(Z)-3-hexen-1-yl isovalerate

cis-3-hexenyl isovalerate

CAS: 35154-45-1 C11 H20 O2 MW: 184.27880000 green green

Identification

Name(Z)-3-hexen-1-yl isovalerate
IUPAC[(Z)-hex-3-enyl] 3-methylbutanoate
CAS Number35154-45-1
EINECS252-404-3
FDA UNIIL9KN8775G8
Molecular FormulaC11 H20 O2
Molecular Weight184.27880000
MDL NumberMFCD00036533
Nikkaji NumberJ41.509J
Beilstein2433447

Regulatory

FEMA Number3498
FDANo longer provide for the use of these seven synthetic flavoring substances

Physical Properties

Appearance colorless clear liquid (est)
Assay 98.00 to 100.00 sum of isomers
Food Chemicals Codex Listed Yes
Specific Gravity 0.87400 to 0.87600 @ 25.00 °C.
Pounds per Gallon - (est). 7.273 to 7.289
Refractive Index 1.42900 to 1.43500 @ 20.00 °C.
Boiling Point 98.00 °C. @ 15.00 mm Hg, 199.00 °C. @ 760.00 mm Hg
Acid Value 2.00 max. KOH/g
Vapor Pressure 0.061000 mmHg @ 25.00 °C. (est)
Vapor Density 6.3 ( Air = 1 )
Flash Point 140.00 °F. TCC ( 60.00 °C. )
logP (o/w) 3.772 (est)
Soluble in alcohol
Insoluble in water
Similar Items note

Cosmetic Information

CosIngcosmetic data
Cosmetic Usesperfuming agents

Organoleptic Properties

Odor Strength medium ,
Substantivity 4 hour(s) at 100.00 %
Odor Description
at 10.00 % in dipropylene glycol.
Green, fruity, floral and dirty
Fresh green apple with notes reminiscent of fresh blueberries
Sweet green apple odor with fruit effect
Powerful green apple like odor with interesting fruity effect in fragrances
Powerful green apple like odor with interesting fruity effect in fragrances
Fresh green apple fruity tropical pineapple
Odor sample from SCM Glidco Organics
Taste Description
green apple skin fruity tropical grassy green bean
at 10.00 ppm.
Valerian type notes, cheese, ripe fruity notes
Powerful fruity green taste, reminiscent of apple
Powerful green apple like
green apple skin fruity tropical grassy green bean

Safety Information

Preferred SDSView
European informationMost important hazard(s):
Oral/Parenteral Toxicityoral-rat LD50 > 4900 mg/kg
Dermal Toxicityskin-rabbit LD50 > 5000 mg/kg
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavor and fragrance agents
RIFM Fragrance Material Safety AssessmentSearch
Recommendation for (Z)-3-hexen-1-yl isovalerate usage levels up to4.0000 % in the fragrance concentrate.
Maximised Survey-derived Daily Intakes (MSDI-EU)8.00 (μg/capita/day)
baked goods-
beverages(nonalcoholic)-
beverages(alcoholic)-
breakfast cereal-
cheese-
chewing gum-
condiments / relishes-
confectionery froastings-
egg products-
fats / oils-
fish products-
frozen dairy-
fruit ices-
gelatins / puddings-
granulated sugar-
gravies-
hard candy-
imitation dairy-
instant coffee / tea-
jams / jellies-
meat products-
milk products-
nut products-
other grains-
poultry-
processed fruits-
processed vegetables-
reconstituted vegetables-
seasonings / flavors-
snack foods-
soft candy-
soups-
sugar substitutes-
sweet sauces-

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Potential Uses

FR apple green apple FR banana FR blueberry FR guava FR melon FR mint FR pear FR pineapple FR plum FR strawberry FL tea FL tropical FL/FR valerian

Natural Occurrence

artemisia campestris spp. glutinosa flower oil italy @ 0.20% Data PbMd artemisia variabilis flower oil italy @ trace% Data cornmint oil india @ 0.28% Data mint pepper tabasco pepper PMC peppermint oil mongolia @ 0.06% Data tea

Synonyms

butanoic acid, 3-methyl-, (3Z)-3-hexen-1-yl ester butanoic acid, 3-methyl-, (3Z)-3-hexenyl ester butanoic acid, 3-methyl-, 3-hexenyl ester, (Z)- butyric acid, 3-methyl-, (Z)-hex-3-en-1-yl ester (3Z)- hex-3-en-1-yl 3-methylbutanoate (Z)- hex-3-enyl 3-methyl butanoate (Z)- hex-3-enyl 3-methylbutanoate (Z)- hex-3-enyl isovalerate [(Z)- hex-3-enyl] 3-methylbutanoate (Z)-3- hexen-1-yl 3-methyl butanoate cis-3- hexen-1-yl 3-methyl butanoate (Z)-3- hexen-1-yl isopentanoate cis-3- hexen-1-yl isopentanoate (Z)-3- hexen-1-yl isovalerate cis-3- hexen-1-yl isovalerate cis-3- hexenyl 3-methylbutanoate (Z)-3- hexenyl 3-methylbutyrate hexenyl cis-3 isovalerate hexenyl cis-3 isovalerate (3-methylbutyrate) cis-3- hexenyl i-valerate cis-3- hexenyl iso valerate cis-3- hexenyl isopentanoate (Z)-3- hexenyl isovalerate C3 hexenyl isovalerate cis-3- hexenyl isovalerate cis-3- hexenyl isovalerate natural cis-3- hexenyl isovaleratefcc, no antioxidant cis-3- hexenyl-3-methylbutanoate hexenyl-cis-3-iso-valerate FCC cis 3- hexyl isovalerianate 3- methyl butanoic acid (3Z)-3-hexen-1-yl ester (Z)-iso valeric acid 3-hexen-1-yl ester iso valeric acid cis-3-hexenyl ester iso valeric acid, 3-hexenyl ester, (Z)- PubMed: Composition of the essential oil of Cynanchum mongolicum (Asclepiadaceae) and insecticidal activities against Aphis glycines (Hemiptera: Aphidiae).