methyl cyclopropane
cyclopropane, methyl-
Identification
| Name | methyl cyclopropane |
| IUPAC | methylcyclopropane |
| CAS Number | 594-11-6 |
| EINECS | 209-825-2 |
| FDA UNII | Search |
| Molecular Formula | C4 H8 |
| Molecular Weight | 56.10776000 |
| Nikkaji Number | J467G |
Regulatory
Physical Properties
| Assay | 95.00 to 100.00 |
| Food Chemicals Codex Listed | No |
| Boiling Point | 0.70 °C. @ 760.00 mm Hg |
| Vapor Pressure | 1779.200000 mmHg @ 25.00 °C. (est) |
| Flash Point | -111.00 °F. TCC ( -79.30 °C. ) (est) |
| logP (o/w) | 2.180 (est) |
| Soluble in | water, 615.4 mg/L @ 25 °C (exp) |
No sensory data available
Safety Information
| Oral/Parenteral Toxicity | Not determined |
| Dermal Toxicity | Not determined |
| Inhalation Toxicity | Not determined |
GHS Classification
['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']
Safety in Use
| Category | information only not used for fragrances or flavors |
| Recommendation for methyl cyclopropane usage levels up to | not for fragrance use. |
| Recommendation for methyl cyclopropane flavor usage levels up to | not for flavor use. |
No supplier data available
Potential Uses
Natural Occurrence
Synonyms
cyclopropane, methyl-
methylcyclopropane
PubMed:
Transient regulation of three clustered tomato class-I small heat-shock chaperone genes by ethylene is mediated by SlMADS-RIN transcription factor.
PubMed:
The Enigmatic P450 Decarboxylase OleT Is Capable of, but Evolved To Frustrate, Oxygen Rebound Chemistry.
PubMed:
Internal Rotation of Methylcyclopropane and Related Molecules: Comparison of Experiment and Theory.
PubMed:
Ruta montana L. leaf essential oil and extracts: characterization of bioactive compounds and suppression of crown gall disease.
PubMed:
Palladium(0)-Catalyzed Methylcyclopropanation of Norbornenes with Vinyl Bromides and Mechanism Study.
PubMed:
An antibacterial ortho-quinone diterpenoid and its derivatives from Caryopteris mongolica.
PubMed:
Two abscission zones proximal to Lansium domesticum fruit: one more sensitive to exogenous ethylene than the other.
PubMed:
Transcriptome changes in apple peel tissues during CO2 injury symptom development under controlled atmosphere storage regimens.
PubMed:
Environmental exposure to pyrethroids and sperm sex chromosome disomy: a cross-sectional study.
PubMed:
S-adenosyl-L-methionine usage during climacteric ripening of tomato in relation to ethylene and polyamine biosynthesis and transmethylation capacity.
PubMed:
Targeted systems biology profiling of tomato fruit reveals coordination of the Yang cycle and a distinct regulation of ethylene biosynthesis during postclimacteric ripening.
PubMed:
Ethylene supports colonization of plant roots by the mutualistic fungus Piriformospora indica.
PubMed:
Thermal rearrangements of 1-ethynyl-2-methylcyclopropane: a computational study.
PubMed:
Recombinant monoclonal antibody yield in transgenic tobacco plants is affected by the wounding response via an ethylene dependent mechanism.
PubMed:
Suppression of 9-cis-epoxycarotenoid dioxygenase, which encodes a key enzyme in abscisic acid biosynthesis, alters fruit texture in transgenic tomato.
PubMed:
Effects of abscisic acid on ethylene biosynthesis and perception in Hibiscus rosa-sinensis L. flower development.
PubMed:
Use of homologous and heterologous gene expression profiling tools to characterize transcription dynamics during apple fruit maturation and ripening.
PubMed:
Jasmonic acid and ethylene modulate local responses to wounding and simulated herbivory in Nicotiana attenuata leaves.
PubMed:
Metabolism of procymidone derivatives in female rats.
PubMed:
Transition state-finding strategies for use with the growing string method.
PubMed:
Different lepidopteran elicitors account for cross-talk in herbivory-induced phytohormone signaling.
PubMed:
Kinetic study of thermally stimulated dissociation of inclusion complex of 1-methylcyclopropene with alpha-cyclodextrin by thermal analysis.
PubMed:
In vitro inhibition of food spoilage and foodborne pathogenic bacteria by essential oil and leaf extracts of Magnolia liliflora Desr.
PubMed:
Chemical composition and antifungal activity of essential oil and various extract of Silene armeria L.
PubMed:
Differential feedback regulation of ethylene biosynthesis in pulp and peel tissues of banana fruit.
PubMed:
Analysis of the ambruticin and jerangolid gene clusters of Sorangium cellulosum reveals unusual mechanisms of polyketide biosynthesis.
PubMed:
Postharvest variation in apple (Malus x domestica Borkh.) Flavonoids following harvest, storage, and 1-MCP treatment.
PubMed:
Contrasting interactions between ethylene and abscisic acid in Rumex species differing in submergence tolerance.
PubMed:
Searching for intermediates in the carbon skeleton rearrangement of 2-methyleneglutarate to (R)-3-methylitaconate catalyzed by coenzyme B12-dependent 2-methyleneglutarate mutase from Eubacterium barkeri.
PubMed:
The Arabidopsis mutant eer2 has enhanced ethylene responses in the light.
PubMed:
A GH3-like gene, CcGH3, isolated from Capsicum chinense L. fruit is regulated by auxin and ethylene.
PubMed:
Six- and eightfold palladium-catalyzed cross-coupling reactions of hexa- and octabromoarenes.
PubMed:
Strain energy of small ring hydrocarbons. Influence of C-h bond dissociation energies.
PubMed:
1-methylcyclopropene increases storability and shelf life in climacteric and nonclimacteric plums.
PubMed:
Hepatic biotransformation of the new calcium-mimetic agent, RWJ-68025, in the rat and in man--API-MS/MS identification of metabolites.
PubMed:
Ethylene rapidly up-regulates the activities of both monomeric GTP-binding proteins and protein kinase(s) in epicotyls of pea.
PubMed:
Quantitative relationships between induced jasmonic acid levels and volatile emission in Zea mays during Spodoptera exigua herbivory.
PubMed:
Ethylene biosynthesis in detached young persimmon fruit is initiated in calyx and modulated by water loss from the fruit.
PubMed:
Regulation of root hair initiation and expansin gene expression in Arabidopsis.
PubMed:
A convenient preparation of 2-fluoro-3-alkoxy-1,3-butadienes.
PubMed:
Mechanistic insights into C-H activation from radical clock chemistry: oxidation of substituted methylcyclopropanes catalyzed by soluble methane monooxygenase from Methylosinus trichosporium OB3b.
PubMed:
Regulation of programmed cell death in maize endosperm by abscisic acid.
PubMed:
Herbivore-induced ethylene suppresses a direct defense but not a putative indirect defense against an adapted herbivore.
PubMed:
Relationships between respiration, ethylene, and aroma production in ripening banana.
PubMed:
Analysis of programmed cell death in wheat endosperm reveals differences in endosperm development between cereals.
PubMed:
Differential expression and internal feedback regulation of 1-aminocyclopropane-1-carboxylate synthase, 1-aminocyclopropane-1-carboxylate oxidase, and ethylene receptor genes in tomato fruit during development and ripening.
PubMed:
Expression and internal feedback regulation of ACC synthase and ACC oxidase genes in ripening tomato fruit.
PubMed:
Effects of chilling on the expression of ethylene biosynthetic genes in Passe-Crassane pear (Pyrus communis L.) fruits.
PubMed:
Pharmacokinetic analysis and antiepileptic activity of tetra-methylcyclopropane analogues of valpromide.
PubMed:
Cytochrome P450-catalyzed hydroxylation of hydrocarbons: kinetic deuterium isotope effects for the hydroxylation of an ultrafast radical clock.
PubMed:
Cytochrome P450 hydroxylation of hydrocarbons: variation in the rate of oxygen rebound using cyclopropyl radical clocks including two new ultrafast probes.
PubMed:
Total synthesis of the racemic form of the second juvenile hormone (methyl 12-homojuvenate) from the cecropia silk moth.
PubMed:
Methylcyclopropane; infrared absorption spectrum and synthesis from i-butyl chloride.