watermelon ketone

calone (Firmenich)

CAS: 28940-11-6 C10 H10 O3 MW: 178.18730000 melon

Identification

Namewatermelon ketone
IUPAC8-methyl-1,5-benzodioxepin-3-one
CAS Number28940-11-6
EINECS249-320-4
FDA UNII0NQ136C313
Molecular FormulaC10 H10 O3
Molecular Weight178.18730000
MDL NumberMFCD07371373
Nikkaji NumberJ286.485A

Regulatory

Physical Properties

Appearance white powder crystals (est)
Assay 98.00 to 100.00
Food Chemicals Codex Listed No
Melting Point 38.00 to 41.00 °C. @ 760.00 mm Hg
Boiling Point 158.00 °C. @ 760.00 mm Hg, 95.00 °C. @ 1.00 mm Hg
Vapor Pressure 0.001000 mmHg @ 25.00 °C. (est)
Flash Point 332.00 °F. TCC ( 166.67 °C. )
logP (o/w) 2.430
Shelf Life 36.00 month(s) or longer if stored properly.
Storage store in cool, dry place in tightly sealed containers, protected from heat and light.
Soluble in alcohol
Insoluble in paraffin oil
Stability APC: traces - 0.5%

Cosmetic Information

CosIngcosmetic data
Cosmetic Usesfragrance

Organoleptic Properties

Odor Strength high ,
Substantivity > 600 hour(s) at 10.00 % in dipropylene glycol
Odor Description
at 10.00 % in dipropylene glycol.
This unusual odorant has intense ozone and marine notes with floral overtones
marine moss ozone floral heliotrope melon green fresh
Fresh, Fruity, Green, Marine
Fresh, watery, clean, melon-green, marine, ozone
Fresh, marine, green, watermelon, oceanic note
Fresh, ozone, sea flavor with a hint of juicy watermelon flesh
Odor sample from CAL/Pfizer

Safety Information

European informationMost important hazard(s):
Oral/Parenteral Toxicityoral-rat LD50 1556 mg/kg
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryfragrance agents
RIFM Fragrance Material Safety AssessmentSearch
Recommendation for watermelon ketone usage levels up to0.5000 % in the fragrance concentrate.
Recommendation for watermelon ketone flavor usage levels up tonot for flavor use.

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Potential Uses

FR agrumen aldehyde FR aldehydic FR algae FR apple red apple blossom tropical blossom FR boxwood FR bramble arctic bramble blackberry FL/FR cilantro FR citrus clean FR cologne FR cucumber FR dogwood exotic fantasy blends FR fern FL fish FR floral FR florida breeze FR forest FR fresh outdoors FL fruit tropical fruit FR galbanum FR gooseberry FR grapefruit FR green FR herbal FR hibiscus FR honeydew FR kiwi FR kiwi blossom FR lemon FR lily of the valley FR mango FR mango flower FR melon montana FR new car FR ocean sea FR ocean sea shell FR sea breeze ozone FR peach FL pear prickly pear rose wild rose FR sea breeze FR spring rain FL tropical FL vegetable watery FR woody

Natural Occurrence

not found in nature

Synonyms

aquamor (IFF) 2H-1,5- benzodioxepin-3(4H)-one, 7-methyl- calone (Firmenich) calone 161 (Firmenich) calone 161 DPG (Firmenich) calone 1951 (Firmenich) ganone marinone (A.C.S. International) methyl benzodioxepinone 7- methyl-1,5-benzodioxepan-3-one 8- methyl-1,5-benzodioxepin-3-one 7- methyl-2H-1,5-benzodioxepin-3(4H)-one 7- methyl-2h-benzo-1,5-dioxepin-3(4h)-one 7- methyl-2H-benzo[b][1,4]dioxepin-3(4H)-one 7- methyl-2H,4H-1,5-benzodioxepin-3-one 7- methyl-2H,4H-benzo[b]1,4-dioxepan-3-one 7- methyl-3,4-dihydro-2H-1,5-benzdioxepine-3-one 7- methyl-3,4-dihydro-2H-1,5-benzodioxepin-3-one 7- methyl-3,4-dihydro(2H)-1,5-benzodioxepepin-3-one methyl-7-3,4-dihydro-(2H)-1,5-benzodioxepine-3-one oceanone oceone ozonor watermelon ketone watermelon ketone 10% dpg watermelon ketone 50% solution in ethyl diglycol watermelon ketone,calone PubMed: Marine fragrance chemistry. PubMed: Characterization and semiquantitative analysis of volatiles in seedless watermelon varieties using solid-phase microextraction.