gyromitrin

N-methyl-N-formyl hydrazone of acetaldehyde

CAS: 16568-02-8 C4 H8 N2 O MW: 100.12096000

Identification

Namegyromitrin
IUPACN-[(E)-ethylideneamino]-N-methylformamide
CAS Number16568-02-8
FDA UNIIS9J72G0T46
Molecular FormulaC4 H8 N2 O
Molecular Weight100.12096000
Beilstein1922396

Regulatory

Physical Properties

Appearance colorless to pale yellow clear liquid (est)
Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Boiling Point 135.80 °C. @ 760.00 mm Hg (est)
Vapor Pressure 7.600000 mmHg @ 25.00 °C. (est)
Flash Point 97.00 °F. TCC ( 36.00 °C. ) (est)
logP (o/w) -0.300 (est)
Soluble in water, 3.608e+005 mg/L @ 25 °C (est)

No sensory data available

Safety Information

Oral/Parenteral Toxicityunreported-child LDLo 10 mg/kg
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categorynatural substances and extractives
Recommendation for gyromitrin usage levels up tonot for fragrance use.
Recommendation for gyromitrin flavor usage levels up tonot for flavor use.

No supplier data available

Potential Uses

None Found

Natural Occurrence

gyromitra esculenta

Synonyms

acetaldehyde formylmethylhydrazone acetaldehyde methyl formyl hydrazone acetaldehyde methylformylhydrazone acetaldehyde N-methyl-N-formylhydrazone acetaldehyde N-methylformylhydrazone acetaldehyde-N-formyl-N-methylhydrazone acetaldehyde-N-methyl-N-formylhydrazone acetaldehyde, N-formyl-N-methylhydrazone acetylaldehyde-N-methyl-N-formylhydrazone N-[(E)- ethylideneamino]-N-methylformamide formic acid, 2-ethylidene-1-methylhydrazide formic acid, ethylidenemethylhydrazide hydrazine carboxaldehyde, ethylidenemethyl- hydrazine carboxyaldehyde, ethylidenemethyl- hydrazinecarboxaldehyde, ethylidenemethyl- N- methyl-N-formyl hydrazone of acetaldehyde PubMed: [Mushroom poisonings that we don't think about: Gyromitra poisoning]. PubMed: Gas chromatography-mass spectrometry determination of the pentafluorobenzoyl derivative of methylhydrazine in false morel (Gyromitra esculenta) as a monitor for the content of the toxin gyromitrin. PubMed: The epidemiology, toxidromic classification, general management, and prevention of mushroom poisoning in the United States. PubMed: [Acute higher funghi mushroom poisoning and its treatment]. PubMed: Cytotoxic fungi--an overview. PubMed: Clinical approach to toxic mushroom ingestion. PubMed: Methylation of rat and mouse DNA by the mushroom poison gyromitrin and its metabolite monomethylhydrazine. PubMed: Poisoning by Gyromitra esculenta--a review. PubMed: [Poisoning by Geromitra esculenta]. PubMed: [Diagnosis and therapy of mushroom poisoning (II)]. PubMed: Un fleur du mal--gyromitrin poisoning. PubMed: N-methyl-N-formylhydrazine: a toxic and mutagenic inhibitor of the intestinal diamine oxidase. PubMed: Methylation of deoxyribonucleic acid in the rat by the mushroom poison gyromitrin. PubMed: Gyromitrin (acetaldehyde formylmethylhydrazone). PubMed: On the mutagenicity of metabolites derived from the mushroom poison gyromitrin. PubMed: Poisoning by Gyromitra : a possible mechanism. PubMed: [Influence of the mushroom poison gyromitrin on the lipids of rat liver (author's transl)]. PubMed: The toxicology of 1-acetyl-2-methyl-2-formyl hydrazine (Ac-MFH). PubMed: Cancer induction in mice with acetaldehyde methylformylhydrazone of the false morel mushroom. PubMed: Considerations on the carcinogenicity of the mushroom poison gyromitrin and its metabolites. PubMed: Gyromitrin as a tumor inducer. PubMed: Indications for nitrosamide formation from the mushroom poison gyromitrin by rat liver microsomes. PubMed: The importance of human intestinal diamine oxidase in the oxidation of histamine and/or putrescine. PubMed: Renal functional response to the mushroom poison gyromitrin. PubMed: Liver injury by the false morel poison gyromitrin. PubMed: [Acute poisoning by Gyromitra esculenta (author's transl)]. PubMed: Mutagenic properties of ethylidene gyromitrin and its metabolites in microsomal activation tests and in the host-mediated assay. PubMed: Acute oral toxicity of ethylidene gyromitrin in rabbits, rats and chickens. PubMed: Formation of methylhydrazine from acetaldehyde N-methyl-N-formylhydrazone, a component of Gyromitra esculenta. PubMed: Short-term peroral toxicity of ethylidene gyromitrin in rabbits and chickens. PubMed: Tests for gyromitrin, a poisonous compound in false morel gyromitra esculenta. PubMed: [Detection and content determination of gyromitrin in fresh Gyromitra esculenta. 19. Mushroom contents]. PubMed: [Gyromitrin, the poison of Gyromitra esculenta. 16. On the fungi contents].