mutagen norharman with o- and m-toluidine isomers.
PubMed:
Biological monitoring of phenmedipham: determination of m-toluidine in urine.
PubMed:
Determination of the levels of aromatic amines in indoor and outdoor air in Italy.
PubMed:
Assay of tolnaftate and related impurities by isocratic supercritical fluid chromatography.
PubMed:
Enzymatic method for assaying uric acid in serum with a new tetrazolium salt produces water-soluble formazan dye.
PubMed:
Formation of DNA adducts by the co-mutagen norharman with aromatic amines.
PubMed:
Biomonitoring of urinary aromatic amines and arylamine hemoglobin adducts in exposed workers and nonexposed control persons.
PubMed:
Magnetic state of poly(m-toluidine): Dependence on absorbed water.
PubMed:
Serum sialic acid enzymatic assay based on microtitre plates: application for measuring capillary serum sialic acid concentrations.
PubMed:
Primary aromatic amines from side-stream cigarette smoke are common contaminants of indoor air.
PubMed:
Liquid film pertraction-A liquid membrane preconcentration technique.
PubMed:
Automated microanalysis of creatinine by coupled enzyme reactions.
PubMed:
Adsorptive stripping voltammetry determination of molybdenum(VI) in water and soil.
PubMed:
Enzymatic assay of 3-mercaptopyruvate sulfurtransferase activity in human red blood cells using pyruvate oxidase.
PubMed:
Rapid enzymatic analysis of plasma for tyrosine.
PubMed:
[Gas chromatography methods of the measurement of concentrations of 2-bromo-6-chloro-4-nitroaniline, N,N-dioxyethyl-M-chloroaniline, N-oxyethyl-N-beta-cyanoethylaniline and N-ethyl-N-beta-cyanoethyl-M-toluidine in the working zone air].
PubMed:
[Plasmids for biphenyl, chlorobiphenyl and metatoluylate degradation from Pseudomonas putida].
PubMed:
Photodynamic inactivation of rubella virus enhances recombination with a latent virus of a baby hamster kidney cell line BHK21.
PubMed:
Test-strip method for measuring lactate in whole blood.
PubMed:
Histochemical demonstration of neurotoxic esterase.
PubMed:
Anticalcification treatments of bioprosthetic heart valves: in vivo studies in sheep.
PubMed:
A colorimetric assay for the measurement of D-glucose consumption by cultured cells.
PubMed:
The effects of anticalcification treatments on bioprosthetic heart valves implanted in sheep.
PubMed:
A rapid assay method for ammonia using glutamine synthetase from glutamate-producing bacteria.
PubMed:
Kinetic assay of gamma-glutamyltransferase with use of bilirubin oxidase as a coupled enzyme.
PubMed:
Effect of toluidines on drug metabolizing enzymes in rat liver, kidney and lung.
PubMed:
[The synthesis, analysis, stability and biotransformation of N-(3-methylphenyl)-N'-cyanobenzamidine and analogues (author's transl)].
PubMed:
Metabolism of ortho-, meta-, and para-toluidine in the adult male rat.
PubMed:
Testing of twenty-one environmental aromatic amines or derivatives for long-term toxicity or carcinogenicity.
PubMed:
Determination of aminocresol isomers by high-speed liquid chromatography.
PubMed:
Percutaneous penetration and metabolism of topical (14C)flutamide in men.
PubMed:
Disposition of a new, nonsteroid, antiandrogen, alpha,alpha,alpha-trifluoro-2-methyl-4'-nitro-m-propionotoluidide (Flutamide), in men following a single oral 200 mg dose.