sulfuryl fluoride
sulfuric oxyfluoride
Identification
| Name | sulfuryl fluoride |
| IUPAC | sulfuryl difluoride |
| CAS Number | 2699-79-8 |
| EINECS | 220-281-5 |
| FDA UNII | 64B59K7U6Q |
| Molecular Formula | F2 O2 S |
| Molecular Weight | 102.06020640 |
| Nikkaji Number | J95.298B |
Regulatory
Physical Properties
| Appearance | colorless odorless gas (est) |
| Assay | 95.00 to 100.00 |
| Food Chemicals Codex Listed | No |
No sensory data available
Safety Information
| Oral/Parenteral Toxicity | oral-guinea pig LD50 100 mg/kg |
| Dermal Toxicity | Not determined |
| Inhalation Toxicity | inhalation-mouse LCLo 1200 ppm/1H |
GHS Classification
['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']
Safety in Use
| Category | herbicides / pesticides |
| Recommendation for sulfuryl fluoride usage levels up to | not for fragrance use. |
| Recommendation for sulfuryl fluoride flavor usage levels up to | not for flavor use. |
No supplier data available
Potential Uses
Natural Occurrence
Synonyms
EPA pesticide chemical code 078003
fluoro de sulfurilo
fluorure de sulfuryle
HSDB 828
sulfonyl fluoride
sulfur difluoride dioxide
sulfuric oxyfluoride
sulfuryl difluoride
sulfuryl fluoride [UN2191] [Poison gas]
sulphuryl difluoride
sulphuryl fluoride
sulphuryl fluoride [ISO]
vikane
PubMed:
Controlling pests in dry-cured ham: A review.
PubMed:
Evaluation of Structural Treatment Efficacy against Tribolium castaneum and Tribolium confusum (Coleoptera: Tenebrionidae) Using Meta-Analysis of Multiple Studies Conducted in Food Facilities.
PubMed:
Exposure of Brown Recluse and Brown Widow Spiders (Araneae: Sicariidae, Theridiidae) to a Commercial Sulfuryl Fluoride Fumigation.
PubMed:
Evaluation of methyl bromide alternatives efficacy against soil-borne pathogens, nematodes and soil microbial community.
PubMed:
Evaluation of sorbent materials for the sampling and analysis of phosphine, sulfuryl fluoride and methyl bromide in air.
PubMed:
Susceptibility to sulfuryl fluoride and lack of cross-resistance to phosphine in developmental stages of the red flour beetle, Tribolium castaneum (Coleoptera: Tenebrionidae).
PubMed:
Fumigation of bed bugs (Hemiptera: Cimicidae): effective application rates for sulfuryl fluoride.
PubMed:
Sulfur(VI) fluoride exchange (SuFEx): another good reaction for click chemistry.
PubMed:
A chemical "hub" for absolute quantification of a targeted protein: orthogonal integration of elemental and molecular mass spectrometry.
PubMed:
Sulfonyl fluorides as alternative to sulfonyl chlorides in parallel synthesis of aliphatic sulfonamides.
PubMed:
Ascertaining the suitability of aryl sulfonyl fluorides for [18F]radiochemistry applications: a systematic investigation using microfluidics.
PubMed:
Decomposition treatment of SO2F2 using packed bed DBD plasma followed by chemical absorption.
PubMed:
Production, partial purification and characterization of protease from a phytopathogenic fungi Alternaria solani (Ell. and Mart.) Sorauer.
PubMed:
Broad-spectrum antimalarial activity of peptido sulfonyl fluorides, a new class of proteasome inhibitors.
PubMed:
Chemical proteomics with sulfonyl fluoride probes reveals selective labeling of functional tyrosines in glutathione transferases.
PubMed:
Efficacy of sulfuryl fluoride against the pinewood nematode, Bursaphelenchus xylophilus (Nematoda: Aphelenchidae), in Pinus pinaster boards.
PubMed:
Evaluation of sulfuryl fluoride as a soil fumigant in China.
PubMed:
Tribolium castaneum (Coleoptera: Tenebrionidae) associated with rice mills: fumigation efficacy and population rebound.
PubMed:
Sulfonyl fluoride analogues as activity-based probes for serine proteases.
PubMed:
Sulfonyl fluoride-based prosthetic compounds as potential 18F labelling agents.
PubMed:
Effectiveness of sulfuryl fluoride for control of different life stages of stored-product psocids (Psocoptera).
PubMed:
Europium-labeled activity-based probe through click chemistry: absolute serine protease quantification using (153)Eu isotope dilution ICP/MS.
PubMed:
Polyisoprenylation potentiates the inhibition of polyisoprenylated methylated protein methyl esterase and the cell degenerative effects of sulfonyl fluorides.
PubMed:
Synthesis and biological evaluation of novel irreversible serine protease inhibitors using amino acid based sulfonyl fluorides as an electrophilic trap.
PubMed:
Anomeric effects in sulfonyl compounds: an experimental and computational study of fluorosulfonyl azide, FSO(2)N(3), and trifluoromethylsulfonyl azide, CF(3)SO(2)N(3).
PubMed:
Sulfuryl fluoride as a quarantine treatment for emerald ash borer (Coleoptera: Buprestidae) in ash logs.
PubMed:
Environmental and health risks of sulfuryl fluoride, a fumigant replacement for methyl bromide.
PubMed:
Sulfuryl fluoride as a quarantine treatment for Chlorophorus annularis (Coleoptera: Cerambycidae) in Chinese bamboo poles.
PubMed:
Sulfuryl fluoride fumigation effects on the safety, volatile composition, and sensory quality of dry cured ham.
PubMed:
Reactive and nonreactive quenching of O(1D) by the potent greenhouse gases SO2F2, NF3, and SF5CF3.
PubMed:
Atmospheric chemistry of sulfuryl fluoride: reaction with OH radicals, Cl atoms and O3, atmospheric lifetime, IR spectrum, and global warming potential.
PubMed:
Experimental and theoretical study of the atmospheric chemistry and global warming potential of SO2F2.
PubMed:
Systemic fluoride poisoning and death from inhalational exposure to sulfuryl fluoride.
PubMed:
Sorption of sulfuryl fluoride by food commodities.
PubMed:
[Determination of sulfuryl fluoride and ethylene oxide in aerosol pesticide by GC].
PubMed:
Evaluation of microwave irradiation for analysis of carbonyl sulfide, carbon disulfide, cyanogen, ethyl formate, methyl bromide, sulfuryl fluoride, propylene oxide, and phosphine in hay.
PubMed:
Lipid chain selectivity by outer membrane phospholipase A.
PubMed:
Sulfuryl fluoride as a quarantine treatment for Anoplophora glabripennis (Coleoptera: Cerambycidae) in regulated wood packing material.
PubMed:
A convenient preparation of heteroaryl sulfonamides and sulfonyl fluorides from heteroaryl thiols.
PubMed:
A scaled quantum mechanical force field for the sulfuryl halides II. The SO(2)XF (X=Cl, Br) halides.
PubMed:
Rapid uptake, metabolism, and elimination of inhaled sulfuryl fluoride fumigant by rats.
PubMed:
Convenient synthesis of fluorinated nucleosides with perfluoroalkanesulfonyl fluorides.
PubMed:
Alternatives to methyl bromide treatments for stored-product and quarantine insects.
PubMed:
Inhibition of lipoprotein lipase by alkanesulfonyl fluorides.
PubMed:
Centrifugal Distortion Analysis of a Near-Spherical Top, SO(2)F(2): The First Determination of All Six Quartic Centrifugal Distortion Constants for an Asymmetric Top.
PubMed:
Health effects associated with sulfuryl fluoride and methyl bromide exposure among structural fumigation workers.
PubMed:
Agreement between company-recorded and self-reported estimates of duration and frequency of occupational fumigant exposure.
PubMed:
Sulfonyl fluorides and the promotion of diisopropyl fluorophosphate neuropathy.
PubMed:
Residues of methyl bromide and sulfuryl fluoride in manufacturer-packaged household foods following fumigation.
PubMed:
Fluoride residues in frozen foods fumigated with sulfuryl fluoride.
PubMed:
The effects of inhalation exposure to sulfuryl fluoride on fetal development in rats and rabbits.
PubMed:
Inhalation toxicity of sulfuryl fluoride in rats and rabbits.
PubMed:
Subchronic neurotoxicity in rats of the structural fumigant, sulfuryl fluoride.
PubMed:
Desorption of residual sulfuryl fluoride from structural and household commodities by headspace analysis using gas chromatography.
PubMed:
Leads from the MMWR. Fatalities resulting from sulfuryl fluoride exposure after home fumigation--Virginia.
PubMed:
Fatalities resulting from sulfuryl fluoride exposure after home fumigation--Virginia.
PubMed:
Incapacitation and treatment of rats exposed to a lethal dose of sulfuryl fluoride.
PubMed:
Suicide by exposure to sulfuryl fluoride.
PubMed:
Neurobehavioral evaluation of soil and structural fumigators using methyl bromide and sulfuryl fluoride.
PubMed:
Carpet beetle dermatitis.