methyl cyclopropane

cyclopropane, methyl-

CAS: 594-11-6 C4 H8 MW: 56.10776000

Identification

Namemethyl cyclopropane
IUPACmethylcyclopropane
CAS Number594-11-6
EINECS209-825-2
FDA UNIISearch
Molecular FormulaC4 H8
Molecular Weight56.10776000
Nikkaji NumberJ467G

Regulatory

Physical Properties

Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Boiling Point 0.70 °C. @ 760.00 mm Hg
Vapor Pressure 1779.200000 mmHg @ 25.00 °C. (est)
Flash Point -111.00 °F. TCC ( -79.30 °C. ) (est)
logP (o/w) 2.180 (est)
Soluble in water, 615.4 mg/L @ 25 °C (exp)

No sensory data available

Safety Information

Oral/Parenteral ToxicityNot determined
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryinformation only not used for fragrances or flavors
Recommendation for methyl cyclopropane usage levels up tonot for fragrance use.
Recommendation for methyl cyclopropane flavor usage levels up tonot for flavor use.

No supplier data available

Potential Uses

None Found

Natural Occurrence

not found in nature

Synonyms

cyclopropane, methyl- methylcyclopropane PubMed: Transient regulation of three clustered tomato class-I small heat-shock chaperone genes by ethylene is mediated by SlMADS-RIN transcription factor. PubMed: The Enigmatic P450 Decarboxylase OleT Is Capable of, but Evolved To Frustrate, Oxygen Rebound Chemistry. PubMed: Internal Rotation of Methylcyclopropane and Related Molecules: Comparison of Experiment and Theory. PubMed: Ruta montana L. leaf essential oil and extracts: characterization of bioactive compounds and suppression of crown gall disease. PubMed: Palladium(0)-Catalyzed Methylcyclopropanation of Norbornenes with Vinyl Bromides and Mechanism Study. PubMed: An antibacterial ortho-quinone diterpenoid and its derivatives from Caryopteris mongolica. PubMed: Two abscission zones proximal to Lansium domesticum fruit: one more sensitive to exogenous ethylene than the other. 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PubMed: Suppression of 9-cis-epoxycarotenoid dioxygenase, which encodes a key enzyme in abscisic acid biosynthesis, alters fruit texture in transgenic tomato. PubMed: Effects of abscisic acid on ethylene biosynthesis and perception in Hibiscus rosa-sinensis L. flower development. PubMed: Use of homologous and heterologous gene expression profiling tools to characterize transcription dynamics during apple fruit maturation and ripening. PubMed: Jasmonic acid and ethylene modulate local responses to wounding and simulated herbivory in Nicotiana attenuata leaves. PubMed: Metabolism of procymidone derivatives in female rats. PubMed: Transition state-finding strategies for use with the growing string method. PubMed: Different lepidopteran elicitors account for cross-talk in herbivory-induced phytohormone signaling. PubMed: Kinetic study of thermally stimulated dissociation of inclusion complex of 1-methylcyclopropene with alpha-cyclodextrin by thermal analysis. PubMed: In vitro inhibition of food spoilage and foodborne pathogenic bacteria by essential oil and leaf extracts of Magnolia liliflora Desr. PubMed: Chemical composition and antifungal activity of essential oil and various extract of Silene armeria L. PubMed: Differential feedback regulation of ethylene biosynthesis in pulp and peel tissues of banana fruit. PubMed: Analysis of the ambruticin and jerangolid gene clusters of Sorangium cellulosum reveals unusual mechanisms of polyketide biosynthesis. PubMed: Postharvest variation in apple (Malus x domestica Borkh.) Flavonoids following harvest, storage, and 1-MCP treatment. PubMed: Contrasting interactions between ethylene and abscisic acid in Rumex species differing in submergence tolerance. PubMed: Searching for intermediates in the carbon skeleton rearrangement of 2-methyleneglutarate to (R)-3-methylitaconate catalyzed by coenzyme B12-dependent 2-methyleneglutarate mutase from Eubacterium barkeri. PubMed: The Arabidopsis mutant eer2 has enhanced ethylene responses in the light. PubMed: A GH3-like gene, CcGH3, isolated from Capsicum chinense L. fruit is regulated by auxin and ethylene. PubMed: Six- and eightfold palladium-catalyzed cross-coupling reactions of hexa- and octabromoarenes. PubMed: Strain energy of small ring hydrocarbons. Influence of C-h bond dissociation energies. PubMed: 1-methylcyclopropene increases storability and shelf life in climacteric and nonclimacteric plums. PubMed: Hepatic biotransformation of the new calcium-mimetic agent, RWJ-68025, in the rat and in man--API-MS/MS identification of metabolites. PubMed: Ethylene rapidly up-regulates the activities of both monomeric GTP-binding proteins and protein kinase(s) in epicotyls of pea. PubMed: Quantitative relationships between induced jasmonic acid levels and volatile emission in Zea mays during Spodoptera exigua herbivory. PubMed: Ethylene biosynthesis in detached young persimmon fruit is initiated in calyx and modulated by water loss from the fruit. PubMed: Regulation of root hair initiation and expansin gene expression in Arabidopsis. PubMed: A convenient preparation of 2-fluoro-3-alkoxy-1,3-butadienes. PubMed: Mechanistic insights into C-H activation from radical clock chemistry: oxidation of substituted methylcyclopropanes catalyzed by soluble methane monooxygenase from Methylosinus trichosporium OB3b. PubMed: Regulation of programmed cell death in maize endosperm by abscisic acid. PubMed: Herbivore-induced ethylene suppresses a direct defense but not a putative indirect defense against an adapted herbivore. PubMed: Relationships between respiration, ethylene, and aroma production in ripening banana. PubMed: Analysis of programmed cell death in wheat endosperm reveals differences in endosperm development between cereals. PubMed: Differential expression and internal feedback regulation of 1-aminocyclopropane-1-carboxylate synthase, 1-aminocyclopropane-1-carboxylate oxidase, and ethylene receptor genes in tomato fruit during development and ripening. PubMed: Expression and internal feedback regulation of ACC synthase and ACC oxidase genes in ripening tomato fruit. PubMed: Effects of chilling on the expression of ethylene biosynthetic genes in Passe-Crassane pear (Pyrus communis L.) fruits. PubMed: Pharmacokinetic analysis and antiepileptic activity of tetra-methylcyclopropane analogues of valpromide. PubMed: Cytochrome P450-catalyzed hydroxylation of hydrocarbons: kinetic deuterium isotope effects for the hydroxylation of an ultrafast radical clock. PubMed: Cytochrome P450 hydroxylation of hydrocarbons: variation in the rate of oxygen rebound using cyclopropyl radical clocks including two new ultrafast probes. PubMed: Total synthesis of the racemic form of the second juvenile hormone (methyl 12-homojuvenate) from the cecropia silk moth. PubMed: Methylcyclopropane; infrared absorption spectrum and synthesis from i-butyl chloride.