vinyl butyrate

butanoic acid, ethenyl ester (9CI)

CAS: 123-20-6 C6 H10 O2 MW: 114.14410000

Identification

Namevinyl butyrate
IUPACethenyl butanoate
CAS Number123-20-6
EINECS204-609-4
FDA UNIISearch
Molecular FormulaC6 H10 O2
Molecular Weight114.14410000
MDL NumberMFCD00059410
Nikkaji NumberJ45.693D
Beilstein1744933

Regulatory

FDA Mainterm (IAUFC)123-20-6 ; VINYL BUTYRATE

Physical Properties

Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Melting Point -116.70 °C. @ 760.00 mm Hg
Boiling Point 119.00 to 120.00 °C. @ 760.00 mm Hg (est)
Vapor Pressure 15.569000 mmHg @ 25.00 °C. (est)
Flash Point 80.00 °F. TCC ( 26.40 °C. ) (est)
logP (o/w) 1.648 (est)
Soluble in alcohol
Insoluble in water

No sensory data available

Safety Information

Preferred SDSView
Oral/Parenteral Toxicityoral-rat LD50 8530 mg/kg
Dermal Toxicityskin-rabbit LD50 > 8 ml/kg
Inhalation Toxicityinhalation-rat LCLo 4000 ppm/4H

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categorynatural substances and extractives
Recommendation for vinyl butyrate usage levels up tonot for fragrance use.
Recommendation for vinyl butyrate flavor usage levels up tonot for flavor use.

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Potential Uses

None Found

Natural Occurrence

coffee PMC licania tomentosa fruit

Synonyms

butanoic acid ethenyl ester butanoic acid, ethenyl ester (9CI) butyric acid vinyl ester butyric acid, vinyl ester ethenyl butanoate vinyl butanoate vinyl butyrate, inhibited [UN2838] [Flammable liquid] PubMed: Solvent-Free Synthesis of Flavour Esters through Immobilized Lipase Mediated Transesterification. PubMed: Rapid synthesis of cellulose esters by transesterification of cellulose with vinyl esters under the catalysis of NaOH or KOH in DMSO. PubMed: Enhanced productivity of electrospun polyvinyl alcohol nanofibrous mats using aqueous N,N-dimethylformamide solution and their application to lipase-immobilizing membrane-shaped catalysts. PubMed: Sugar ester synthesis by thermostable lipase from Streptomyces thermocarboxydus ME168. PubMed: Enantioselective Transesterification Catalysis by Nanosized Serine Protease Subtilisin Carlsberg Particles in Tetrahydrofuran. PubMed: Non-lipolytic and lipolytic sequence-related carboxylesterases: a comparative study of the structure-function relationships of rabbit liver esterase 1 and bovine pancreatic bile-salt-activated lipase. PubMed: Enantioselective transesterification of glycidol catalysed by a novel lipase expressed from Bacillus subtilis. PubMed: Suppression of water as a nucleophile in Candida antarctica lipase B catalysis. PubMed: Two-Step Enzymatic Modification of Solid-Supported Bergenin in Aqueous and Organic Media. PubMed: Significant changes in the transesterification activity of free and mesoporous-immobilized Rhizopus oryzae lipase in ionic liquids. PubMed: Efficiently enhancing regioselective acylation of 5-azacytidine catalyzed by Candida antarctica lipase B with co-solvent mixtures as the reaction media. PubMed: Transesterification activity of a novel lipase from Acinetobacter venetianus RAG-1. PubMed: Effect of PEG modification on subtilisin Carlsberg activity, enantioselectivity, and structural dynamics in 1,4-dioxane. PubMed: Purification and biochemical characterization of a turkey preduodenal esterase. PubMed: Dynamic kinetic resolution of secondary alcohols combining enzyme-catalyzed transesterification and zeolite-catalyzed racemization. PubMed: On the relationship between the activity and structure of PEG-alpha-chymotrypsin conjugates in organic solvents. PubMed: Use of ionic liquids as media for the biocatalytic preparation of flavonoid derivatives with antioxidant potency. PubMed: How gastric lipase, an interfacial enzyme with a Ser-His-Asp catalytic triad, acts optimally at acidic pH. PubMed: Substrate specificity and kinetic properties of enzymes belonging to the hormone-sensitive lipase family: comparison with non-lipolytic and lipolytic carboxylesterases. PubMed: Enhanced enzyme activity and enantioselectivity of lipases in organic solvents by crown ethers and cyclodextrins. PubMed: Understanding structure-stability relationships of Candida antartica lipase B in ionic liquids. PubMed: Enhancement of enzyme activity and enantioselectivity by cyclopentyl methyl ether in the transesterification catalyzed by Pseudomonas cepacia lipase co-lyophilized with cyclodextrins. PubMed: Effect of immobilization support, water activity, and enzyme ionization state on cutinase activity and enantioselectivity in organic media. PubMed: Stereochemistry of a diastereoisomeric amphiphile and the species of the lipase influence enzyme activity in the transesterification catalyzed by a lipase-co-lyophilizate with the amphiphile in organic media. PubMed: Ester synthesis from trimethylammonium alcohols in dry organic media catalyzed by immobilized Candida antarctica lipase B. PubMed: [Chemical discrimination of compounds possessing an amino group]. PubMed: Distinction between esterases and lipases: a kinetic study with vinyl esters and TAG. PubMed: Nonaqueous biocatalytic synthesis of new cytotoxic doxorubicin derivatives: exploiting unexpected differences in the regioselectivity of salt-activated and solubilized subtilisin. PubMed: Lipase-catalysed hydrolysis of short-chain substrates in solution and in emulsion: a kinetic study. PubMed: Kinetic properties of Penicillium cyclopium lipases studied with vinyl esters. PubMed: Optimization of Pseudomonas cepacia lipase preparations for catalysis in organic solvents. PubMed: Activity, stability, and conformation of methoxypoly(ethylene glycol)-subtilisin at different concentrations of water in dioxane. PubMed: The influence of the mode of enzyme preparation on enzymatic enantioselectivity in organic solvents and its temperature dependence. PubMed: Probing a functional role of Glu87 and Trp89 in the lid of Humicola lanuginosa lipase through transesterification reactions in organic solvent. PubMed: Synthesis, absolute configuration, and enantioselectivity of antiretroviral effect of (R)-(-)- and (S)-(+)-cytallene. Lipase-catalyzed enantioselective acylations of (+/-)-N4-acylcytallenes. PubMed: Effect of support material and enzyme pretreatment on enantioselectivity of immobilized subtilisin in organic solvents. PubMed: Computer-assisted modeling of subtilisin enantioselectivity in organic solvents. PubMed: Inactivation and stabilization of stabilisins in neat organic solvents.