dimethyl (R)-malate
butanedioic acid, 2-hydroxy-, dimethyl ester, (2R)-
Identification
| Name | dimethyl (R)-malate |
| IUPAC | dimethyl (2R)-2-hydroxybutanedioate |
| CAS Number | 70681-41-3 |
| FDA UNII | Search |
| Molecular Formula | C6 H10 O5 |
| Molecular Weight | 162.14170000 |
| MDL Number | MFCD00066216 |
| Nikkaji Number | J231.848B |
| Beilstein | 1908705 |
Regulatory
Physical Properties
| Assay | 95.00 to 100.00 |
| Food Chemicals Codex Listed | No |
| Boiling Point | 249.60 °C. @ 760.00 mm Hg (est) |
| Flash Point | 212.00 °F. TCC ( 100.10 °C. ) (est) |
| logP (o/w) | -0.830 (est) |
| Soluble in | water, 1e+006 mg/L @ 25 °C (est) |
No sensory data available
Safety Information
| Preferred SDS | View |
| Oral/Parenteral Toxicity | Not determined |
| Dermal Toxicity | Not determined |
| Inhalation Toxicity | Not determined |
GHS Classification
['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']
Safety in Use
| Category | information only not used for fragrances or flavors |
| Recommendation for dimethyl (R)-malate usage levels up to | not for fragrance use. |
| Recommendation for dimethyl (R)-malate flavor usage levels up to | not for flavor use. |
Potential Uses
Natural Occurrence
Synonyms
butanedioic acid, 2-hydroxy-, dimethyl ester, (2R)-
dimethyl (2R)-2-hydroxybutanedioate
dimethyl (2R)-2-hydroxysuccinate
dimethyl (R)-(+)-malate
dimethyl D-(+)-malate
PubMed:
[Chemical constituents from rizomes of Homalomena occulta].
PubMed:
Concise route to the chiral pyrrolidine core of selective inhibitors of neuronal nitric oxide.
PubMed:
Gateways to clinical trials.
PubMed:
Enthalpy change on mixing a couple of S- and R-enantiomers of some chiral compounds at 298.15 K.
PubMed:
Anthelmintic efficacy of Flemingia vestita (Fabaceae): alterations in glucose metabolism of the cestode, Raillietina echinobothrida.
PubMed:
A new approach for asymmetric synthesis of (R)-3-methylpyrrolidine alkaloids from (S)-malic acid.
PubMed:
Control of dimethylsulfoxide reductase expression in Rhodobacter capsulatus: the role of carbon metabolites and the response regulators DorR and RegA.
PubMed:
Synthesis and 31P chemical shift identification of tripeptide active site models that represent human serum acetylcholinesterase covalently modified at serine by certain organophosphates.
PubMed:
Counteractive Effects of ABA and GA3 on Extracellular and Intracellular pH and Malate in Barley Aleurone.
PubMed:
Genetic and physiological characterization of the Rhodospirillum rubrum carbon monoxide dehydrogenase system.
PubMed:
12(R)-hydroxyeicosatrienoic acid: a vasodilator cytochrome P-450-dependent arachidonate metabolite from the bovine corneal epithelium.
PubMed:
Equilibrium constants of several reactions involved in the fermentation of glutamate.
PubMed:
Nicotinic acid metabolism. Dimethylmaleate hydratase.
PubMed:
Fermentation and anaerobic respiration by Rhodospirillum rubrum and Rhodopseudomonas capsulata.