pulvinic acid

benzeneacetic acid, alpha-(3-hydroxy-5-oxo-4-phenyl-2(5H)-furanylidene)-, (E)- (9CI)

CAS: 26548-70-9 C18 H12 O5 MW: 308.28964000

Identification

Namepulvinic acid
IUPAC(2E)-2-(3-hydroxy-5-oxo-4-phenylfuran-2-ylidene)-2-phenylacetic acid
CAS Number26548-70-9
FDA UNIIQ17C0F3Z5W
Molecular FormulaC18 H12 O5
Molecular Weight308.28964000
Nikkaji NumberJ68.365E

Regulatory

Physical Properties

Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Boiling Point 544.39 °C. @ 760.00 mm Hg (est)
Flash Point 399.00 °F. TCC ( 203.90 °C. ) (est)
logP (o/w) 2.945 (est)
Soluble in water, 91.16 mg/L @ 25 °C (est)

No sensory data available

Safety Information

Oral/Parenteral Toxicityintraperitoneal-mouse LD50 500 mg/kg
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryherbicides / pesticides
Recommendation for pulvinic acid usage levels up tonot for fragrance use.
Recommendation for pulvinic acid flavor usage levels up tonot for flavor use.

No supplier data available

Potential Uses

None Found

Natural Occurrence

found in nature

Synonyms

acetic acid, (3-hydroxy-5-oxo-4-phenyl-2(5H)-furylidene)phenyl- benzeneacetic acid, alpha-(3-hydroxy-5-oxo-4-phenyl-2(5H)-furanylidene)-, (E)- (9CI) delta(sup 2(5H),alpha)- furanacetic acid, 3-hydroxy-5-oxo-alpha,4-diphenyl- 2,4- hexadienedioic acid, 3,4-dihydroxy-2,5-diphenyl-, gamma-lactone (E)-alpha-(3- hydroxy-5-oxo-4-phenyl-2(5H)-furanylidene) benzene acetic acid (2E)-2-(3- hydroxy-5-oxo-4-phenylfuran-2-ylidene)-2-phenylacetic acid pulvic acid PubMed: Development of models for prediction of the antioxidant activity of derivatives of natural compounds. PubMed: UV-protectant metabolites from lichens and their symbiotic partners. PubMed: Design and synthesis of new antioxidants predicted by the model developed on a set of pulvinic acid derivatives. PubMed: Synthesis and radioprotective properties of pulvinic acid derivatives. PubMed: Synthesis and antioxidant properties of pulvinic acids analogues. PubMed: Norbadione a: kinetics and thermodynamics of cesium uptake in aqueous and alcoholic media. PubMed: Chemical constituents of the lichen, Candelaria concolor: a complete NMR and chemical degradative investigation. PubMed: In vitro inhibitory effects of pulvinic acid derivatives isolated from Chinese edible mushrooms, Boletus calopus and Suillus bovinus, on cytochrome P450 activity. PubMed: Evaluation of antioxidant properties of monoaromatic derivatives of pulvinic acids. PubMed: Synthesis of pulvinic derivatives via TBAF-mediated regioselective opening of an unsymmetrical monoaromatic pulvinic dilactone. PubMed: Dissociation and metal-binding characteristics of yellow lichen substances suggest a relationship with site preferences of lichens. PubMed: Mollusc grazing may constrain the ecological niche of the old forest lichen Pseudocyphellaria crocata. PubMed: Conformational and Cs+ complexation properties of norbadione-A: a molecular modeling study. PubMed: Interactions of sterile-cultured lichen-forming ascomycetes with asbestos fibres. PubMed: Pinastric acid revisited: a complete NMR and X-ray structure assignment. PubMed: Dichlorinated pulvinic acid derivative from a Malaysian Scleroderma sp. PubMed: Pulvinones as bacterial cell wall biosynthesis inhibitors. PubMed: High-throughput evaluation of antioxidant and pro-oxidant activities of polyphenols with thymidine protection assays. PubMed: Raman spectroscopy of hot desert, high altitude epilithic lichens. PubMed: Uncatalyzed reaction of silyl ketene acetals with oxalyl chloride: a straightforward preparation of symmetrical pulvinic acids. PubMed: Unusual pulvinic acid dimers from the common fungi Scleroderma citrinum (common earthball) and Chalciporus piperatus (peppery bolete). PubMed: Norbadione A: synthetic approach to the bis(pulvinic acid) moiety and cesium-complexation studies. PubMed: Simple method for reversed-phase high-performance liquid chromatographic analysis of fungal pigments in fruit-bodies of Boletales (Fungi). PubMed: Pharmaceutically relevant metabolites from lichens. PubMed: [Mushroom pigments. 3. Xerocomic acid and gomphidic acid, 2 chemotaxonomically interesting pulvinic acid derivatives from Gomphidius glutinosus (Schff) Fr]. PubMed: [New pulvinic acid derivatives from Xerocomus chrysenteron (Bull. ex St. Amans) Quel. and studies on the question of the occurrence of anthraquinone pigments in boletaceae].