levoglucosenone

6,8-dioxabicyclo(3.2.1)oct-2-en-4-one, (1S)-

CAS: 37112-31-5 C6 H6 O3 MW: 126.11142000

Identification

Namelevoglucosenone
IUPAC(1S)-6,8-dioxabicyclo[3.2.1]oct-2-en-4-one
CAS Number37112-31-5
FDA UNIIB7N23SN1LB
Molecular FormulaC6 H6 O3
Molecular Weight126.11142000
MDL NumberMFCD00191664
Beilstein4859778

Regulatory

Physical Properties

Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Boiling Point 254.40 °C. @ 760.00 mm Hg (est)
Flash Point 209.00 °F. TCC ( 98.20 °C. ) (est)
logP (o/w) -0.740 (est)
Soluble in water, 1.431e+005 mg/L @ 25 °C (est)

No sensory data available

Safety Information

Preferred SDSView
Oral/Parenteral ToxicityNot determined
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryinformation only not used for fragrances or flavors
Recommendation for levoglucosenone usage levels up tonot for fragrance use.
Recommendation for levoglucosenone flavor usage levels up tonot for flavor use.

BOC Sciences

Best of Chemicals Supplier

Quality supplier of research chemicals and biochemicals including inhibitors, building blocks, GMP Products, impurities and metabolites, APIs for Veterinary, Natural Compounds, ADCs, Stem Cell Molecul...

View All Website 1-631-485-4226 account@bocsci.com

TCI AMERICA

Moving Your Chemistry Forward

We continuously strive to advance our technology.

View All Website 1-800-423-8616 Sales-US@TCIchemicals.com;

Potential Uses

None Found

Natural Occurrence

not found in nature

Synonyms

1,6- anhydro-3,4-dideoxyhex-3-enopyran-2-ulose (1S)-6,8- dioxabicyclo(3.2.1)oct-2-en-4-one 6,8- dioxabicyclo(3.2.1)oct-2-en-4-one, (1S)- PubMed: Catalytic fast pyrolysis of cellulose and biomass to produce levoglucosenone using magnetic SO4(2-)/TiO2-Fe3O4. PubMed: Theoretical insight into the pyrolytic deformylation of levoglucosenone and isolevoglucosenone. PubMed: Total synthesis of (+)-chloriolide. PubMed: Synthesis of tri-O-acetyl-D-allal from levoglucosenone. PubMed: 1,3-Dipolar cycloaddition reactions of azomethine ylides with a cellulose-derived chiral enone. A novel route for organocatalysts development. PubMed: Mechanism research on cellulose pyrolysis by Py-GC/MS and subsequent density functional theory studies. PubMed: Preparation of levoglucosenone through sulfuric acid promoted pyrolysis of bagasse at low temperature. PubMed: Catalytic fast pyrolysis of cellulose to prepare levoglucosenone using sulfated zirconia. PubMed: Cycloaddition and one-carbon homologation studies in the synthesis of advanced iridoid precursors. PubMed: Design, synthesis, and biological evaluation of levoglucosenone-derived ras activation inhibitors. PubMed: Pi-stacking effect on levoglucosenone derived internal chiral auxiliaries. A case of complete enantioselectivity inversion on the Diels-Alder reaction. PubMed: Quasienantiomeric levoglucosenone and isolevoglucosenone allow the parallel kinetic resolution of a racemic nitrone. PubMed: Inhibition of acid-catalyzed depolymerization of cellulose with boric acid in non-aqueous acidic media. PubMed: An efficient total synthesis of optically active tetrodotoxin from levoglucosenone. PubMed: [Unsaturated sugars in enantiospecific synthesis of natural low-molecular bioregulators and their structural analogues]. PubMed: Microwave-assisted regioselective cycloaddition reactions between 9-substituted anthracenes and levoglucosenone. PubMed: The use of levoglucosenone and isolevoglucosenone as templates for the construction of C-linked disaccharides. PubMed: Highly diastereoselective Diels-Alder reaction using a chiral auxiliary derived from levoglucosenone. PubMed: [Effect of acid hydrolysis of oak wood on its aroma-forming complex]. PubMed: Functionalized S-thio-di- and S-oligosaccharide precursors as templates for novel SLex/a mimetic antimetastatic agents. PubMed: Thio-sugars VII. Effect of 3-deoxy-4-S-(beta-D-gluco- and beta-D-galactopyranosyl)-4-thiodisaccharides and their sulfoxides and sulfones on the viability and growth of selected murine and human tumor cell lines. PubMed: Comparative Studies of Cathodically-Promoted and Base-Catalyzed Michael Addition Reactions of Levoglucosenone. PubMed: A Facile Entry into Naphthopyran Quinones via an Annelation Reaction of Levoglucosenone. The Total Synthesis of (-)-Hongconin(1). PubMed: Initiating activity of eight pyrolysates of carbohydrates in a two-stage mouse skin tumorigenesis model. PubMed: Chromosome aberrations induced by pyrolysates of carbohydrates in Chinese hamster V79 cells. PubMed: An unusual reaction of 1,6-anhydroaldohexopyranose derivatives leading to glycals.