3-methyl hexanoic acid

hexanoic acid, 3-methyl-

CAS: 3780-58-3 C7 H14 O2 MW: 130.18698000

Identification

Name3-methyl hexanoic acid
IUPAC3-methylhexanoic acid
CAS Number3780-58-3
FDA UNIIE4GWJ09TGV
Molecular FormulaC7 H14 O2
Molecular Weight130.18698000
Nikkaji NumberJ362.527C
Beilstein1721252

Regulatory

DG SANTE Food Flavourings08.096 3-methylhexanoic acid

Physical Properties

Appearance colorless to pale yellow clear liquid (est)
Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Specific Gravity 0.91600 to 0.92200 @ 25.00 °C.
Pounds per Gallon - (est). 7.622 to 7.672
Refractive Index 1.41900 to 1.42500 @ 20.00 °C.
Boiling Point 210.00 to 212.00 °C. @ 760.00 mm Hg
Vapor Pressure 0.058000 mmHg @ 25.00 °C. (est)
Flash Point 217.00 °F. TCC ( 102.78 °C. )
logP (o/w) 2.070 (est)
Soluble in alcohol
Insoluble in water

No sensory data available

Safety Information

Oral/Parenteral Toxicityintraperitoneal-mouse LD > 400 mg/kg
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavoring agents
Recommendation for 3-methyl hexanoic acid usage levels up tonot for fragrance use.
Maximised Survey-derived Daily Intakes (MSDI-EU)0.24 (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI)2200 (μg/person/day)
Threshold of Concern1800 (μg/person/day)
Structure ClassI
Dairy products, excluding products of category 02.0 (01.0)3.00000
Fats and oils, and fat emulsions (type water-in-oil) (02.0)2.00000
Edible ices, including sherbet and sorbet (03.0)3.00000
Processed fruit (04.1)2.00000
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2)-
Confectionery (05.0)10.00000
Chewing gum (05.3)-
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0)5.00000
Bakery wares (07.0)10.00000
Meat and meat products, including poultry and game (08.0)2.00000
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0)2.00000
Eggs and egg products (10.0)-
Sweeteners, including honey (11.0)-
Salts, spices, soups, sauces, salads, protein products, etc. (12.0)5.00000
Foodstuffs intended for particular nutritional uses (13.0)10.00000
Non-alcoholic ("soft") beverages, excl. dairy products (14.1)-
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2)10.00000
Ready-to-eat savouries (15.0)15.00000
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0)5.00000

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Potential Uses

None Found

Natural Occurrence

not found in nature

Synonyms

hexanoic acid, 3-methyl- 3- methyl caproic acid 3- methylcaproic acid 3- methylhexanoic acid 3- methylhexylic acid PubMed: Gender-specific differences between the concentrations of nonvolatile (R)/(S)-3-methyl-3-sulfanylhexan-1-Ol and (R)/(S)-3-hydroxy-3-methyl-hexanoic acid odor precursors in axillary secretions. PubMed: A broad diversity of volatile carboxylic acids, released by a bacterial aminoacylase from axilla secretions, as candidate molecules for the determination of human-body odor type. PubMed: Identification of new odoriferous compounds in human axillary sweat. PubMed: Finding of an isoleucine derivative of a recombinant protein for pharmaceutical use. PubMed: A specific bacterial aminoacylase cleaves odorant precursors secreted in the human axilla. PubMed: Existence of beta-methylnorleucine in recombinant hirudin produced by Escherichia coli. PubMed: Mechanisms of microenvironmental pH regulation in the cuticle of Ascaris suum. PubMed: beta-methylnorleucine, an antimetabolite produced by Serratia marcescens.