3-mercapto-2-methyl pentanol

3-mercapto-2-methylpentan-1-ol (racemic)

CAS: 227456-27-1 C6 H14 O S MW: 134.24178000 sulfurous alliaceous

Identification

Name3-mercapto-2-methyl pentanol
CAS Number227456-27-1
FDA UNII7XRY329G5S
Molecular FormulaC6 H14 O S
Molecular Weight134.24178000
MDL NumberMFCD08741458
Nikkaji NumberJ1.340.022I

Regulatory

JECFA Food Flavoring1291 3-mercapto-2-methylpentan-1-ol (racemic)
DG SANTE Food Flavourings12.238 3-mercapto-2-methylpentan-1-ol (racemic)
FEMA Number3996
FDANo longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF)227456-27-1 ; 3-MERCAPTO-2-METHYL-1-PENTANOL

Physical Properties

Appearance colorless to yellow clear liquid (est)
Assay 99.00 to 100.00
Food Chemicals Codex Listed No
Specific Gravity 0.98500 to 0.99500 @ 25.00 °C.
Pounds per Gallon - (est). 8.196 to 8.279
Refractive Index 1.48000 to 1.49000 @ 20.00 °C.
Boiling Point 50.00 °C. @ 0.50 mm Hg, 205.00 °C. @ 760.00 mm Hg (est)
Acid Value 1.00 max. KOH/g
Vapor Pressure 0.061000 mmHg @ 25.00 °C. (est)
Flash Point 172.00 °F. TCC ( 77.80 °C. ) (est)
logP (o/w) 1.626 (est)
Soluble in alcohol
Insoluble in water

Organoleptic Properties

Odor Description at 0.10 % in propylene glycol.
Taste Description alliaceous brothy burnt cooked meaty metallic roasted sulfurous

Safety Information

Oral/Parenteral ToxicityNot determined
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavoring agents
Recommendation for 3-mercapto-2-methyl pentanol usage levels up tonot for fragrance use.
Maximised Survey-derived Daily Intakes (MSDI-EU)0.01 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA)0.70 (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI)348 (μg/person/day)
NOEL (No Observed Effect Level)0.7 (mg/kg bw per day)
Threshold of Concern1800 (μg/person/day)
Structure ClassI
baked goods0.00500
beverages(nonalcoholic)-
beverages(alcoholic)-
breakfast cereal0.00300
cheese-
chewing gum-
condiments / relishes0.00300
confectionery froastings-
egg products-
fats / oils0.00500
fish products0.00100
frozen dairy-
fruit ices-
gelatins / puddings-
granulated sugar-
gravies0.00500
hard candy-
imitation dairy-
instant coffee / tea-
jams / jellies-
meat products0.00300
milk products-
nut products-
other grains0.00100
poultry-
processed fruits-
processed vegetables0.00100
reconstituted vegetables0.00100
seasonings / flavors0.03000
snack foods0.00100
soft candy-
soups0.00300
sugar substitutes-
sweet sauces-
Dairy products, excluding products of category 02.0 (01.0)0.60000
Fats and oils, and fat emulsions (type water-in-oil) (02.0)0.04000
Edible ices, including sherbet and sorbet (03.0)0.50000
Processed fruit (04.1)-
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2)0.20000
Confectionery (05.0)0.75000
Chewing gum (05.3)-
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0)0.62000
Bakery wares (07.0)0.80000
Meat and meat products, including poultry and game (08.0)0.73000
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0)0.10000
Eggs and egg products (10.0)0.08000
Sweeteners, including honey (11.0)-
Salts, spices, soups, sauces, salads, protein products, etc. (12.0)0.45000
Foodstuffs intended for particular nutritional uses (13.0)-
Non-alcoholic ("soft") beverages, excl. dairy products (14.1)0.50000
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2)0.10000
Ready-to-eat savouries (15.0)1.10000
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0)-

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Endeavour Specialty Chemicals Ltd

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Natural Advantage

Manufacturer of natural flavor ingredients

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Penta International Corporation

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Robinson Brothers Limited

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R C Treatt and Co Ltd

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Qingdao Free Trade Zone United International Co Ltd

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WholeChem, LLC

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Potential Uses

FL garlic FL onion

Natural Occurrence

wine

Synonyms

racemic-3- mercapto-2-methyl pentan-1-ol 3- mercapto-2-methylpenta-1-ol 3- mercapto-2-methylpentan-1-ol 3- mercapto-2-methylpentan-1-ol (racemic) 3- mercapto-2-methylpentanol 2- methyl-3-sulfanylpentan-1-ol pentan-1-ol, 3-mercapto-2-methyl- 1- pentanol, 3-mercapto-2-methyl- PubMed: Evaluation of the key aroma compounds in beef and pork vegetable gravies a la chef by stable isotope dilution assays and aroma recombination experiments. PubMed: Characterization of the key aroma compounds in beef and pork vegetable gravies á la chef by application of the aroma extract dilution analysis. PubMed: Odorous impact of volatile thiols on the aroma of young botrytized sweet wines: identification and quantification of new sulfanyl alcohols. PubMed: Quantitation of the intense aroma compound 3-mercapto-2-methylpentan-1-ol in raw and processed onions (Allium cepa) of different origins and in other Allium varieties using a stable isotope dilution assay. PubMed: Inhibition of peroxynitrite-mediated cellular toxicity, tyrosine nitration, and alpha1-antiproteinase inactivation by 3-mercapto-2-methylpentan-1-ol, a novel compound isolated from Allium cepa. PubMed: Enantioselective syntheses and sensory properties of the 3-mercapto-2-methylpentanols. PubMed: 3-Mercapto-2-methylpentan-1-ol, a new powerful aroma compound.