pulvinic acid
benzeneacetic acid, alpha-(3-hydroxy-5-oxo-4-phenyl-2(5H)-furanylidene)-, (E)- (9CI)
Identification
| Name | pulvinic acid |
| IUPAC | (2E)-2-(3-hydroxy-5-oxo-4-phenylfuran-2-ylidene)-2-phenylacetic acid |
| CAS Number | 26548-70-9 |
| FDA UNII | Q17C0F3Z5W |
| Molecular Formula | C18 H12 O5 |
| Molecular Weight | 308.28964000 |
| Nikkaji Number | J68.365E |
Regulatory
Physical Properties
| Assay | 95.00 to 100.00 |
| Food Chemicals Codex Listed | No |
| Boiling Point | 544.39 °C. @ 760.00 mm Hg (est) |
| Flash Point | 399.00 °F. TCC ( 203.90 °C. ) (est) |
| logP (o/w) | 2.945 (est) |
| Soluble in | water, 91.16 mg/L @ 25 °C (est) |
No sensory data available
Safety Information
| Oral/Parenteral Toxicity | intraperitoneal-mouse LD50 500 mg/kg |
| Dermal Toxicity | Not determined |
| Inhalation Toxicity | Not determined |
GHS Classification
['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']
Safety in Use
| Category | herbicides / pesticides |
| Recommendation for pulvinic acid usage levels up to | not for fragrance use. |
| Recommendation for pulvinic acid flavor usage levels up to | not for flavor use. |
No supplier data available
Potential Uses
Natural Occurrence
Synonyms
acetic acid, (3-hydroxy-5-oxo-4-phenyl-2(5H)-furylidene)phenyl-
benzeneacetic acid, alpha-(3-hydroxy-5-oxo-4-phenyl-2(5H)-furanylidene)-, (E)- (9CI)
delta(sup 2(5H),alpha)-
furanacetic acid, 3-hydroxy-5-oxo-alpha,4-diphenyl-
2,4-
hexadienedioic acid, 3,4-dihydroxy-2,5-diphenyl-, gamma-lactone
(E)-alpha-(3-
hydroxy-5-oxo-4-phenyl-2(5H)-furanylidene) benzene acetic acid
(2E)-2-(3-
hydroxy-5-oxo-4-phenylfuran-2-ylidene)-2-phenylacetic acid
pulvic acid
PubMed:
Development of models for prediction of the antioxidant activity of derivatives of natural compounds.
PubMed:
UV-protectant metabolites from lichens and their symbiotic partners.
PubMed:
Design and synthesis of new antioxidants predicted by the model developed on a set of pulvinic acid derivatives.
PubMed:
Synthesis and radioprotective properties of pulvinic acid derivatives.
PubMed:
Synthesis and antioxidant properties of pulvinic acids analogues.
PubMed:
Norbadione a: kinetics and thermodynamics of cesium uptake in aqueous and alcoholic media.
PubMed:
Chemical constituents of the lichen, Candelaria concolor: a complete NMR and chemical degradative investigation.
PubMed:
In vitro inhibitory effects of pulvinic acid derivatives isolated from Chinese edible mushrooms, Boletus calopus and Suillus bovinus, on cytochrome P450 activity.
PubMed:
Evaluation of antioxidant properties of monoaromatic derivatives of pulvinic acids.
PubMed:
Synthesis of pulvinic derivatives via TBAF-mediated regioselective opening of an unsymmetrical monoaromatic pulvinic dilactone.
PubMed:
Dissociation and metal-binding characteristics of yellow lichen substances suggest a relationship with site preferences of lichens.
PubMed:
Mollusc grazing may constrain the ecological niche of the old forest lichen Pseudocyphellaria crocata.
PubMed:
Conformational and Cs+ complexation properties of norbadione-A: a molecular modeling study.
PubMed:
Interactions of sterile-cultured lichen-forming ascomycetes with asbestos fibres.
PubMed:
Pinastric acid revisited: a complete NMR and X-ray structure assignment.
PubMed:
Dichlorinated pulvinic acid derivative from a Malaysian Scleroderma sp.
PubMed:
Pulvinones as bacterial cell wall biosynthesis inhibitors.
PubMed:
High-throughput evaluation of antioxidant and pro-oxidant activities of polyphenols with thymidine protection assays.
PubMed:
Raman spectroscopy of hot desert, high altitude epilithic lichens.
PubMed:
Uncatalyzed reaction of silyl ketene acetals with oxalyl chloride: a straightforward preparation of symmetrical pulvinic acids.
PubMed:
Unusual pulvinic acid dimers from the common fungi Scleroderma citrinum (common earthball) and Chalciporus piperatus (peppery bolete).
PubMed:
Norbadione A: synthetic approach to the bis(pulvinic acid) moiety and cesium-complexation studies.
PubMed:
Simple method for reversed-phase high-performance liquid chromatographic analysis of fungal pigments in fruit-bodies of Boletales (Fungi).
PubMed:
Pharmaceutically relevant metabolites from lichens.
PubMed:
[Mushroom pigments. 3. Xerocomic acid and gomphidic acid, 2 chemotaxonomically interesting pulvinic acid derivatives from Gomphidius glutinosus (Schff) Fr].
PubMed:
[New pulvinic acid derivatives from Xerocomus chrysenteron (Bull. ex St. Amans) Quel. and studies on the question of the occurrence of anthraquinone pigments in boletaceae].