bupirimate
sulfamic acid, N,N-dimethyl-, ester with 5-butyl-2-ethylamino-6-methylpyrimidin-4-ol
Identification
| Name | bupirimate |
| IUPAC | [5-butyl-2-(ethylamino)-6-methylpyrimidin-4-yl] N,N-dimethylsulfamate |
| CAS Number | 41483-43-6 |
| FDA UNII | MCJ121RIOI |
| Molecular Formula | C13 H24 N4 O3 S |
| Molecular Weight | 316.42488000 |
| MDL Number | MFCD00055518 |
| Nikkaji Number | J15.826G |
| Beilstein | 0758056 |
| XlogP3 | 2.70 (est) |
Regulatory
Physical Properties
| Assay | 95.00 to 100.00 |
| Food Chemicals Codex Listed | No |
| Melting Point | 50.00 °C. @ 760.00 mm Hg |
| Boiling Point | 463.20 °C. @ 760.00 mm Hg (est) |
| Flash Point | 453.00 °F. TCC ( 233.90 °C. ) (est) |
| logP (o/w) | 2.700 |
| Soluble in | water, 22 mg/L @ 25 °C (exp) |
No sensory data available
Safety Information
| Oral/Parenteral Toxicity | oral-guinea pig LD50 4000 mg/kg |
| Dermal Toxicity | skin-mammal (species unspecified) LD50 > 4 mL/kg |
| Inhalation Toxicity | Not determined |
GHS Classification
['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']
Safety in Use
| Category | herbicides / pesticides |
| Recommendation for bupirimate usage levels up to | not for fragrance use. |
| Recommendation for bupirimate flavor usage levels up to | not for flavor use. |
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Potential Uses
Natural Occurrence
Synonyms
5-
butyl-2-(ethylamino)-6-methyl-4-pyrimidinyl dimethylsulfamate
[5-
butyl-2-(ethylamino)-6-methylpyrimidin-4-yl] N,N-dimethylsulfamate
5-
butyl-2-ethylamino-6-methylpyrimidin-4-yl dimethylsulphamate
5-
butyl-2-ethylamino-6-methylpyrimidin-4-yldimethylsulphamate
dimethylsulfamic acid 5-butyl-2-(ethylamino)-6-methyl-4-pyrimidinyl ester
nimrod T
sulfamic acid, dimethyl-, 5-butyl-2-(ethylamino)-6-methyl-4-pyrimidinyl ester
sulfamic acid, N,N-dimethyl-, ester with 5-butyl-2-ethylamino-6-methylpyrimidin-4-ol
PubMed:
Determination of 28 pesticides applied on two tomato cultivars with a different surface/weight ratio of the berries, using a multiresidue GC-MS/MS method.
PubMed:
Identification of pesticide transformation products in agricultural soils using liquid chromatography/quadrupole-time-of-flight mass spectrometry.
PubMed:
Anti-androgenic activities of environmental pesticides in the MDA-kb2 reporter cell line.
PubMed:
Capabilities of different liquid chromatography tandem mass spectrometry systems in determining pesticide residues in food. Application to estimate their daily intake.
PubMed:
Identification of new human pregnane X receptor ligands among pesticides using a stable reporter cell system.
PubMed:
Routine application using single quadrupole liquid chromatography-mass spectrometry to pesticides analysis in citrus fruits.
PubMed:
Comparison of liquid chromatography using triple quadrupole and quadrupole ion trap mass analyzers to determine pesticide residues in oranges.
PubMed:
Efficacy and adverse effects of patient-controlled epidural or intravenous analgesia after major surgery.
PubMed:
Measurement uncertainty from physical sample preparation: estimation including systematic error.
PubMed:
Focused microwave assistance for extracting some pesticide residues from strawberries into water before their determination by SPME/HPLC/DAD.
PubMed:
Pressurised fluid extraction of bupirimate and ethirimol from aged soils.
PubMed:
Solid-phase microextraction coupled with high performance liquid chromatography: a complementary technique to solid-phase microextraction-gas chromatography for the analysis of pesticide residues in strawberries.
PubMed:
Analysis of pesticide residues in hops and their extraction by liquid CO2 during the production of hop extracts.
PubMed:
Allergic contact dermatitis from the fungicide bupirimate.
PubMed:
Risk assessment of dermal exposure of greenhouse workers to pesticides after re-entry.
PubMed:
Assessment of dermal exposure of greenhouse workers to the pesticide bupirimate.
PubMed:
Induction of numerical chromosomal aberrations during DNA synthesis using the fungicides nimrod and rubigan-4 in root tips of Vicia faba L.