humulene oxide II

(3E,7E,11R)-1,5,5,8-tetramethyl-12-oxabicyclo[9.1.0]dodeca-3,7-diene

CAS: 19888-34-7 C15 H24 O MW: 220.35548000

Identification

Namehumulene oxide II
IUPAC(3E,7E,11R)-1,5,5,8-tetramethyl-12-oxabicyclo[9.1.0]dodeca-3,7-diene
CAS Number19888-34-7
FDA UNIISearch
Molecular FormulaC15 H24 O
Molecular Weight220.35548000

Regulatory

Physical Properties

Appearance colorless to pale yellow clear liquid (est)
Assay 90.00 to 100.00
Food Chemicals Codex Listed No
Boiling Point 285.00 to 286.00 °C. @ 760.00 mm Hg
Vapor Pressure 0.005000 mmHg @ 25.00 °C. (est)
Flash Point 254.00 °F. TCC ( 123.33 °C. )
logP (o/w) 4.514 (est)
Soluble in alcohol
Insoluble in water

No sensory data available

Safety Information

Oral/Parenteral ToxicityNot determined
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categorynatural substances and extractives
Recommendation for humulene oxide II usage levels up tonot for fragrance use.
Recommendation for humulene oxide II flavor usage levels up tonot for flavor use.

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Potential Uses

None Found

Natural Occurrence

allspice plant cassinia laevis flower oil australia @ 1.00% Data cassinia laevis leaf oil australia @ 0.70% Data geranium rose-scented oil (pelargonium spp.) cuba @ 1.80% Data ginger rhizome guava leaf oil cuba @ 0.20% Data hop jambu flower oil brazil @ 0.10% Data mikania cordata (burm. f.) b.l. robinson var. cordata leaf oil france @ 2.70% Data myrtle oil @ 0.09% Data nepeta betonicifolia c.a. meyer oil turkey @ 4.70% Data protium heptaphyllum (aubl.) march leaf oil brazil @ 1.00% Data rosemary plant sage oil dalmatian @ 1.20% Data salvia officinalis seed oil tunisia @ 0.25% Data vassoura oil @ 0.10% Data

Synonyms

6,7- epoxy-2,9-humuladiene humulene epoxide II (3E,7E,11R)-1,5,5,8- tetramethyl-12-oxabicyclo[9.1.0]dodeca-3,7-diene PubMed: ent-Kaurane diterpenes from the stem bark of Annona vepretorum (Annonaceae) and cytotoxic evaluation. PubMed: Characterization of novel single-variety oxygenated sesquiterpenoid hop oil fractions via headspace solid-phase microextraction and gas chromatography-mass spectrometry/olfactometry. PubMed: Chemical composition and biological activities of the essential oil of Athanasia brownii Hochr. (Asteraceae) endemic to Madagascar. PubMed: Comparison of different extraction methods for the determination of α- and β-thujone in sage (Salvia officinalis L.) herbal tea. PubMed: Essential oils from the leaves of six medicinal plants of Nigeria. PubMed: Chemical composition of the essential oil of Zingiber zerumbet var. darcyi. PubMed: Chemical composition, antimicrobial, and cytotoxicity studies on S. erianthum and S. macranthum essential oils. PubMed: Isoiridomyrmecin rich essential oil from Nepeta erecta Benth. and its antioxidant activity. PubMed: Caryophyllene oxide-rich essential oils of Lithuanian Artemisia campestris ssp. campestris and their toxicity. PubMed: Oil constituents of Artemisia nilagirica var. septentrionalis growing at different altitudes. PubMed: Chemical composition and larvicidal activity against Aedes aegypti larvae of essential oils from four Guarea species. PubMed: Chemical composition and evaluation of the anti-hypernociceptive effect of the essential oil extracted from the leaves of Ugni myricoides on inflammatory and neuropathic models of pain in mice. PubMed: Chemical composition of the essential oils of the flowers, leaves and stems of two senecio polyanthemoides Sch. Bip. samples from South Africa. PubMed: Suppression of lipopolysaccharide-stimulated inducible nitric oxide synthase (iNOS) expression by a novel humulene derivative in macrophage cells. PubMed: Anti-inflammatory effects of compounds alpha-humulene and (-)-trans-caryophyllene isolated from the essential oil of Cordia verbenacea. PubMed: Isolation and identification of mosquito bite deterrent terpenoids from leaves of American (Callicarpa americana) and Japanese (Callicarpa japonica) beautyberry. PubMed: Antennal responses to floral scents in the butterfly Heliconius melpomene. PubMed: Inhibitors of nitric oxide production from hops (Humulus lupulus L.). PubMed: Zerumbone, a Southeast Asian ginger sesquiterpene, markedly suppresses free radical generation, proinflammatory protein production, and cancer cell proliferation accompanied by apoptosis: the alpha,beta-unsaturated carbonyl group is a prerequisite. PubMed: Composition and some biological activities of the essential oil of Callicarpa americana (L.). PubMed: Multichemical defense of plant bugHotea gambiae (westwood) (Heteroptera: Scutelleridae) : Sesquiterpenoids from abdominal gland in larvae.