tert-butyl methacrylate

methacrylic acid, tert-butyl ester

CAS: 585-07-9 C8 H14 O2 MW: 142.19798000

Identification

Nametert-butyl methacrylate
CAS Number585-07-9
EINECS209-548-7
FDA UNIIF9029V5818
Molecular FormulaC8 H14 O2
Molecular Weight142.19798000
MDL NumberMFCD00048245
Nikkaji NumberJ47.811C
Beilstein1746394
XlogP32.50 (est)

Regulatory

DG SANTE Food Contact Materialsmethacrylic acid, tert-butyl ester
FDA Mainterm (IAUFC)585-07-9 ; TERT-BUTYL METHACRYLATE

Physical Properties

Appearance colorless to pale yellow clear liquid (est)
Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Boiling Point 156.94 °C. @ 760.00 mm Hg (est)
Vapor Pressure 6.170000 mmHg @ 25.00 °C. (est)
Flash Point 106.00 °F. TCC ( 41.10 °C. ) (est)
logP (o/w) 2.540
Soluble in water, 1000 mg/L @ 25 °C (exp)

Cosmetic Information

CosIngcosmetic data
Cosmetic Usesfilm formers

No sensory data available

Safety Information

Preferred SDSView
Oral/Parenteral Toxicityoral-mouse LD50 8549 mg/kg
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryfilm forming agents
Recommendation for tert-butyl methacrylate usage levels up tonot for fragrance use.
Recommendation for tert-butyl methacrylate flavor usage levels up tonot for flavor use.

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Potential Uses

None Found

Natural Occurrence

not found in nature

Synonyms

tert- butyl 2-methylprop-2-enoate t- butyl methacrylate 1,1- dimethylethyl 2-methyl-2-propenoate methacrylic acid t-butyl ester methacrylic acid tert-butyl ester methacrylic acid, tert-butyl ester 2- methyl-2-propanyl methacrylate 2- methyl-2-propenoic acid 1,1-dimethyl ethyl ester 2- methyl-2-propenoic acid 1,1-dimethylethyl ester 2- propenoic acid, 2-methyl-, 1,1-dimethylethyl ester PubMed: Thermodynamics of copolymer solutions: how the pair interactions contribute to the overall effect. PubMed: Micro and macrorheology at fluid-fluid interfaces. PubMed: Polycationic nanoparticles for siRNA delivery: comparing ARGET ATRP and UV-initiated formulations. PubMed: Application of High-Resolution MALDI-TOFMS with a Spiral Ion Trajectory for the Structural Characterization of Free Radical Polymerized Methacrylate Ester Copolymers. PubMed: Amphiphilic block copolymer modified magnetic nanoparticles for microwave-assisted extraction of polycyclic aromatic hydrocarbons in environmental water. PubMed: Counterion-mediated hierarchical self-assembly of an ABC miktoarm star terpolymer. PubMed: Phase transitions of n-hexadecane in nanoencapsulated binary solutions of n-hexadecane and 1-octanol. PubMed: Dye-loaded porous nanocapsules immobilized in a permeable polyvinyl alcohol matrix: a versatile optical sensor platform. PubMed: Correlations between Chemical Compositions and Retention Times of Methacrylate Random Copolymers Using LC-ESI-MS. PubMed: Formation of polyampholyte brushes via controlled radical polymerization and their assembly in solution. PubMed: Scanning thermal lithography of tailored tert-butyl ester protected carboxylic acid functionalized (meth)acrylate polymer platforms. PubMed: Temperature- and pH-triggered reversible transfer of doubly responsive hairy particles between water and a hydrophobic ionic liquid. PubMed: Core-crosslinked compartmentalized cylinders. PubMed: Going beyond the surface: revealing complex block copolymer morphologies with 3D scanning force microscopy. PubMed: Self-assembly of poly(4-methylstyrene)-g-poly(methacrylic acid) graft copolymer in selective solvents for grafts: scattering and molecular dynamics simulation study. PubMed: Thermosensitive aqueous gels with tunable sol-gel transition temperatures from thermo- and pH-responsive hydrophilic ABA triblock copolymer. PubMed: An efficient, selective, and reducing agent-free copper catalyst for the atom-transfer radical addition of halo compounds to activated olefins. PubMed: Amphoteric core-shell microgels: contraphilic two-compartment colloidal particles. PubMed: Protein-functionalized hairy diamond nanoparticles. PubMed: Alignment of tellurium nanorods via a magnetization-alignment-demagnetization ("MAD") process assisted by an external magnetic field. PubMed: Undulated multicompartment cylinders by the controlled and directed stacking of polymer micelles with a compartmentalized corona. PubMed: pH-responsive supramolecular self-assembly of well-defined zwitterionic ABC miktoarm star terpolymers. PubMed: Structured and gradient polymer brushes from biphenylthiol self-assembled monolayers by self-initiated photografting and photopolymerization (SIPGP). PubMed: Integral geometry analysis of fluorescence micrographs for quantitative relative comparison of protein adsorption onto polymer surfaces. PubMed: Joint theoretical experimental investigation of the electron spin resonance spectra of nitroxyl radicals: application to intermediates in in situ nitroxide mediated polymerization (in situ NMP) of vinyl monomers. PubMed: Staleya guttiformis attachment on poly(tert-butylmethacrylate) polymeric surfaces. PubMed: A comparative study between the adsorption and covalent binding of human immunoglobulin and lysozyme on surface-modified poly(tert-butyl methacrylate). PubMed: Vibrio fischeri and Escherichia coli adhesion tendencies towards photolithographically modified nanosmooth poly (tert-butyl methacrylate) polymer surfaces. PubMed: Surface hydrophobicity modulates the operation of actomyosin-based dynamic nanodevices. PubMed: Mesoscale simulations of the behavior of charged polymer brushes under normal compression and lateral shear forces. PubMed: Polymer brushes in nanopores surrounded by silicon-supported tris(trimethylsiloxy)silyl monolayers. PubMed: Towards nanoporous membranes based on ABC triblock terpolymers. PubMed: Janus discs. PubMed: An optical thermometer based on the delayed fluorescence of C70. PubMed: One-pot synthesis of pegylated ultrasmall iron-oxide nanoparticles and their in vivo evaluation as magnetic resonance imaging contrast agents. PubMed: Effects of temperature and chemical modification on polymer Langmuir films. PubMed: ATP level variations in heterotrophic bacteria during attachment on hydrophilic and hydrophobic surfaces. PubMed: Synthesis, isolation via self-assembly, and single-molecule observation of a [60]fullerene-end-capped isotactic poly(methyl methacrylate). PubMed: Solvent-induced large compound vesicle of [60]fullerene containing poly(tert-butyl methacrylate). PubMed: pH-sensitive unimolecular polymeric micelles: synthesis of a novel drug carrier. PubMed: Detection of coccoid forms of Sulfitobacter mediterraneus using atomic force microscopy. PubMed: Carbohydrate/monomer complexes in aqueous polymerizations: methylated-beta-cyclodextrin mediated aqueous polymerization of hydrophobic methacrylic monomers. PubMed: Protein profiled features patterned via confocal microscopy. PubMed: Actin motion on microlithographically functionalized myosin surfaces and tracks. PubMed: Ultrathin films of a polyelectrolyte with layered architecture