S-lipoate

1,2-dithiolane-3-pentanoic acid, (S)-

CAS: 1077-27-6 C8 H14 O2 S2 MW: 206.32798000

Identification

NameS-lipoate
IUPAC5-[(3S)-dithiolan-3-yl]pentanoic acid
CAS Number1077-27-6
FDA UNIIJ2Y905FQ57
Molecular FormulaC8 H14 O2 S2
Molecular Weight206.32798000
MDL NumberMFCD01863481
Nikkaji NumberJ231.967E
Beilstein0081852

Regulatory

Physical Properties

Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Boiling Point 362.50 °C. @ 760.00 mm Hg (est)
Flash Point 343.00 °F. TCC ( 173.00 °C. ) (est)
logP (o/w) 2.160 (est)
Soluble in water, 126.6 mg/L @ 25 °C (est)

No sensory data available

Safety Information

Preferred SDSView
Oral/Parenteral ToxicityNot determined
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryinformation only not used for fragrances or flavors
Recommendation for S-lipoate usage levels up tonot for fragrance use.
Recommendation for S-lipoate flavor usage levels up tonot for flavor use.

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Potential Uses

None Found

Natural Occurrence

not found in nature

Synonyms

5-[(3S)- dithiolan-3-yl]pentanoic acid 5-[(3S)-1,2- dithiolan-3-yl]pentanoic acid (S)-1,2- dithiolane-3-pentanoic acid 1,2- dithiolane-3-pentanoic acid, (S)- (S)- lipoic acid (S)-(-)- lipoic acid S-(-)-alpha- lipoic acid (-)- thioctic acid (S)- thioctic acid L- thioctic acid thioctic acid L-form thioctic acid laevo-form PubMed: R-α lipoic acid γ-cyclodextrin complex increases energy expenditure: a 4-month feeding study in mice. PubMed: Lipoic acid prevents fructose-induced changes in liver carbohydrate metabolism: role of oxidative stress. PubMed: Lipoic acid prevents liver metabolic changes induced by administration of a fructose-rich diet. PubMed: Age and gender dependent bioavailability of R- and R,S-α-lipoic acid: a pilot study. PubMed: Kinetic resolution of alpha-lipoic acid via enzymatic differentiation of a remote stereocenter. PubMed: Coenzyme Q(10) and alpha-lipoic acid supplementation in diabetic rats: conduction velocity distributions. PubMed: (r)-, but not (s)-alpha lipoic acid stimulates deficient brain pyruvate dehydrogenase complex in vascular dementia, but not in Alzheimer dementia. PubMed: Effect of single and combined supply of glutamine, glycine, N-acetylcysteine, and R,S-alpha-lipoic acid on glutathione content of myelomonocytic cells. PubMed: Purification, characterization, and cDNA cloning of lipoate-activating enzyme from bovine liver. PubMed: Engagement of the insulin-sensitive pathway in the stimulation of glucose transport by alpha-lipoic acid in 3T3-L1 adipocytes. PubMed: Inhibition of L-homocysteic acid and buthionine sulphoximine-mediated neurotoxicity in rat embryonic neuronal cultures with alpha-lipoic acid enantiomers. PubMed: Enantioselective high-performance liquid chromatography assay of (+)R- and (-)S-alpha-lipoic acid in human plasma. PubMed: Cytosolic and mitochondrial systems for NADH- and NADPH-dependent reduction of alpha-lipoic acid. PubMed: Stereospecific effects of R-lipoic acid on buthionine sulfoximine-induced cataract formation in newborn rats. PubMed: Antioxidant inhibition of skin inflammation induced by reactive oxidants: evaluation of the redox couple dihydrolipoate/lipoate. PubMed: 2-ketoacid dehydrogenase complexes of Escherichia coli: stereospecificities of the three components for (R)-lipoate. PubMed: [Kinetics of 35S-lipoate binding in vitro by plasma proteins and formed elements of the blood]. PubMed: Studies of energy-linked reactions. Net synthesis of adenosine triphosphate by isolated adenosine triphosphate synthase preparations: a role for lipoic acid and unsaturated fatty acids.