(Z)-3-hexen-1-yl formate
cis-3-hexenyl formate
Identification
| Name | (Z)-3-hexen-1-yl formate |
| IUPAC | [(Z)-hex-3-enyl] formate |
| CAS Number | 33467-73-1 |
| EINECS | 251-532-7 |
| FDA UNII | E34OB83TYM |
| Molecular Formula | C7 H12 O2 |
| Molecular Weight | 128.17104000 |
| MDL Number | MFCD00036490 |
| Nikkaji Number | J59.827E |
| CoE Number | 2153 |
Regulatory
| JECFA Food Flavoring | 123 cis-3-hexenyl formate |
| DG SANTE Food Flavourings | 09.240 hex-3(cis)-enyl formate |
| FEMA Number | 3353 |
| FDA | No longer provide for the use of these seven synthetic flavoring substances |
| FDA Mainterm (SATF) | 33467-73-1 ; CIS-3-HEXENYL FORMATE |
Physical Properties
| Appearance | colorless clear liquid (est) |
| Assay | 98.00 to 100.00 sum of isomers |
| Food Chemicals Codex Listed | No |
| Specific Gravity | 0.90800 to 0.91800 @ 25.00 °C. |
| Pounds per Gallon - (est). | 7.555 to 7.639 |
| Refractive Index | 1.42400 to 1.43100 @ 20.00 °C. |
| Boiling Point | 72.00 °C. @ 40.00 mm Hg, 154.00 to 156.00 °C. @ 760.00 mm Hg |
| Acid Value | 2.00 max. KOH/g |
| Vapor Pressure | 2.567000 mmHg @ 25.00 °C. (est) |
| Vapor Density | 4.4 ( Air = 1 ) |
| Flash Point | 113.00 °F. TCC ( 45.00 °C. ) |
| logP (o/w) | 2.098 (est) |
| Shelf Life | 24.00 month(s) or longer if stored properly. |
| Storage | store in cool, dry place in tightly sealed containers, protected from heat and light. |
| Soluble in | alcohol |
| Insoluble in | water |
| Similar Items | note |
Cosmetic Information
| CosIng | cosmetic data |
| Cosmetic Uses | perfuming agents |
Organoleptic Properties
| Odor Strength | high , |
| Substantivity | 1 hour(s) at 10.00 % in dipropylene glycol |
| Odor Description |
at 10.00 % in dipropylene glycol. Green, diffusive, fresh, fruity, citrus, waxy, melon and vegetable Strong ethereal, sweet, green apple odor with woody undertones ethereal, green apple Sharp green vegetable like odor, reminiscence of cucumber
|
| Odor sample from | Bedoukian Research, Inc. |
| Taste Description |
at 20.00 ppm. Green, fresh vegetable, slightly fruity ethereal, green, fruity, waxy, fresh vegetable; apple, guava, banana Green, fresh, sharp with an arugula note
|
Safety Information
| Preferred SDS | View |
| European information | Most important hazard(s): |
| Human Experience | 10 % solution: no irritation or sensitization. |
| Oral/Parenteral Toxicity | oral-rat LD50 > 5000 mg/kg |
| Dermal Toxicity | skin-rabbit LD50 > 5000 mg/kg |
| Inhalation Toxicity | Not determined |
GHS Classification
['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']
Safety in Use
| Category | flavor and fragrance agents |
| RIFM Fragrance Material Safety Assessment | Search |
| Recommendation for (Z)-3-hexen-1-yl formate usage levels up to | 6.0000 % in the fragrance concentrate. |
| Maximised Survey-derived Daily Intakes (MSDI-EU) | 43.00 (μg/capita/day) |
| baked goods | - |
| beverages(nonalcoholic) | - |
| beverages(alcoholic) | - |
| breakfast cereal | - |
| cheese | - |
| chewing gum | - |
| condiments / relishes | - |
| confectionery froastings | - |
| egg products | - |
| fats / oils | - |
| fish products | - |
| frozen dairy | - |
| fruit ices | - |
| gelatins / puddings | - |
| granulated sugar | - |
| gravies | - |
| hard candy | - |
| imitation dairy | - |
| instant coffee / tea | - |
| jams / jellies | - |
| meat products | - |
| milk products | - |
| nut products | - |
| other grains | - |
| poultry | - |
| processed fruits | - |
| processed vegetables | - |
| reconstituted vegetables | - |
| seasonings / flavors | - |
| snack foods | - |
| soft candy | - |
| soups | - |
| sugar substitutes | - |
| sweet sauces | - |
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