chlorophyll D

CAS: 519-63-1 C54 H70 Mg N4 O6 MW: 895.48010000

Identification

Namechlorophyll D
CAS Number519-63-1
FDA UNII60L1FX1O1U
Molecular FormulaC54 H70 Mg N4 O6
Molecular Weight895.48010000

Regulatory

Physical Properties

Assay 95.00 to 100.00
Food Chemicals Codex Listed No

No sensory data available

Safety Information

Oral/Parenteral ToxicityNot determined
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categorynatural substances and extractives
Recommendation for chlorophyll D usage levels up tonot for fragrance use.
Recommendation for chlorophyll D flavor usage levels up tonot for flavor use.

No supplier data available

Potential Uses

None Found

Natural Occurrence

found in nature

Synonyms

chlorophyll D Info: chlorophyll PubMed: Theoretical isotopic fractionation of magnesium between chlorophylls. PubMed: Excitation energy transfer in phycobiliproteins of the cyanobacterium Acaryochloris marina investigated by spectral hole burning. PubMed: Photosynthesis at the far-red region of the spectrum in Acaryochloris marina. PubMed: The identification of IsiA proteins binding chlorophyll d in the cyanobacterium Acaryochloris marina. PubMed: Phytanic acid consumption and human health, risks, benefits and future trends: A review. PubMed: Spectral properties of bacteriophytochrome AM1_5894 in the chlorophyll d-containing cyanobacterium Acaryochloris marina. PubMed: Transcriptomic analysis illuminates genes involved in chlorophyll synthesis after nitrogen starvation in Acaryochloris sp. CCMEE 5410. PubMed: Chlorophylls d and f and Their Role in Primary Photosynthetic Processes of Cyanobacteria. PubMed: Photoconversion and Fluorescence Properties of a Red/Green-Type Cyanobacteriochrome AM1_C0023g2 That Binds Not Only Phycocyanobilin But Also Biliverdin. PubMed: Two Unrelated 8-Vinyl Reductases Ensure Production of Mature Chlorophylls in Acaryochloris marina. PubMed: RfpA, RfpB, and RfpC are the Master Control Elements of Far-Red Light Photoacclimation (FaRLiP). PubMed: Adaptive and acclimative responses of cyanobacteria to far-red light. PubMed: Red-shifted red/green-type cyanobacteriochrome AM1_1870g3 from the chlorophyll d-bearing cyanobacterium Acaryochloris marina. PubMed: A biliverdin-binding cyanobacteriochrome from the chlorophyll d-bearing cyanobacterium Acaryochloris marina. PubMed: Establishment of the forward genetic analysis of the chlorophyll d-dominated cyanobacterium Acaryochloris marina MBIC 11017 by applying in vivo transposon mutagenesis system. PubMed: Modified molecular interactions of the pheophytin and plastoquinone electron acceptors in photosystem II of chlorophyll D-containing Acaryochloris marina as revealed by FTIR spectroscopy. PubMed: Effects of substituents on synthetic analogs of chlorophylls. Part 4: How formyl group location dictates the spectral properties of chlorophylls b, d and f. PubMed: Extensive remodeling of a cyanobacterial photosynthetic apparatus in far-red light. PubMed: Chlorophyll f and chlorophyll d are produced in the cyanobacterium Chlorogloeopsis fritschii when cultured under natural light and near-infrared radiation. PubMed: In vitro conversion of vinyl to formyl groups in naturally occurring chlorophylls. PubMed: Chlorophyll modifications and their spectral extension in oxygenic photosynthesis. PubMed: Rapid TaqMan-based quantification of chlorophyll d-containing cyanobacteria in the genus Acaryochloris. PubMed: Excitation energy transfer and electron-vibrational coupling in phycobiliproteins of the cyanobacterium Acaryochloris marina investigated by site-selective spectroscopy. PubMed: Response of chlorophyll d-containing cyanobacterium Acaryochloris marina to UV and visible irradiations. PubMed: Chlorophyll d and Acaryochloris marina: current status. PubMed: Spectroscopic properties of chlorophyll f. PubMed: A unique regulation of the expression of the psbA, psbD, and psbE genes, encoding the 01, 02 and cytochrome b559 subunits of the Photosystem II complex in the chlorophyll d containing cyanobacterium Acaryochloris marina. PubMed: Subsurface associations of Acaryochloris-related picocyanobacteria with oil-utilizing bacteria in the Arabian Gulf water body: promising consortia in oil sediment bioremediation. PubMed: A Novel Epiphytic Chlorophyll d-containing Cyanobacterium Isolated from a Mangrove-associated Red Alga. PubMed: Acaryochloris - Explaining the Riddle of Chlorophyll d in Red Algae and Expanding PAR for Oxygenic Photosynthesis. PubMed: Photosystem trap energies and spectrally-dependent energy-storage efficiencies in the Chl d-utilizing cyanobacterium, Acaryochloris marina. PubMed: Non-enzymatic conversion of chlorophyll-a into chlorophyll-d in vitro: a model oxidation pathway for chlorophyll-d biosynthesis. PubMed: Biofilm growth and near-infrared radiation-driven photosynthesis of the chlorophyll d-containing cyanobacterium Acaryochloris marina. PubMed: Artificially produced [7-formyl]-chlorophyll d functions as an antenna pigment in the photosystem II isolated from the chlorophyllide a oxygenase-expressing Acaryochloris marina. PubMed: Extinction coefficient for red-shifted chlorophylls: chlorophyll d and chlorophyll f. PubMed: Selective detection and phylogenetic diversity of Acaryochloris spp. that exist in association with didemnid ascidians and sponge. PubMed: Metabolic engineering of the Chl d-dominated cyanobacterium Acaryochloris marina: production of a novel Chl species by the introduction of the chlorophyllide a oxygenase gene. PubMed: Dinitrogen fixation in a unicellular chlorophyll d-containing cyanobacterium. PubMed: Cationic state distribution over the chlorophyll d-containing P(D1)/P(D2) pair in photosystem II. PubMed: Microbial diversity of biofilm communities in microniches associated with the didemnid ascidian Lissoclinum patella. PubMed: Cyanobacterial diversity and a new acaryochloris-like symbiont from Bahamian sea-squirts. PubMed: Efficiency of photosynthesis in a Chl d-utilizing cyanobacterium is comparable to or higher than that in Chl a-utilizing oxygenic species. PubMed: Dynamics of gene duplication in the genomes of chlorophyll d-producing cyanobacteria: implications for the ecological niche. PubMed: Effects of molecular structures on reduction properties of formyl groups in chlorophylls and pheophytins prepared from oxygenic photosynthetic organisms. PubMed: Phosphorescence study of chlorophyll d photophysics. Determination of the energy and lifetime of the photo-excited triplet state. Evidence of singlet oxygen photosensitization. PubMed: Constitution and energetics of photosystem I and photosystem II in the chlorophyll d-dominated cyanobacterium Acaryochloris marina. PubMed: Redox potentials of primary electron acceptor quinone molecule (QA)- and conserved energetics of photosystem II in cyanobacteria with chlorophyll a and chlorophyll d. PubMed: Expanding the solar spectrum used by photosynthesis. PubMed: Excitation energy transfer in intact cells and in the phycobiliprotein antennae of the chlorophyll d containing cyanobacterium Acaryochloris marina. PubMed: A mild conversion from 3-vinyl- to 3-formyl-chlorophyll derivatives. PubMed: Discovery of cyanophage genomes which contain mitochondrial DNA polymerase. PubMed: Endolithic chlorophyll d-containing phototrophs. PubMed: Synthesis of ¹⁸O-labeled photosynthetically active chlorophylls at the 3- or 7-carbonyl group with high regioselectivity. PubMed: 18O labeling of chlorophyll d in Acaryochloris marina reveals that chlorophyll a and molecular oxygen are precursors. PubMed: A new chlorophyll d-containing cyanobacterium: evidence for niche adaptation in the genus Acaryochloris. PubMed: Primary photophysical processes in photosystem II: bridging the gap between crystal structure and optical spectra. PubMed: Redox potential of pheophytin a in photosystem II of two cyanobacteria having the different special pair chlorophylls. PubMed: X-ray structures of the peridinin-chlorophyll-protein reconstituted with different chlorophylls. PubMed: Demetalation kinetics of natural chlorophylls purified from oxygenic photosynthetic organisms: effect of the formyl groups conjugated directly to the chlorin pi-macrocycle. PubMed: Incorporation of the chlorophyll d-binding light-harvesting protein from Acaryochloris marina and its localization within the photosynthetic apparatus of Synechocystis sp. PCC6803. PubMed: Purification and characterization of cytochrome c(6) from Acaryochloris marina. PubMed: Supramolecular organization of phycobiliproteins in the chlorophyll d-containing cyanobacterium Acaryochloris marina. PubMed: Chromatic photoacclimation extends utilisable photosynthetically active radiation in the chlorophyll d-containing cyanobacterium, Acaryochloris marina. PubMed: Wide-field photon counting fluorescence lifetime imaging microscopy: application to photosynthesizing systems. PubMed: Triplet-triplet energy transfer in Peridinin-Chlorophyll a-protein reconstituted with Chl a and Chl d as revealed by optically detected magnetic resonance and pulse EPR: comparison with the native PCP complex from Amphidinium carterae. PubMed: A viewpoint: why chlorophyll a? PubMed: Unique photosystems in Acaryochloris marina. PubMed: Energetics of Photosystem II charge recombination in Acaryochloris marina studied by thermoluminescence and flash-induced chlorophyll fluorescence measurements. PubMed: Spectroscopic studies of the chlorophyll d containing photosystem I from the cyanobacterium, Acaryochloris marina. PubMed: Evidence of global chlorophyll d. PubMed: The thermodynamics and kinetics of electron transfer between cytochrome b6f and photosystem I in the chlorophyll d-dominated cyanobacterium, Acaryochloris marina. PubMed: Two unique cyanobacteria lead to a traceable approach of the first appearance of oxygenic photosynthesis. PubMed: The primary electron donor of photosystem II of the cyanobacterium Acaryochloris marina is a chlorophyll d and the water oxidation is driven by a chlorophyll a/chlorophyll d heterodimer. PubMed: Characterization of highly purified photosystem I complexes from the chlorophyll d-dominated cyanobacterium Acaryochloris marina MBIC 11017. PubMed: Niche adaptation and genome expansion in the chlorophyll d-producing cyanobacterium Acaryochloris marina. PubMed: Function of chlorophyll d in reaction centers of photosystems I and II of the oxygenic photosynthesis of Acaryochloris marina. PubMed: Vibrational mode frequency calculations of chlorophyll-d for assessing (P740(+)-P740) FTIR difference spectra obtained using photosystem I particles from Acaryochloris marina. PubMed: Pigment composition and adaptation in free-living and symbiotic strains of Acaryochloris marina. PubMed: Identification of the special pair of photosystem II in a chlorophyll d-dominated cyanobacterium. PubMed: Both chlorophylls a and d are essential for the photochemistry in photosystem II of the cyanobacteria, Acaryochloris marina. PubMed: Redox potential of chlorophyll d in vitro. PubMed: An electron paramagnetic resonance investigation of the electron transfer reactions in the chlorophyll d containing photosystem I of Acaryochloris marina. PubMed: Optical spectroscopic studies of light-harvesting by pigment-reconstituted peridinin-chlorophyll-proteins at cryogenic temperatures. PubMed: Ultrastructural and genetic characteristics of endolithic cyanobacterial biofilms colonizing Antarctic granite rocks. PubMed: Theoretical study on the thermodynamic properties of chlorophyll d-peptides coordinating ligand. PubMed: Chromatic photoacclimation, photosynthetic electron transport and oxygen evolution in the chlorophyll d-containing oxyphotobacterium Acaryochloris marina. PubMed: Molecular detection of epiphytic Acaryochloris spp. on marine macroalgae. PubMed: Characterization of the water oxidizing complex of photosystem II of the Chl d-containing cyanobacterium Acaryochloris marina via its reactivity towards endogenous electron donors and acceptors. PubMed: Magneto-optic spectroscopy of a protein tetramer binding two exciton-coupled chlorophylls. PubMed: Stereochemical determination of chlorophyll-d molecule from Acaryochloris marina and its modification to a self-aggregative chlorophyll as a model of green photosynthetic bacterial antennae. PubMed: Effect of iron on growth and ultrastructure of Acaryochloris marina. PubMed: The nature of the photosystem II reaction centre in the chlorophyll d-containing prokaryote, Acaryochloris marina. PubMed: Excitation energy transfer from phycobiliprotein to chlorophyll d in intact cells of Acaryochloris marina studied by time- and wavelength-resolved fluorescence spectroscopy. PubMed: Quest for minor but key chlorophyll molecules in photosynthetic reaction centers - unusual pigment composition in the reaction centers of the chlorophyll d-dominated cyanobacterium Acaryochloris marina. PubMed: Functional characteristics of chlorophyll d-predominating photosynthetic apparatus in intact cells of Acaryochloris marina. PubMed: Spectroscopic studies of photosystem II in chlorophyll d-containing Acaryochloris marina. PubMed: Minor but key chlorophylls in photosystem II. PubMed: Pigment exchange of photosystem II reaction center by chlorophyll d. PubMed: Chlorophyll d: the puzzle resolved. PubMed: Iron deficiency induces a chlorophyll d-binding Pcb antenna system around Photosystem I in Acaryochloris marina. PubMed: Ecology: a niche for cyanobacteria containing chlorophyll d. PubMed: Structure of a large photosystem II supercomplex from Acaryochloris marina. PubMed: Discovery of a free-living chlorophyll d-producing cyanobacterium with a hybrid proteobacterial/cyanobacterial small-subunit rRNA gene. PubMed: Unique origin and lateral transfer of prokaryotic chlorophyll-b and chlorophyll-d light-harvesting systems. PubMed: Chlorophyll d in an epiphytic cyanobacterium of red algae. PubMed: Raman properties of chlorophyll d, the major pigment of Acaryochloris marina: studies using both Raman spectroscopy and density functional theory. PubMed: Identification of the primary electron donor in PS II of the Chl d-dominated cyanobacterium Acaryochloris marina. PubMed: Photo-oxidation of P740, the primary electron donor in photosystem I from Acaryochloris marina. PubMed: Photosystem II single crystals studied by transient EPR: the light-induced triplet state. PubMed: Examination of the photophysical processes of chlorophyll d leading to a clarification of proposed uphill energy transfer processes in cells of Acaryochloris marinas. PubMed: Raman spectroscopy of chlorophyll d from Acaryochloris marina. PubMed: Energy equilibration and primary charge separation in chlorophyll d-based photosystem I reaction center isolated from Acaryochloris marina. PubMed: Detection of chlorophyll d' and pheophytin a in a chlorophyll d-dominating oxygenic photosynthetic prokaryote Acaryochloris marina. PubMed: Modification of photosystem I reaction center by the extraction and exchange of chlorophylls and quinones. PubMed: Ultrastructure of Acaryochloris marina, an oxyphotobacterium containing mainly chlorophyll d. PubMed: Uphill energy transfer in a chlorophyll d-dominating oxygenic photosynthetic prokaryote, Acaryochloris marina. PubMed: Molecular structure, localization and function of biliproteins in the chlorophyll a/d containing oxygenic photosynthetic prokaryote Acaryochloris marina. PubMed: Fluorescence properties of chlorophyll d-dominating prokaryotic alga, acaryochloris marina: studies using time-resolved fluorescence spectroscopy on intact cells PubMed: A photosystem I reaction center driven by chlorophyll d in oxygenic photosynthesis. PubMed: The origin and evolution of oxygenic photosynthesis. PubMed: Light-harvesting in Acaryochloris marina--spectroscopic characterization of a chlorophyll d-dominated photosynthetic antenna system. PubMed: Isolation and characterization of biliprotein aggregates from Acaryochloris marina, a Prochloron-like prokaryote containing mainly chlorophyll d. PubMed: Changes in Protein Composition and Mn Abundance in Photosystem II Particles on Photoactivation of the Latent O(2)-Evolving System in Flash-Grown Wheat Leaves. PubMed: [Raman resonance diffusion of chlorophyll d]. PubMed: [Isolation of chlorophyll d from the alga Grateloupia dichotoma]. PubMed: PRESENCE OF A CHLOROPHYLL D-LIKE PIGMENT IN CHLORELLA EXTRACTS.