Identification

Namecinnamyl tiglate
IUPAC[(E)-3-phenylprop-2-enyl] (Z)-2-methylbut-2-enoate
EINECS263-215-0
FDA UNIISearch
Molecular FormulaC14 H16 O2
Molecular Weight216.27992000
Nikkaji NumberJ297.576I

Regulatory

DG SANTE Food Flavourings09.339 cinnamyl 2-methylcrotonate

Physical Properties

Appearance colorless clear oily liquid (est)
Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Specific Gravity 0.99500 to 1.00100 @ 25.00 °C.
Pounds per Gallon - (est). 8.279 to 8.329
Refractive Index 1.52100 to 1.52700 @ 20.00 °C.
Melting Point 18.00 °C. @ 760.00 mm Hg
Boiling Point 340.00 °C. @ 760.00 mm Hg
Vapor Pressure 0.001320 mmHg @ 25.00 °C.
Flash Point 388.00 °F. TCC ( 197.78 °C. )
logP (o/w) 4.010 (est)
Soluble in alcohol
Insoluble in water
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Cosmetic Information

CosIngcosmetic data
Cosmetic Usesperfuming agents

Organoleptic Properties

Odor Description at 100.00 %.

Safety Information

Human Experience4 % solution: no irritation or sensitization.
Oral/Parenteral Toxicityoral-rat LD50 > 5000 mg/kg
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryfragrance agents
RIFM Fragrance Material Safety AssessmentSearch
maximum skin levels for fine fragrances0.0020 % and are based on the assumption that the fragrance mixture is used at 20% in a consumer product (IFRA Use Level Survey). (IFRA, 2001)
Recommendation for cinnamyl tiglate usage levels up to2.0000 % in the fragrance concentrate.
use level in formulae for use in cosmetics0.0100 %
Dermal Systemic Exposure in Cosmetic Products0.0003 mg/kg/day (IFRA, 2001)
Maximised Survey-derived Daily Intakes (MSDI-EU)0.012 (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI)3900 (μg/person/day)
Threshold of Concern1800 (μg/person/day)
Structure ClassI
Dairy products, excluding products of category 02.0 (01.0)7.00000
Fats and oils, and fat emulsions (type water-in-oil) (02.0)5.00000
Edible ices, including sherbet and sorbet (03.0)10.00000
Processed fruit (04.1)7.00000
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2)-
Confectionery (05.0)10.00000
Chewing gum (05.3)-
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0)5.00000
Bakery wares (07.0)10.00000
Meat and meat products, including poultry and game (08.0)2.00000
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0)2.00000
Eggs and egg products (10.0)-
Sweeteners, including honey (11.0)-
Salts, spices, soups, sauces, salads, protein products, etc. (12.0)5.00000
Foodstuffs intended for particular nutritional uses (13.0)10.00000
Non-alcoholic ("soft") beverages, excl. dairy products (14.1)5.00000
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2)10.00000
Ready-to-eat savouries (15.0)20.00000
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0)5.00000

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Potential Uses

FR leather russian leather FR woody

Natural Occurrence

champaca concrete @ 0.05% Data

Synonyms

2- butenoic acid, 2-methyl-, (2E)-3-phenyl-2-propen-1-yl ester, (2E)- 2- butenoic acid, 2-methyl-, 3-phenyl-2-propenyl ester, (2E)- cinnamyl 2-methyl crotonate cinnamyl 2-methylcrotonate 3- phenyl allyl 2-methyl crotonate 3- phenyl-2-propenyl (E)-2-methyl-2-butenoate (2E)-3- phenylprop-2-en-1-yl (2E)-2-methylbut-2-enoate [(E)-3- phenylprop-2-enyl] (E)-2-methylbut-2-enoate tiglic acid cinnamyl ester Try the PubMed Search.