meta-toluidine

benzenamine, 3-methyl-

CAS: 108-44-1 C7 H9 N MW: 107.15573000

Identification

Namemeta-toluidine
CAS Number108-44-1
EINECS203-597-8
FDA UNII006FKQ96T3
Molecular FormulaC7 H9 N
Molecular Weight107.15573000
MDL NumberMFCD00007808
Nikkaji NumberJ3.249B
Beilstein0635944
XlogP31.40 (est)

Regulatory

Physical Properties

Appearance colorless to pale yellow clear liquid (est)
Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Boiling Point 203.00 to 204.00 °C. @ 760.00 mm Hg, 119.00 to 120.00 °C. @ 50.00 mm Hg
Vapor Pressure 0.303000 mmHg @ 25.00 °C. (est)
Flash Point 186.00 °F. TCC ( 85.60 °C. ) (est)
logP (o/w) 1.400
Soluble in water, 7085 mg/L @ 25 °C (est)

No sensory data available

Safety Information

Preferred SDSView
Oral/Parenteral Toxicityoral-bird - wild LD50 242 mg/kg
Dermal Toxicityskin-rabbit LD50 3250 mg/kg
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categorypharmaceuticals / chemical synthisis
Recommendation for meta-toluidine usage levels up tonot for fragrance use.
Recommendation for meta-toluidine flavor usage levels up tonot for flavor use.

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Potential Uses

None Found

Natural Occurrence

not found in nature

Synonyms

3- amino-1-methylbenzene 3- aminotoluene m- aminotoluene benzenamine, 3-methyl- 3- methylalanine 3- methylaniline 3- methylbenzenamine 3- methylphenylamine 3- toluidine m- toluidine m- tolylamine PubMed: Quantification of Nitrogen compounds in diesel fuel samples by comprehensive two-dimensional gas chromatography coupled with quadrupole mass spectrometry. PubMed: Exposure of hairdressers to ortho- and meta-toluidine in hair dyes. PubMed: Microscopically based calculations of the free energy barrier and dynamic length scale in supercooled liquids: the comparative role of configurational entropy and elasticity. PubMed: Optical storage in azobenzene-containing epoxy polymers processed as Langmuir Blodgett films. PubMed: Density and confinement effects of glass forming m-toluidine in nanoporous Vycor investigated by depolarized dynamic light scattering. PubMed: Factors affecting the selectivity of the photocatalytic conversion of nitroaromatic compounds over TiO2 to valuable nitrogen-containing organic compounds. PubMed: Laser therapy as an effective method for implant surface decontamination: a histomorphometric study in rats. PubMed: Evaluation of the Dyre shoving model using dynamic data near the glass temperature. PubMed: Comparative studies of the dynamics in viscous liquids by means of dielectric spectroscopy and field cycling NMR. PubMed: Adsorption and separation of reactive aromatic isomers and generation and stabilization of their radicals within cadmium(II)-triazole metal-organic confined space in a single-crystal-to-single-crystal fashion. PubMed: Synthesis, characterization and cytotoxicity of iodo-bridged binuclear platinum(II) complexes. PubMed: High resolution electronic spectroscopy of o- and m-toluidine in the gas phase. barrier height determinations for the methyl group torsional motions. PubMed: A direct test of the correlation between elastic parameters and fragility of ten glass formers and their relationship to elastic models of the glass transition. PubMed: Comparison of methods for identifying ano-genital injury after consensual intercourse. PubMed: Tuning the supramolecular chirality of polyaniline by methyl substitution. PubMed: The measurement of mechanical properties of glycerol, m-toluidine, and sucrose benzoate under consideration of corrected rheometer compliance: an in-depth study and review. PubMed: Monoarylamines in the general population--a cross-sectional population-based study including 1004 Bavarian subjects. PubMed: Analysis of a heterodyne-detected transient-grating experiment on a molecular supercooled liquid. II. Application to m-toluidine. PubMed: Structure-property relationships of DEAEM-containing bone cements: effect of the substitution of a methylene group by an aromatic ring. PubMed: On the correlation between fragility and stretching in glass-forming liquids. PubMed: 2-[(1S,3S)-3-Acetyl-2,2-dimethyl-cyclo-butyl]-N-(m-tol-yl)acetamide. PubMed: Dynamic shear modulus of glycerol: corrections due to instrument compliance. PubMed: Tuning the structure of SDS micelles by substituted anilinium ions. PubMed: Shear stress relaxation and physical aging study on simple glass-forming materials. PubMed: Effect of dietary fat on selected parameters of toxicity following 1- or 3-month exposure of rats to toluidine isomers. PubMed: Ergodic to nonergodic transition in liquids with a local order: the case of m-toluidine. PubMed: Slow dynamics of supercooled m-toluidine investigated by mechanical spectroscopy. PubMed: Dynamics of glassy and liquid m-toluidine investigated by high-resolution dielectric spectroscopy. PubMed: Two biologically active thiophene-3-carboxamide derivatives. PubMed: Study of charge transfer complexes of menadione (vitamin K3) with a series of anilines. PubMed: New one-dimensional azido-bridged manganese(II) coordination polymers exhibiting alternating ferromagnetic-antiferromagnetic interactions: structural and magnetic studies. PubMed: Analysis of some aromatic amines by means of derivative spectrophotometry. PubMed: Solid-phase microextraction of monocyclic aromatic amines using novel fibers coated with crown ether. PubMed: Liquid chromatographic/mass spectrometric determination of desmedipham and phenmedipham and their metabolites in soil. PubMed: Haemoglobin adducts from aromatic amines in children in relation to area of residence and exposure to environmental tobacco smoke. PubMed: Structures of mutagens produced by the co-mutagen norharman with o- and m-toluidine isomers. PubMed: Biological monitoring of phenmedipham: determination of m-toluidine in urine. PubMed: Determination of the levels of aromatic amines in indoor and outdoor air in Italy. PubMed: Assay of tolnaftate and related impurities by isocratic supercritical fluid chromatography. PubMed: Enzymatic method for assaying uric acid in serum with a new tetrazolium salt produces water-soluble formazan dye. PubMed: Formation of DNA adducts by the co-mutagen norharman with aromatic amines. PubMed: Biomonitoring of urinary aromatic amines and arylamine hemoglobin adducts in exposed workers and nonexposed control persons. PubMed: Magnetic state of poly(m-toluidine): Dependence on absorbed water. PubMed: Serum sialic acid enzymatic assay based on microtitre plates: application for measuring capillary serum sialic acid concentrations. PubMed: Primary aromatic amines from side-stream cigarette smoke are common contaminants of indoor air. PubMed: Liquid film pertraction-A liquid membrane preconcentration technique. PubMed: Automated microanalysis of creatinine by coupled enzyme reactions. PubMed: Adsorptive stripping voltammetry determination of molybdenum(VI) in water and soil. PubMed: Enzymatic assay of 3-mercaptopyruvate sulfurtransferase activity in human red blood cells using pyruvate oxidase. PubMed: Rapid enzymatic analysis of plasma for tyrosine. PubMed: [Gas chromatography methods of the measurement of concentrations of 2-bromo-6-chloro-4-nitroaniline, N,N-dioxyethyl-M-chloroaniline, N-oxyethyl-N-beta-cyanoethylaniline and N-ethyl-N-beta-cyanoethyl-M-toluidine in the working zone air]. PubMed: [Plasmids for biphenyl, chlorobiphenyl and metatoluylate degradation from Pseudomonas putida]. PubMed: Photodynamic inactivation of rubella virus enhances recombination with a latent virus of a baby hamster kidney cell line BHK21. PubMed: Test-strip method for measuring lactate in whole blood. PubMed: Histochemical demonstration of neurotoxic esterase. PubMed: Anticalcification treatments of bioprosthetic heart valves: in vivo studies in sheep. PubMed: A colorimetric assay for the measurement of D-glucose consumption by cultured cells. PubMed: The effects of anticalcification treatments on bioprosthetic heart valves implanted in sheep. PubMed: A rapid assay method for ammonia using glutamine synthetase from glutamate-producing bacteria. PubMed: Kinetic assay of gamma-glutamyltransferase with use of bilirubin oxidase as a coupled enzyme. PubMed: Effect of toluidines on drug metabolizing enzymes in rat liver, kidney and lung. PubMed: [The synthesis, analysis, stability and biotransformation of N-(3-methylphenyl)-N'-cyanobenzamidine and analogues (author's transl)]. PubMed: Metabolism of ortho-, meta-, and para-toluidine in the adult male rat. PubMed: Testing of twenty-one environmental aromatic amines or derivatives for long-term toxicity or carcinogenicity. PubMed: Determination of aminocresol isomers by high-speed liquid chromatography. PubMed: Percutaneous penetration and metabolism of topical (14C)flutamide in men. PubMed: Disposition of a new, nonsteroid, antiandrogen, alpha,alpha,alpha-trifluoro-2-methyl-4'-nitro-m-propionotoluidide (Flutamide), in men following a single oral 200 mg dose.