lobaric acid

11H-dibenzo(b,e)(1,4)dioxepin-7-carboxylic acid, 8-hydroxy-3-methoxy-11-oxo-1-(1-oxopentyl)-6-pentyl-

CAS: 522-53-2 C25 H28 O8 MW: 456.49176000

Identification

Namelobaric acid
IUPAC3-hydroxy-9-methoxy-6-oxo-7-pentanoyl-1-pentylbenzo[b][1,4]benzodioxepine-2-carboxylic acid
CAS Number522-53-2
FDA UNIISearch
Molecular FormulaC25 H28 O8
Molecular Weight456.49176000
MDL NumberMFCD00597234
Nikkaji NumberJ11.718H

Regulatory

Physical Properties

Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Boiling Point 667.90 °C. @ 760.00 mm Hg (est)
Flash Point 438.00 °F. TCC ( 225.70 °C. ) (est)
logP (o/w) 7.070 (est)
Soluble in water, 0.007725 mg/L @ 25 °C (est)

No sensory data available

Safety Information

Oral/Parenteral ToxicityNot determined
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categorynatural substances and extractives
Recommendation for lobaric acid usage levels up tonot for fragrance use.
Recommendation for lobaric acid flavor usage levels up tonot for flavor use.

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Potential Uses

None Found

Natural Occurrence

parmelia PMC stereocaulon PMC

Synonyms

11H- dibenzo(b,e)(1,4)dioxepin-7-carboxylic acid, 8-hydroxy-3-methoxy-11-oxo-1-(1-oxopentyl)-6-pentyl- 8- hydroxy-3-methoxy-11-oxo-1-(1-oxopentyl)-6-pentyl-11H-dibenzo(b,e)(1,4)dioxepin-7-carboxylic acid 8- hydroxy-3-methoxy-11-oxo-1-pentanoyl-6-pentyl-11H-dibenzo[b,e][1,4]dioxepine-7-carboxylic acid 3- hydroxy-9-methoxy-6-oxo-7-pentanoyl-1-pentylbenzo[b][1,4]benzodioxepine-2-carboxylic acid usnetic acid PubMed: UV-protectant metabolites from lichens and their symbiotic partners. PubMed: Sekikaic acid and lobaric acid target a dynamic interface of the coactivator CBP/p300. PubMed: Lobarin from the Sumatran lichen, Stereocaulon halei. PubMed: Cytotoxic activity and antioxidant capacity of purified lichen metabolites: an in vitro study. PubMed: Antioxidant activity of some lichen metabolites. PubMed: Antimitotic activity of lobaric acid and a new benzofuran, sakisacaulon A from Stereocaulon sasakii. PubMed: Protein tyrosine phosphatase 1B inhibitory effects of depsidone and pseudodepsidone metabolites from the Antarctic lichen Stereocaulon alpinum. PubMed: Eubacterium rangiferina, a novel usnic acid-resistant bacterium from the reindeer rumen. PubMed: Spectroscopic and photochemical properties of the lichen compound lobaric acid. PubMed: Anti-proliferative lichen compounds with inhibitory activity on 12(S)-HETE production in human platelets. PubMed: Anti-proliferative effects of lichen-derived lipoxygenase inhibitors on twelve human cancer cell lines of different tissue origin in vitro. PubMed: Antimycobacterial activity of lichen metabolites in vitro. PubMed: Anti-proliferative effects of lichen-derived inhibitors of 5-lipoxygenase on malignant cell-lines and mitogen-stimulated lymphocytes. PubMed: Effect of lobaric acid on cysteinyl-leukotriene formation and contractile activity of guinea pig taenia coli. PubMed: Inhibitory effects of the lichen metabolite lobaric acid on arachidonate metabolism in vitro.