gyromitrin
N-methyl-N-formyl hydrazone of acetaldehyde
Identification
| Name | gyromitrin |
| IUPAC | N-[(E)-ethylideneamino]-N-methylformamide |
| CAS Number | 16568-02-8 |
| FDA UNII | S9J72G0T46 |
| Molecular Formula | C4 H8 N2 O |
| Molecular Weight | 100.12096000 |
| Beilstein | 1922396 |
Regulatory
Physical Properties
| Appearance | colorless to pale yellow clear liquid (est) |
| Assay | 95.00 to 100.00 |
| Food Chemicals Codex Listed | No |
| Boiling Point | 135.80 °C. @ 760.00 mm Hg (est) |
| Vapor Pressure | 7.600000 mmHg @ 25.00 °C. (est) |
| Flash Point | 97.00 °F. TCC ( 36.00 °C. ) (est) |
| logP (o/w) | -0.300 (est) |
| Soluble in | water, 3.608e+005 mg/L @ 25 °C (est) |
No sensory data available
Safety Information
| Oral/Parenteral Toxicity | unreported-child LDLo 10 mg/kg |
| Dermal Toxicity | Not determined |
| Inhalation Toxicity | Not determined |
GHS Classification
['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']
Safety in Use
| Category | natural substances and extractives |
| Recommendation for gyromitrin usage levels up to | not for fragrance use. |
| Recommendation for gyromitrin flavor usage levels up to | not for flavor use. |
No supplier data available
Potential Uses
Natural Occurrence
Synonyms
acetaldehyde formylmethylhydrazone
acetaldehyde methyl formyl hydrazone
acetaldehyde methylformylhydrazone
acetaldehyde N-methyl-N-formylhydrazone
acetaldehyde N-methylformylhydrazone
acetaldehyde-N-formyl-N-methylhydrazone
acetaldehyde-N-methyl-N-formylhydrazone
acetaldehyde, N-formyl-N-methylhydrazone
acetylaldehyde-N-methyl-N-formylhydrazone
N-[(E)-
ethylideneamino]-N-methylformamide
formic acid, 2-ethylidene-1-methylhydrazide
formic acid, ethylidenemethylhydrazide
hydrazine carboxaldehyde, ethylidenemethyl-
hydrazine carboxyaldehyde, ethylidenemethyl-
hydrazinecarboxaldehyde, ethylidenemethyl-
N-
methyl-N-formyl hydrazone of acetaldehyde
PubMed:
[Mushroom poisonings that we don't think about: Gyromitra poisoning].
PubMed:
Gas chromatography-mass spectrometry determination of the pentafluorobenzoyl derivative of methylhydrazine in false morel (Gyromitra esculenta) as a monitor for the content of the toxin gyromitrin.
PubMed:
The epidemiology, toxidromic classification, general management, and prevention of mushroom poisoning in the United States.
PubMed:
[Acute higher funghi mushroom poisoning and its treatment].
PubMed:
Cytotoxic fungi--an overview.
PubMed:
Clinical approach to toxic mushroom ingestion.
PubMed:
Methylation of rat and mouse DNA by the mushroom poison gyromitrin and its metabolite monomethylhydrazine.
PubMed:
Poisoning by Gyromitra esculenta--a review.
PubMed:
[Poisoning by Geromitra esculenta].
PubMed:
[Diagnosis and therapy of mushroom poisoning (II)].
PubMed:
Un fleur du mal--gyromitrin poisoning.
PubMed:
N-methyl-N-formylhydrazine: a toxic and mutagenic inhibitor of the intestinal diamine oxidase.
PubMed:
Methylation of deoxyribonucleic acid in the rat by the mushroom poison gyromitrin.
PubMed:
Gyromitrin (acetaldehyde formylmethylhydrazone).
PubMed:
On the mutagenicity of metabolites derived from the mushroom poison gyromitrin.
PubMed:
Poisoning by Gyromitra : a possible mechanism.
PubMed:
[Influence of the mushroom poison gyromitrin on the lipids of rat liver (author's transl)].
PubMed:
The toxicology of 1-acetyl-2-methyl-2-formyl hydrazine (Ac-MFH).
PubMed:
Cancer induction in mice with acetaldehyde methylformylhydrazone of the false morel mushroom.
PubMed:
Considerations on the carcinogenicity of the mushroom poison gyromitrin and its metabolites.
PubMed:
Gyromitrin as a tumor inducer.
PubMed:
Indications for nitrosamide formation from the mushroom poison gyromitrin by rat liver microsomes.
PubMed:
The importance of human intestinal diamine oxidase in the oxidation of histamine and/or putrescine.
PubMed:
Renal functional response to the mushroom poison gyromitrin.
PubMed:
Liver injury by the false morel poison gyromitrin.
PubMed:
[Acute poisoning by Gyromitra esculenta (author's transl)].
PubMed:
Mutagenic properties of ethylidene gyromitrin and its metabolites in microsomal activation tests and in the host-mediated assay.
PubMed:
Acute oral toxicity of ethylidene gyromitrin in rabbits, rats and chickens.
PubMed:
Formation of methylhydrazine from acetaldehyde N-methyl-N-formylhydrazone, a component of Gyromitra esculenta.
PubMed:
Short-term peroral toxicity of ethylidene gyromitrin in rabbits and chickens.
PubMed:
Tests for gyromitrin, a poisonous compound in false morel gyromitra esculenta.
PubMed:
[Detection and content determination of gyromitrin in fresh Gyromitra esculenta. 19. Mushroom contents].
PubMed:
[Gyromitrin, the poison of Gyromitra esculenta. 16. On the fungi contents].