strawberry glycidate 1 (aldehyde C-16 (so-called))

ethyl methylphenylglycidate

CAS: 77-83-8 C12 H14 O3 MW: 206.24118000 fruity fruity

Identification

Namestrawberry glycidate 1 (aldehyde C-16 (so-called))
IUPACethyl 3-methyl-3-phenyloxirane-2-carboxylate
CAS Number77-83-8
EINECS201-061-8
FDA UNIIUD51D5KR4A
Molecular FormulaC12 H14 O3
Molecular Weight206.24118000
MDL NumberMFCD00022338
Nikkaji NumberJ15.727I
Beilstein0012299
CoE Number6002

Regulatory

JECFA Food Flavoring1577 ethyl methylphenylglycidate
DG SANTE Food Flavourings16.015 ethyl methylphenylglycidate
FEMA Number2444
FDANo longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF)77-83-8 ; 3-METHYL-3-PHENYL GLYCIDIC ACID ETHYL ESTER
FDA RegulationFDA PART 182 -- SUBSTANCES GENERALLY RECOGNIZED AS SAFE

Physical Properties

Appearance colorless to pale yellow clear liquid (est)
Assay 98.00 to 100.00 sum of isomers
Food Chemicals Codex Listed Yes
Specific Gravity 1.08600 to 1.11200 @ 25.00 °C.
Pounds per Gallon - (est). 9.037 to 9.253
Refractive Index 1.49900 to 1.51200 @ 20.00 °C.
Boiling Point 272.00 to 275.00 °C. @ 760.00 mm Hg
Acid Value 2.00 max. KOH/g
Vapor Pressure 0.006000 mmHg @ 25.00 °C. (est)
Flash Point > 200.00 °F. TCC ( > 93.33 °C. )
logP (o/w) 1.655 (est)
Shelf Life 12.00 month(s) or longer if stored properly.
Storage refrigerate in tightly sealed containers.
Soluble in benzyl alcohol
Insoluble in glycerin
Stability cream

Cosmetic Information

CosIngcosmetic data
Cosmetic Usesperfuming agents

Organoleptic Properties

Odor Strength medium
Substantivity 241 hour(s) at 100.00 %
Odor Description
at 100.00 %.
Sweet, fruity strawberry-like with floral honey undertones
Fruity, Strawberry, Powerful
strongly fruity, aromatic; reminiscent of strawberry
fruity aromatic strawberry honey phenolic
Sweet, berry, strawberry, fruity, floral nuances
Odor sample from Givaudan Corporation
Taste Description
at 50.00 ppm.
sweet berry strawberry fruity tutti frutti floral
fruity, strawberry, fermenty, honey

Safety Information

Preferred SDSView
European informationMost important hazard(s):
Human Experience1 % solution: no irritation or sensitization.
Oral/Parenteral Toxicityoral-rat LD50 [sex: M,F] 5470 mg/kg
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavor and fragrance agents
RIFM Fragrance Material Safety AssessmentSearch
Recommendation for strawberry glycidate 1 (aldehyde C-16 (so-called)) usage levels up to15.0000 % in the fragrance concentrate.
Maximised Survey-derived Daily Intakes (MSDI-EU)205.00 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA)1840.00 (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI)ND (μg/person/day)
Threshold of Concern90 (μg/person/day)
Structure ClassIII
baked goods-
beverages(nonalcoholic)-
beverages(alcoholic)-
breakfast cereal-
cheese-
chewing gum-
condiments / relishes-
confectionery froastings-
egg products-
fats / oils-
fish products-
frozen dairy-
fruit ices-
gelatins / puddings-
granulated sugar-
gravies-
hard candy-
imitation dairy-
instant coffee / tea-
jams / jellies-
meat products-
milk products-
nut products-
other grains-
poultry-
processed fruits-
processed vegetables-
reconstituted vegetables-
seasonings / flavors-
snack foods-
soft candy-
soups-
sugar substitutes-
sweet sauces-

ACS International GmbH

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Potential Uses

FR acacia FR aldehydic FR almond FR angel essence FR apple FR apple green apple FR apple red apple FR apricot FR blackberry FR blueberry FR butterscotch FR cherry FR cherry blossom FR christmas FR citrus FR civet FR cranberry FR cyclamen FR decumaria FR floral FR grape FR hibiscus FR hyacinth FR jasmin FR kiwi FR lilac FR lily FR melon FR mulberry FR orange blossom FR papaya FR passion fruit FR peach FR peach blossom FR pineapple FR plum FR potpourri FR raspberry FR raspberry black raspberry FR rose FR rose absolute replacer FR spice FR strawberry FL/FR valerian FR vanilla FR violet warm FR zibeline

Natural Occurrence

not found in nature

Synonyms

aldehyde C 16 aldehyde C-16 aldehyde C-16 (EMPG) aldehyde C-16 (so called) aldehyde C-16 (so-called) aldehyde C-16 10% dpg aldehyde C-16 FCC aldehyde C16 aldehyde c16 "so called" FCC butanoic acid, 2,3-epoxy-3-phenyl-, ethyl ester 2,3- epoxy-3-phenyl butyric acid ethyl ester 2,3- epoxy-3-phenylbutyric acid, ethyl ester alpha,beta- epoxy-beta-methyl hydrocinnamic acid ethyl ester ethyl 2,3-epoxy-2-methyl-3-phenyl propionate ethyl 2,3-epoxy-3-methyl-3-phenyl propionate ethyl 2,3-epoxy-3-methyl-3-phenylpropionate ethyl 2,3-epoxy-3-phenyl butanoate ethyl 2,3-epoxy-3-phenylbutyrate ethyl 3-methyl 3-phenyl glycidate ethyl 3-methyl-2,3-epoxy-hydrocinamic acid ethyl 3-methyl-3-phenyl glycidate ethyl 3-methyl-3-phenyl oxirane carboxylate ethyl 3-methyl-3-phenyl-2-oxiranecarboxylate ethyl 3-methyl-3-phenylglycidate ethyl 3-methyl-3-phenyloxirane-2-carboxylate ethyl 3-methyl-3-phenyloxiranecarboxylate ethyl alpha,beta-epoxy-beta-methyl hydrocinnamate ethyl alpha,beta-epoxy-beta-methyl phenyl propionate ethyl ester of 2, 3-epoxy-3-phenylbutanoic acid ethyl ester of 2,3-epoxy-3-phenylbutanoic acid ethyl methyl phenyl glycidate ethyl methylphenylglycidate ethyl(methyl phenyl)glycidate fraise pure 3- methyl-3-phenyl glycidic acid ethyl ester 3- methyl-3-phenyl hydrocinnamic acid, ethylester 3- methyl-3-phenyl oxirane carboxylic acid ethyl ester 3- methyl-3-phenylglycidic acid ethyl ester 3- methyl-3-phenylglycidic acid, ethyl ester 3- methyl-3-phenyloxiranecarboxylic acid, ethyl ester 2- oxiranecarboxylic acid, 3-methyl-3-phenyl-, ethyl ester 3- phenyl-2,3-epoxybutyic acid ethyl ester 3- phenyl-2,3-epoxybutyric acid ethyl ester strawberry aldehyde strawberry glycidate 1 strawberry glycidate 1 (aldehyde C-16 (so-called)) strawberry pure (Givaudan) Info: epoxides PubMed: Effect of fat level on the perception of five flavor chemicals in ice cream with or without fat mimetics by using a descriptive test. PubMed: Study of artificial flavouring substances for mutagenicity in the Salmonella/microsome, Basc and micronucleus tests. PubMed: Long-term toxicity study of ethyl methylphenylglycidate (strawberry aldehyde) in the rat. PubMed: Studies on the purity and short-term toxicity of ethyl methylphenylglycidate (strawberry aldehyde) in rats. PubMed: [On synthetic aroma substances (author's transl)].