HC blue no. 2

p-phenylenediamine, 3-nitro-N(sup 1),N(sup 1),N(sup 4)-tris(2-hydroxyethyl)-

CAS: 33229-34-4 C12 H19 N3 O5 MW: 285.30043000

Identification

NameHC blue no. 2
CAS Number33229-34-4
EINECS251-410-3
FDA UNII6C0EL1931V
Molecular FormulaC12 H19 N3 O5
Molecular Weight285.30043000
MDL NumberMFCD00071762
Nikkaji NumberJ78.133I
Beilstein2148848

Regulatory

Physical Properties

Appearance dark blue to dark brown microcrystalline powder (est)
Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Melting Point 93.00 °C. @ 760.00 mm Hg
Boiling Point 582.70 °C. @ 760.00 mm Hg (est)
Flash Point 583.00 °F. TCC ( 306.20 °C. ) (est)
logP (o/w) 1.700
Soluble in water, 527.8 mg/L @ 25 °C (est)

Cosmetic Information

CosIngcosmetic data
Cosmetic Useshair dyeing agents

No sensory data available

Safety Information

Preferred SDSView
Oral/Parenteral Toxicityoral-mouse LD > 1000 mg/kg
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryhair dyeing agents
Recommendation for HC blue no. 2 usage levels up tonot for fragrance use.
Recommendation for HC blue no. 2 flavor usage levels up tonot for flavor use.

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Potential Uses

hair dyeing agents

Natural Occurrence

not found in nature

Synonyms

ethanol, 2,2'-((4-((2-hydroxyethyl)amino)-3-nitrophenyl)imino)bis- ethanol, 2,2'-((4-((2-hydroxyethyl)amino)-3-nitrophenyl)imino)di- HC blue 2 2,2'-((4-((2- hydroxyethyl)amino)-3-nitrophenyl)imino) bisethanol 2,2'-((4-((2- hydroxyethyl)amino)-3-nitrophenyl)imino)bis(ethanol) 2-[4-[bis(2- hydroxyethyl)amino]-2-nitroanilino]ethanol 2,2'-({4-[(2- hydroxyethyl)amino]-3-nitrophenyl}imino)diethanol 3- nitro-N(sup 1),N(sup 1),N(sup 4)-tris(2-hydroxyethyl)- p- phenylenediamine, 3-nitro-N(sup 1),N(sup 1),N(sup 4)-tris(2-hydroxyethyl)- PubMed: Assessing the predictiveness of the Syrian hamster embryo cell transformation assay for determining the rodent carcinogenic potential of single ring aromatic/nitroaromatic amine compounds. PubMed: HC Blue No. 2. PubMed: Mutagenicity evaluation of HC Blue No. 1 and HC Blue No. 2, II. Effect on the in vitro induction of unscheduled DNA synthesis in rat, mouse, rabbit, hamster, and monkey primary hepatocytes. PubMed: Mutagenicity evaluation of HC Blue No. 1 and HC Blue No. 2, I. Effect on the induction of micronuclei in mouse bone marrow cells. PubMed: Mutagenicity evaluation of HC Blue No. 1 and HC Blue No. 2. III. Effects in the Salmonella typhimurium/Escherichia coli reversion assay and the mouse lymphoma L5178Y TK+/- forward mutation assay. PubMed: Comparative metabolism and genotoxicity of the structurally similar nitrophenylenediamine dyes, HC Blue 1 and HC Blue 2, in mouse hepatocytes. PubMed: Species comparisons regarding comparative metabolism of two structurally similar phenylenediamines (HC Blue 1 and HC Blue 2). PubMed: Comparative carcinogenicity of two structurally similar phenylenediamine dyes (HC blue no. 1 and HC blue no. 2) in F344/N rats and B6C3F1 mice. PubMed: NTP Toxicology and Carcinogenesis Studies of C.I. Acid Orange 3 (CAS No. 6373-74-6) in F344/N Rats and B6C3F1 Mice (Gavage Studies). PubMed: Failure of short-term in vitro mutagenicity tests to predict the animal carcinogenicity of hair dyes. PubMed: NTP Toxicology and Carcinogenesis Studies of HC Blue No. 2 [2,2'-((4-((2-Hydroxyethyl)amino)-3-nitrophenyl)imino)bis(ethanol)] (CAS No. 33229-34-4) in F344/N Rats and B6C3F 1 Mice (Feed Studies).