triglochinin

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2-hexenedioic acid, 4-(cyano(beta-D-glucopyranosyloxy)methylene)-, (E,Z)-

CAS: 28876-11-1 C14 H17 N O10 MW: 359.28849000
All Ingredients Aromatic Ingredients CAS Numbers Found in Nature

Identification

Nametriglochinin
IUPAC(Z,4E)-4-[cyano-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxymethylidene]hex-2-enedioic acid
CAS Number28876-11-1
FDA UNIISearch
Molecular FormulaC14 H17 N O10
Molecular Weight359.28849000
Nikkaji NumberJ17.361D

Regulatory

Physical Properties

Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Soluble in water, 1e+006 mg/L @ 25 °C (est)

No sensory data available

Safety Information

Oral/Parenteral ToxicityNot determined
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categorynatural substances and extractives
Recommendation for triglochinin usage levels up tonot for fragrance use.
Recommendation for triglochinin flavor usage levels up tonot for flavor use.

No supplier data available

Potential Uses

None Found

Natural Occurrence

alocasia macrorrhiza

Synonyms

(E,Z)-4-( cyano(beta-dextro-glucopyranosyl oxy)methylene)-2-hexene dioic acid (Z,4E)-4-[ cyano-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxymethylidene]hex-2-enedioic acid 2- hexenedioic acid, 4-(cyano(beta-D-glucopyranosyloxy)methylene)-, (E,Z)- PubMed: Cloning and expression of cytochrome P450 enzymes catalyzing the conversion of tyrosine to p-hydroxyphenylacetaldoxime in the biosynthesis of cyanogenic glucosides in Triglochin maritima. PubMed: Biosynthesis of cyanogenic glucosides in Triglochin maritima and the involvement of cytochrome P450 enzymes. PubMed: In-vitro biosynthesis of 1-(4'-hydroxyphenyl)-2-nitroethane and production of cyanogenic compounds in osmotically stressed cell suspension cultures of Eschscholtzia californica Cham. PubMed: Aspects on the Biosynthesis of the Cyanogenic Glucoside Triglochinin in Triglochin maritima1. PubMed: [beta-Glucosidases specific for the cyanogenic glucoside triglochinin from Alocasia macrorrhiza Schott: further characterization of properties (author's transl)]. PubMed: [Glucosidases specific for the cyanogenic glucoside triglochinin. Purification and characterization of beta-glucosidases from Alocasia macrorrhiza Schott]. PubMed: Stereoselective synthesis of triglochinic acid, (E)-2-butene-1,2,4-tricarboxylic acid, derived from the cyanogenic glucoside triglochinin.