oxyfluorfen

benzene, 2-chloro-1-(3-ethoxy-4-nitrophenoxy)-4-(trifluoromethyl)- (9CI)

CAS: 42874-03-3 C15 H11 Cl F3 N O4 MW: 361.70367960

Identification

Nameoxyfluorfen
IUPAC2-chloro-1-(3-ethoxy-4-nitrophenoxy)-4-(trifluoromethyl)benzene
CAS Number42874-03-3
EINECS255-983-0
FDA UNII46GY4Y6567
Molecular FormulaC15 H11 Cl F3 N O4
Molecular Weight361.70367960
MDL NumberMFCD00072435
Nikkaji NumberJ15.822D
Beilstein2065259
XlogP34.70 (est)

Regulatory

Physical Properties

Appearance orange crystalline solid (est)
Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Melting Point 84.00 °C. @ 760.00 mm Hg
Boiling Point 358.20 °C. @ 760.00 mm Hg
Vapor Pressure 2.000000 mmHg @ 25.00 °C. (est)
Flash Point 370.00 °F. TCC ( 187.90 °C. ) (est)
logP (o/w) 4.730
Soluble in water, 0.116 mg/L @ 25 °C (exp)

No sensory data available

Safety Information

Oral/Parenteral Toxicityoral-dog LD50 > 5 mg/kg
Dermal Toxicityskin-rabbit LD50 > 10000 mg/kg
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryherbicides / pesticides
Recommendation for oxyfluorfen usage levels up tonot for fragrance use.
Recommendation for oxyfluorfen flavor usage levels up tonot for flavor use.

No supplier data available

Potential Uses

None Found

Natural Occurrence

not found in nature

Synonyms

benzene, 2-chloro-1-(3-ethoxy-4-nitrophenoxy)-4-(trifluoromethyl)- (9CI) 2- chloro-1-(3-ethoxy-4-nitrophenoxy)-4-(trifluoromethyl)benzene 2- chloro-1-(3-ethoxy-4-nitrophenoxy)-4-trifluoromethylbenzene 2- chloro-alpha,alpha,alpha-trifluoro-p-tolyl-3-ethoxy-4-nitrophenyl ether ether, 2-chloro-alpha,alpha,alpha-trifluoro-p-tolyl 3-ethoxy-4-nitrophenyl galigan goldate hada F koltar oxyfluorfene PubMed: Behaviour of oxyfluorfen in soils amended with edaphic biostimulants/biofertilizers obtained from sewage sludge and chicken feathers. Effects on soil biological properties. PubMed: Evaluation of three herbicide resistance genes for use in genetic transformations and for potential crop protection in algae production. PubMed: Behavior of oxyfluorfen in soils amended with different sources of organic matter. Effects on soil biology. PubMed: Monitoring of selected priority and emerging contaminants in the Guadalquivir River and other related surface waters in the province of Jaén, South East Spain. PubMed: Contaminants of legacy and emerging concern in largescale suckers (Catostomus macrocheilus) and the foodweb in the lower Columbia River, Oregon and Washington, USA. PubMed: Community air monitoring for pesticides-part 2: multiresidue determination of pesticides in air by gas chromatography, gas chromatography-mass spectrometry, and liquid chromatography-mass spectrometry. PubMed: Community air monitoring for pesticides. Part 3: using health-based screening levels to evaluate results collected for a year. PubMed: Persistence of oxyfluorfen in soil, runoff water, sediment and plants of a sunflower cultivation. PubMed: Hypospadias and residential proximity to pesticide applications. PubMed: Field dissipation of oxyfluorfen in onion and its dynamics in soil under Indian tropical conditions. PubMed: Photolysis of oxyfluorfen in aqueous methanol. PubMed: The use of antioxidant enzymes in freshwater biofilms: temporal variability vs. toxicological responses. PubMed: Identifying the cause of sediment toxicity in agricultural sediments: the role of pyrethroids and nine seldom-measured hydrophobic pesticides. PubMed: Assessment of possible carcinogenicity of oxyfluorfen to humans using mode of action analysis of rodent liver effects. PubMed: Light history modulates antioxidant and photosynthetic responses of biofilms to both natural (light) and chemical (herbicides) stressors. PubMed: Differential physiological and biochemical responses of two cyanobacteria Nostoc muscorum and Phormidium foveolarum against oxyfluorfen and UV-B radiation. PubMed: Toxicity of sediment-associated pesticides to Chironomus dilutus and Hyalella azteca. PubMed: Overexpression of a specific soybean GmGSTU4 isoenzyme improves diphenyl ether and chloroacetanilide herbicide tolerance of transgenic tobacco plants. PubMed: [Determination of biphenyl ether herbicides in water using HPLC with cloud-point extraction]. PubMed: Enhanced dissipation of oxyfluorfen, ethalfluralin, trifluralin, propyzamide, and pendimethalin in soil by solarization and biosolarization. PubMed: Development of a sample preparation method for the analysis of current-use pesticides in sediment using gas chromatography. PubMed: Pesticide extraction from table grapes and plums using ionic liquid based dispersive liquid-liquid microextraction. PubMed: Ionic liquid based dispersive liquid-liquid microextraction for the extraction of pesticides from bananas. PubMed: Pendimethalin and oxyfluorfen degradation under two irrigation conditions over four years application. PubMed: Persistence and bioaccumulation of oxyfluorfen residues in onion. PubMed: Micellar modified spectrophotometric determination of nitrobenzenes based upon reduction with tin(II), diazotisation and coupling with the Bratton-Marshall reagent. PubMed: Metabolism of nitrodiphenyl ether herbicides by dioxin-degrading bacterium Sphingomonas wittichii RW1. PubMed: Optimization of separation and detection conditions for the multiresidue analysis of pesticides in grapes by comprehensive two-dimensional gas chromatography-time-of-flight mass spectrometry. PubMed: Evaluation of six pesticides leaching indexes using field data of herbicide application in Casablanca Valley, Chile. PubMed: Determination of diphenylether herbicides in water samples by solid-phase microextraction coupled to liquid chromatography. PubMed: [Experimental study on oxyfluorfen technical herbicides induced mutagenicity]. PubMed: Effect of systemic herbicides on N2-fixing and phosphate solubilizing microorganisms in relation to availability of nitrogen and phosphorus in paddy soils of West Bengal. PubMed: [Determination of acetochlor and oxyfluorfen by capillary gas chromatography]. PubMed: Assessment of the plasma desorption time-of-flight mass spectrometry technique for pesticide adsorption and degradation on 'as-received' treated soil samples. PubMed: Herbicidal and antioxidant responses of transgenic rice overexpressing Myxococcus xanthus protoporphyrinogen oxidase. PubMed: Weed control and persistence of two oxyfluorfen formulations in olive groves under non tillage conditions. PubMed: Pesticide patch test series for the assessment of allergic contact dermatitis among banana plantation workers in panama. PubMed: Surface retention and photochemical reactivity of the diphenylether herbicide oxyfluorfen. PubMed: Oxyfluorfen toxic effect on S. obliquus evaluated by different photosynthetic and enzymatic biomarkers. PubMed: A point mutation of valine-311 to methionine in Bacillus subtilis protoporphyrinogen oxidase does not greatly increase resistance to the diphenyl ether herbicide oxyfluorfen. PubMed: Effect of the herbicides oxadiazon and oxyfluorfen on phosphates solubilizing microorganisms and their persistence in rice fields. PubMed: Dissipation of the herbicide oxyfluorfen in subtropical soils and its potential to contaminate groundwater. PubMed: Weed control in rose-scented geranium (Pelargonium spp). PubMed: Jasmonate is involved in the induction of tyrosine aminotransferase and tocopherol biosynthesis in Arabidopsis thaliana. PubMed: Degradation of oxyfluorfen by Azotobacter chroococcum (Beijerink). PubMed: Toxicological effects of the herbicide oxyfluorfen on acetylcholinesterase in two fish species: Oreochromis niloticus and Gambusia affinis. PubMed: Resistance of a soybean cell line to oxyfluorfen by overproduction of mitochondrial protoporphyrinogen oxidase. PubMed: Transgenic rice plants expressing a Bacillus subtilis protoporphyrinogen oxidase gene are resistant to diphenyl ether herbicide oxyfluorfen. PubMed: Laboratory study on leachability of five herbicides in South Australian soils. PubMed: Induction of hsp70 by the herbicide oxyfluorfen (Goal) in the Egyptian Nile fish, Oreochromis niloticus. PubMed: Herbicide residues in grapes and wine. PubMed: Herbicide-induced experimental variegate porphyria in mice: tissue porphyrinogen accumulation and response to porphyrogenic drugs. PubMed: Effects of a diphenyl-ether herbicide, oxyfluorfen, on human BFU-E/CFU-E development and haemoglobin synthesis. PubMed: Protoporphyrinogen oxidase: high affinity tetrahydrophthalimide radioligand for the inhibitor/herbicide-binding site in mouse liver mitochondria. PubMed: Photoaffinity labeling of protoporphyrinogen oxidase, the molecular target of diphenylether-type herbicides. PubMed: Effect of the protoporphyrinogen oxidase-inhibiting herbicide fomesafen on liver uroporphyrin and heptacarboxylic porphyrin in two mouse strains. PubMed: Effect of diphenyl ether herbicides and oxadiazon on porphyrin biosynthesis in mouse liver, rat primary hepatocyte culture and HepG2 cells. PubMed: Developmental toxicity of diphenyl ether herbicides in nestling American kestrels. PubMed: Determination of oxyfluorfen herbicide and oxyfluorfen amine residues in garbanzo beans by liquid chromatography. PubMed: Disappearance of oxyfluorfen (goal) from onions and organic soils. PubMed: The generation of singlet oxygen (o(2)) by the nitrodiphenyl ether herbicide oxyfluorfen is independent of photosynthesis. PubMed: Photosynthesis involvement in the mechanism of action of diphenyl ether herbicides. PubMed: Evidence from studies with acifluorfen for participation of a flavin-cytochrome complex in blue light photoreception for phototropism of oat coleoptiles. PubMed: Fate of 2-chloro-1-(3-ethoxy-4-nitrophenoxy)-4-(trifluoromethyl) benzene (oxyfluorofen) in rats.