dichlorfop-methyl
propionic acid, 2-(4-(2,4-dichlorophenoxy)phenoxy)-, methyl ester
Identification
| Name | dichlorfop-methyl |
| CAS Number | 51338-27-3 |
| EINECS | 257-141-8 |
| FDA UNII | 9T8QCB25UO |
| Molecular Formula | C16 H14 Cl2 O4 |
| Molecular Weight | 341.18838000 |
| MDL Number | MFCD00128052 |
| Nikkaji Number | J11.840K |
| Beilstein | 2224754 |
Regulatory
Physical Properties
| Appearance | colorless crystals (est) |
| Assay | 95.00 to 100.00 |
| Food Chemicals Codex Listed | No |
| Melting Point | 40.00 °C. @ 760.00 mm Hg |
| logP (o/w) | 4.620 |
| Soluble in | water, 0.7937 mg/L @ 25 °C (est) |
No sensory data available
Safety Information
| Oral/Parenteral Toxicity | Not determined |
| Dermal Toxicity | Not determined |
| Inhalation Toxicity | Not determined |
GHS Classification
['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']
Safety in Use
| Category | herbicides / pesticides |
| Recommendation for dichlorfop-methyl usage levels up to | not for fragrance use. |
| Recommendation for dichlorfop-methyl flavor usage levels up to | not for flavor use. |
No supplier data available
Potential Uses
Natural Occurrence
Synonyms
dichlordiphenprop
2-(4-(2,4-
dichlorophenoxy)phenoxy)propanoic acid methyl ester
2-(4-(2,4-
dichlorophenoxy)phenoxy)propanoic acid, methyl ester
diclofop methyl ester
diclofop-methyl
(+-)-
diclofop-methyl
hoe-023408
hoelon
hoelon 3EC
illoxan
methyl 2-(4-(2,4-dichlorophenoxy)phenoxy) propionate
methyl 2-(4-(2,4-dichlorophenoxy)phenoxy)propanoate
methyl 2-(4-(2,4-dichlorophenoxy)phenoxy)propionate
(+ or -)-
methyl 2-(4-(2,4-dichlorophenoxy)phenoxy)propionate
methyl 2-[4-(2,4-dichlorophenoxy)phenoxy]propanoate
methyldiclofop
propanoic acid, 2-(4-(2,4-dichlorophenoxy)phenoxy)-, methyl ester
propionic acid, 2-(4-(2,4-dichlorophenoxy)phenoxy)-, methyl ester
PubMed:
Evolution of herbicide resistance mechanisms in grass weeds.
PubMed:
Unraveling the toxicity mechanisms of the herbicide diclofop-methyl in rice: modulation of the activity of key enzymes involved in citrate metabolism and induction of cell membrane anion channels.
PubMed:
Enantioselective metabolism of the chiral herbicide diclofop-methyl and diclofop by HPLC in loach (Misgurnus anguillicaudatus) liver microsomes in vitro.
PubMed:
RNA-Seq transcriptome analysis to identify genes involved in metabolism-based diclofop resistance in Lolium rigidum.
PubMed:
Enhanced herbicide metabolism induced by 2,4-D in herbicide susceptible Lolium rigidum provides protection against diclofop-methyl.
PubMed:
Enantioselective physiological effects of the herbicide diclofop on cyanobacterium Microcystis aeruginosa.
PubMed:
Enhanced rates of herbicide metabolism in low herbicide-dose selected resistant Lolium rigidum.
PubMed:
Analysis of enantioselective biochemical, physiological, and transcriptional effects of the chiral herbicide diclofop methyl on rice seedlings.
PubMed:
Genotoxic effects of chlorophenoxy herbicide diclofop-methyl in mice in vivo and in human lymphocytes in vitro.
PubMed:
Stereoselective degradation of Diclofop-methyl during alcohol fermentation process.
PubMed:
Genetic control of a cytochrome P450 metabolism-based herbicide resistance mechanism in Lolium rigidum.
PubMed:
Environmental behavior of the chiral aryloxyphenoxypropionate herbicide diclofop-methyl and diclofop: enantiomerization and enantioselective degradation in soil.
PubMed:
Distinct non-target site mechanisms endow resistance to glyphosate, ACCase and ALS-inhibiting herbicides in multiple herbicide-resistant Lolium rigidum.
PubMed:
Time-dependent degradation and toxicity of diclofop-methyl in algal suspensions : emerging contaminants.
PubMed:
TiO(2)/BaTiO(3)-assisted photocatalytic mineralization of diclofop-methyl on UV-light irradiation in the presence of oxidizing agents.
PubMed:
One- and two-dimensional direct chiral liquid chromatographic determination of mixtures of diclofop-Acid and diclofop-methyl herbicides.
PubMed:
Enantioselective degradation and ecotoxicity of the chiral herbicide diclofop in three freshwater alga cultures.
PubMed:
Relation of diclofop-methyl toxicity and degradation in algae cultures.
PubMed:
Cross-resistance profile of mesosulfuron-methyl-resistant Italian ryegrass in the southern United States.
PubMed:
Environmental significance of the diclofop-methyl and cyclodextrin inclusion complexes.
PubMed:
High survival frequencies at low herbicide use rates in populations of Lolium rigidum result in rapid evolution of herbicide resistance.
PubMed:
Environmental effects of inclusion complexation between methylated beta-cyclodextrin and diclofop-methyl.
PubMed:
Bioluminescence determination of enzyme activity of firefly luciferase in the presence of pesticides.
PubMed:
Effects of methyl-CD and humic acid on hydrolytic degradation of the herbicide diclofop-methyl.
PubMed:
Lolium rigidum, a pool of resistance mechanisms to ACCase inhibitor herbicides.
PubMed:
Recurrent selection with reduced herbicide rates results in the rapid evolution of herbicide resistance in Lolium rigidum.
PubMed:
Herbicide selection of Italian ryegrass under different levels of UVB radiation.
PubMed:
Tank-mix adjuvants and pesticide residues: some regulatory and quantitative aspects.
PubMed:
Characterisation of target-site resistance to ACCase-inhibiting herbicides in the weed Alopecurus myosuroides (black-grass).
PubMed:
[Effect of diclofop on the activity of some drug-metabolizing enzymes in the liver of male Wistar rats].
PubMed:
Effect of cropping cycles and repeated herbicide applications on the degradation of diclofop-methyl, bentazone, diuron, isoproturon and pendimethalin in soil.
PubMed:
Induction and inactivation of a cytochrome P450 confering herbicide resistance in wheat seedlings.
PubMed:
Sorption and metabolism of selected herbicides in river biofilm communities.
PubMed:
Resistance to ACCase-inhibiting herbicides and isoproturon in UK populations of Lolium multiflorum: mechanisms of resistance and implications for control.
PubMed:
Herbicides and the microtubular apparatus of Nicotiana tabacum pollen tube: immunofluorescence and immunogold labelling studies.
PubMed:
Studies of early hepatocellular proliferation and peroxisomal proliferation in Wistar rats treated with herbicide diclofop.
PubMed:
Molecular analysis and development of 16S rRNA oligonucleotide probes to characterize a diclofop-methyl-degrading biofilm consortium.
PubMed:
Degradation of diclofop-methyl by pure cultures of bacteria isolated from Manitoban soils.
PubMed:
Isolation and characterization of soil microorganisms capable of utilizing the herbicide diclofop-methyl as a sole source of carbon and energy.
PubMed:
Tandem mass spectrometry of herbicide residues in lipid-rich tissue.
PubMed:
Localization and characterization of two structurally different forms of acetyl-CoA carboxylase in young pea leaves, of which one is sensitive to aryloxyphenoxypropionate herbicides.
PubMed:
The role of interactions, sessile growth and nutrient amendments on the degradative efficiency of a microbial consortium.
PubMed:
Determination of the herbicide diclofop in human urine.
PubMed:
Coenzyme A esters of 2-aryloxyphenoxypropionate herbicides and 2-arylpropionate antiinflammatory drugs are potent and stereoselective inhibitors of rat liver acetyl-CoA carboxylase.
PubMed:
Determination of diclofop-methyl and diclofop residues in soil and crops by gas chromatography.
PubMed:
Kinetic characterization, stereoselectivity, and species selectivity of the inhibition of plant acetyl-CoA carboxylase by the aryloxyphenoxypropionic acid grass herbicides.
PubMed:
Biochemical and histological effects of diclofop-methyl in mice and voles under laboratory conditions.
PubMed:
[Food stimulation of the detoxifying system of the liver in preventing pesticide poisonings].
PubMed:
[Gas chromatographic determination of the herbicide illoxan in plants, grain and soil].
PubMed:
The fungicide chloraniformethan and the herbicide dichlofopmethyl affect calmodulin-dependent cyclic nucleotide phosphodiesterase from bovine brain.
PubMed:
Degradation of the herbicide dichlorfop-methyl in prairie soils.
PubMed:
Use of acetonitrile for the extraction of herbicide residues from soils.
PubMed:
Esterification of the hydrolysis product of the herbicide dichlorfop-methyl in methanol.